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Safety Data Sheet EN

D122727

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
D122727
Product Code
73336

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Additive for car engine lubricating oil

Uses advised against

This material should not be used for any other purpose than that recommended without expert advice.

Manufacturers & Suppliers

INFINEUM NETHERLANDS B.V. logo

INFINEUM NETHERLANDS B.V.

Westblaak 89 Rotterdam 3012 KG Nederland

http://www.infineum.com

Emergency Contacts

Emergency Contact

04-4274.4690

Emergency Contact

+33-4.4274.4690

Emergency Contact

0221-7499 3355

Emergency Contact

+49-221-7499 3355

Emergency Contact

019-2150 221

Emergency Contact

+39 019-2150 221

Emergency Contact

01235 549777

Emergency Contact

+44 1235 549777

Emergency Contact

070 245 245

Emergency Contact

+32 70 245 245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Aquatic Chronic Cat. 3 H412

GHS Pictograms

Hazard Statements

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
bis(nonylphenyl)amine EC: 253-249-4 --- 2.5 - 10% Yes
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts EC: 283-392-8 --- 3 - 5% Yes
C14-16-18 Alkyl phenol --- 0.1 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathing has stopped, assist ventilation with a mechanical device. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician.

Skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. In case of burns apply cold water until pain subsides then seek medical advice.

Symptoms: burns

Eye contact

Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists: Get medical advice/ attention.

Symptoms: eye irritation

Ingestion

Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

Medical Treatment

Show this safety data sheet to the doctor in attendance.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames

Unsuitable media

High volume water jet

Specific hazards

Not classified as flammable or combustible, but will combust if ignited.

Instructions

Fire-fighters should exercise extreme caution in enclosed spaces due to the possible presence of toxic decomposition and combustion products. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus. Self-contained full-face overpressure breathing apparatus should be used in enclosed spaces. Use standard body protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Advice for emergency responders: Ensure adequate ventilation. Use personal protective equipment. Material can create slippery conditions. For personal protection see section 8. Advice for non-emergency personnel: Avoid contact with spilled material. Do not touch or walk through spilled material.

Large spill

Dyke far ahead of liquid spill for later recovery and disposal.

Environmental

Prevent entry into waterways, sewers, basements or confined areas. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Recover by pumping or with suitable absorbent. Seek the advice of a specialist before using dispersants. Wipe up with absorbent material (e.g. cloth, fleece).

Materials: absorbent material (e.g. cloth, fleece)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations.

Storage

Product should be stored below the recommended maximum loading / unloading temperature to avoid degradation of product quality and eventually decomposition.

Hygiene

Smoking, eating and drinking should be prohibited in the application area.

Fire prevention

Normal measures for preventive fire protection.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

See attached ES. No special requirements under ordinary conditions of use and with adequate ventilation. If decomposition is suspected, or if the product has been overheated, do not open the container, discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary precautions to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as evacuation of contaminated areas, and use of suitable respiratory protection.

Hands

Polyvinyl alcohol or nitrile- butyl-rubber gloves Before removing gloves clean them with soap and water. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. When handling hot material, use heat resistant gloves. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Eyes

The applicable European standard can be found in EN 166. Eye wash bottle with pure water. Tightly fitting safety goggles. Ensure that eyewash stations and safety showers are close to the workstation location.

Respiratory

The applicable European standard can be found in EN 140, EN 137, EN 143, EN 14387.

Skin/Body

Impervious clothing. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Long sleeved clothing. The applicable European standard can be found in EN 14605.

Environmental

See attached ES. Prevent entry into waterways, sewers, basements or confined areas. Local authorities should be advised if significant spillages cannot be contained. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Try to prevent the material from entering drains or water courses. If the product contaminates rivers and lakes or drains inform respective authorities.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
brown
Colour Intensity
---
Form
viscous
Odor
hydrocarbon-like
Odor Threshold
not determined
Ph
Not applicable
Melting Point
not determined
Boiling Point
not determined
Flash Point
Pensky-Martens Closed Cup (ASTM D93): 161 °C (322 °F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable
Vapor Pressure
< 0,1 hPa (< 0,1 mmHg) at 20 °C (68 °F) estimated
Vapor Density
not determined
Relative Density
0,944 at 15,6 °C (60,1 °F)
Bulk Density
Not applicable
Density
0,943 g/cm3 at 15 °C (59 °F)
Flammability
not determined
Upper Explosive Limit
not determined
Lower Explosive Limit
not determined
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
not determined
Solubility
---
Partition Coefficient
not determined
Solubility In Water
< 0,0001 g/l estimated
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
196 mm2/s at 100 °C (212 °F); 4387 mm2/s at 40 °C (104 °F)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No dangerous reaction known under conditions of normal use.

Hazardous reactions

No hazards to be specially mentioned.

Avoid

Excessive heat.

Incompatible

Strong oxidizing agents, water

Decomposition

Hydrogen Sulfide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product: Toxicity to fish : No data is available on the product itself. Toxicity to daphnia and other aquatic invertebrates : No data is available on the product itself. Toxicity to algae : No data is available on the product itself. Components:

No data is available on the product itself.

12.1 Toxicity

bis(nonylphenyl)amine : Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 100 mg/l Exposure time: 96 h Test Method: static test Test substance: Read-across (Analogy) Method: OECD Test Guideline 203 Based on available data, the classification criteria are not met. Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Test Method: static test Test substance: yes Method: OECD Test Guideline 202 Based on available data, the classification criteria are not met.

The substance is not classified for aquatic toxicity based on available data for fish and daphnia.

Toxicity

Toxicity to algae: EC50 (Desmodesmus subspicatus (green algae)): > 100 mg/l Exposure time: 72 h Test Method: static test Test substance: Read-across (Analogy) Method: OECD Test Guideline 201 Based on available data, the classification criteria are not met.

12.1 Toxicity

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 4,5 mg/l Exposure time: 96 h Test Method: semi-static test Analytical monitoring: no Test substance: yes Method: OECD Test Guideline 203 GLP: yes Toxic to aquatic life. Toxicity to daphnia and other aquatic invertebrates : EL50 (Daphnia magna (Water flea)): 23 mg/l Exposure time: 48 h Test Method: static test Analytical monitoring: no Test substance: yes Method: OECD Test Guideline 202 GLP: yes Harmful to aquatic life. Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 21 mg/l Exposure time: 72 h Test Method: static test Analytical monitoring: no Test substance: yes Method: OECD Test Guideline 201 GLP: yes Harmful to aquatic life. Toxicity to bacteria : IC50 : 10.000 mg/l Exposure time: 3 h Test Method: Respiration inhibition Test substance: yes GLP: Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 0,4 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Analytical monitoring: yes Test substance: yes Method: OECD Test Guideline 211 GLP: yes Toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability

Biodegradability : No data is available on the product itself.

No data is available on the product itself.

12.2 Persistence and degradability

bis(nonylphenyl)amine : Biodegradability : aerobic activated sludge Result: Not biodegradable Biodegradation: 1 % Exposure time: 28 d Test substance: Read-across (Analogy) According to the results of tests of biodegradability this product is not readily biodegradable.

The substance is not readily biodegradable, with 1% biodegradation observed after 28 days in activated sludge.

12.2 Persistence and degradability

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Biodegradability : aerobic activated sludge Concentration: 10 mg/l Result: Not readily biodegradable. Biodegradation: 1,5 % Exposure time: 28 d Method: OECD Test Guideline 301B Test substance: yes GLP: yes According to the results of tests of biodegradability this product is not readily biodegradable. Stability in water : Hydrolysis: 6,6 % at50 °C(120 h) pH: 7 Test substance: yes Method: OECD Test Guideline 111 Hydrolysis: 0 % at50 °C(120 h) pH: 4 Test substance: yes Method: OECD Test Guideline 111 Hydrolysis: 0 % at50 °C(120 h) pH: 9 Test substance: yes Method: OECD Test Guideline 111

The substance is not readily biodegradable based on OECD 301B test results. Hydrolysis tests at 50°C show low degradation at pH 4, 7, and 9.

12.3 Bioaccumulative potential

Product: Bioaccumulation : No data is available on the product itself. Partition coefficient: n-octanol/water : not determined Components:

No data is available on the product itself regarding bioaccumulation; partition coefficient is not determined.

12.3 Bioaccumulative potential

bis(nonylphenyl)amine : 18 / 40 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 D122727 Infineum Version 5.0 Revision Date 11.12.2017 Print Date 12.12.2017 Bioaccumulation : Accumulation in aquatic organisms is expected. Partition coefficient: n-octanol/water : log Pow: > 7,6

12.3 Bioaccumulative potential

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Bioaccumulation : Test substance: Read-across (Analogy) Due to the distribution coefficient n-octanol/water, accumulation in organisms is not expected. Partition coefficient: n-octanol/water : log Pow: 0,56

12.4 Mobility in soil

Product: Mobility : No data is available on the product itself. Components: bis(nonylphenyl)amine : Mobility : After release, adsorbs onto soil. Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Mobility : After release, adsorbs onto soil.

12.5 Results of PBT and vPvB assessment

Product: Assessment : No data is available on the product itself. This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Components: bis(nonylphenyl)amine : Assessment : This substance is not considered to be persistent, bioaccumulating and toxic (PBT)., This substance is not considered to be very persistent and very bioaccumulating (vPvB). Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Assessment : This substance is not considered to be persistent, bioaccumulating and toxic (PBT)., This substance is not considered to be very persistent and very bioaccumulating (vPvB).

The product contains no components considered to be PBT or vPvB at levels of 0.1% or higher. Both listed components are assessed as not being PBT or vPvB.

12.6 Other adverse effects

Product: Additional ecological information : None known.

None known.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of contents/ container to an approved waste disposal plant.

Disposal

Disposal recommendations based on material as supplied, Disposal must be in accordance with applicable laws and regulations, and material characteristics at time of disposal

Waste Codes

13 02 XX waste engine, gear and lubricating oils EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Risk classification according to VbF: Exempt. Major Accident Hazard: 2012/18/EU. Legislation: Not applicable.

Chemical Safety Assessment Not performed

To import this product into the EU your company requires registrations and/or pre-registrations for all constituent substances that are subject to REACH registration.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for D122727?

The signal word is no signal word.

What is the physical form of D122727?

D122727 is a liquid with brown color. It has hydrocarbon-like odor.

What is D122727 used for?

Additive for car engine lubricating oil

What are the hazard statements for D122727?

This substance has 1 hazard statement:

  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of D122727?

The melting point is not determined and the boiling point is not determined.