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Safety Data Sheet EN

B105151

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
B105151

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Automotive gear oil additive

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P391 Collect spillage.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Mineral oil --- 20 - 50% Yes
zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC: 224-235-5 --- 10 - 20% Yes
Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14-tert-alkyl EC: 931-384-6 --- 10 - 20% Yes
Dibutyl phosphonate EC: 217-316-1 --- 5.95 - 10% Yes
Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC: 253-249-4 --- 1 - 5% Yes
C14-18 alpha-olefin epoxide, reaction products with boric acid EC: 939-580-3 --- 1 - 5% Yes
Triphenyl phosphite EC: 202-908-4 --- 1 - 2.5% Yes
O,O,O-triphenylphosphorothioate EC: 209-909-9 --- 0.1 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. Wash with soap and water. If skin irritation or rash occurs: Get medical attention. If skin irritation occurs, get medical attention. Get medical attention if symptoms occur. Launder contaminated clothing before reuse.

Eye contact

Rinse cautiously with water for several minutes. Flush thoroughly with water. If irritation occurs, get medical assistance. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion

Rinse mouth. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Not determined.

Specific hazards

Vapors may cause a flash fire or ignite explosively. Prevent buildup of vapors or gases to explosive concentrations. Vapors may travel considerable distance to a source of ignition and flash back. Water may cause splattering. Container may rupture on heating. See section 10 for additional information.

Instructions

Move containers from fire area if you can do so without risk.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away. Prevent further leakage or spillage if safe to do so. Stop the flow of material, if this is without risk.

Environmental

Avoid release to the environment.

Cleanup methods

Pick up free liquid for recycle and/or disposal.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse. Avoid environmental contamination. In case of spills, beware of slippery floors and surfaces. Use grounding and bonding connection when transferring material. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures. Keep container closed when not in use and use with adequate ventilation. Avoid inhalation of vapors upon opening container. Vapours are heavier than air and will tend to accumulate in low areas. Avoid use in confined areas without adequate ventilation.

Storage

Keep cool. Store in a well-ventilated place. Store away from incompatible materials. Do not store near potential sources of ignition.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use grounding and bonding connection when transferring material. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures. Do not store near potential sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air. Vapors are heavier than air and will tend to accumulate in low areas. Avoid use in confined areas without adequate ventilation. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Chemical resistant gloves Gloves should always be inspected before each use and discarded if they show tears, pinholes, or signs of wear. Gloves are recommended when handling this material. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. Eye protection should meet the standards set out in EN 166.

Respiratory

A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Use respirator with an organic vapor and dust/mist cartridge if the recommended exposure limit is exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites.

Skin/Body

Wear apron or protective clothing in case of contact. Do not wear rings, watches or similar apparel that could entrap the material.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Dark
Colour
Dark
Colour Intensity
---
Form
liquid
Odor
Mild
Odor Threshold
No data available.
Ph
No data available.
Melting Point
---
Boiling Point
No data available.
Flash Point
81 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
No data available.
Relative Density
1.025 - 1.055 (15.6 °C)
Bulk Density
---
Density
---
Flammability
No data available.
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
110 mm2/s (40 °C); 12 mm2/s (100 °C )
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Heat, sparks, flames.

Incompatible

Contact with acids. Strong oxidizing agents.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide , sulfur oxides, mercaptans, sulfides, including hydrogen sulfide and other products of incomplete combustion. Thermal decompositon may generate phosphorus oxides and other phosphorus containing compounds.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity Fish

Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) LC 50 (Rainbow Trout, 4 d): 4.4 mg/l NOEC (Rainbow Trout, 4 d): 3.2 mg/l Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl LC 50 (Rainbow Trout, 4 Days): 24 mg/l NOEC (Rainbow Trout, 4 Days): 3.2 mg/l LC 50 (Fathead Minnow, 4 Days): 8.5 mg/l Dibutyl phosphonate LC 50 (Zebra Fish, 96 h): 63.4 mg/l Reaction products of Benzeneamine, N-phenyl- with nonene (branched) LC 50 (Zebra Fish, 4 d): > 100 mg/l C14-18 alpha-olefin epoxide, reaction products with boric acid LC 50 (Rainbow Trout, 4 d): > 100 mg/l O,O,O-triphenyl phosphorothioate LC 50 (Zebra Fish, 4 d): > 100 mg/l No toxicity at solubility limit. Aquatic Invertebrates Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC 50 (Water flea (Daphnia magna), 2 d): 75 mg/l NOEC (Water flea (Daphnia magna), 2 d): 32 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 0.8 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.4 mg/l

12.1 Toxicity

Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl: EC 50 (Water flea (Daphnia magna), 2 d): 91.4 mg/l, EC 50 (Water flea (Daphnia magna), 21 d): 0.66 mg/l, NOEC (Water flea (Daphnia magna), 21 d): 0.12 mg/l, EC 50 (Green algae (selenastrum capricomutum), 4 Days): 6.4 mg/l, NOEC (Green algae (selenastrum capricomutum), 4 Days): 1.7 mg/l, EC 50 (Sludge, 0.1 Days): 2,433 mg/l. Dibutyl phosphonate: EC 50 (Water Flea (Daphnia Magna), 48 h): 20.8 mg/l, EC 50 (Algae (Pseudokirchneriella subcapitata), 72 h): 14.4 mg/l. Reaction products of Benzeneamine, N-phenyl- with nonene (branched): EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l, EC 50 (Green algae (Selenastrum capricornutum), 3 d): 600 mg/l, EC 50 (Sludge, 0.1 d): > 1,000 mg/l. C14-18 alpha-olefin epoxide, reaction products with boric acid: EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l, NOEC (Water flea (Daphnia magna), 2 d): 100 mg/l, EC 50 (Water flea (Daphnia magna), 21 d): 20 mg/l, NOEC (Water flea (Daphnia magna), 21 d): 10 mg/l, EC 50 (Green algae (selenastrum capricomutum), 3 d): > 100 mg/l, EC 50 (Sludge, 0.1 d): > 10,000 mg/l. Triphenyl phosphite: EC 50 (Water flea (Daphnia magna), 2 d): 0.94 mg/l. O,O,O-triphenyl phosphorothioate: EC 50 (Water Flea (Daphnia Magna), 2 d): > 100 mg/l, NOEC (Water Flea (Daphnia Magna), 21 d): > 5.5 mg/l, EC 50 (Green algae (Scenedesmus quadricauda), 3 d): > 100 mg/l, EC 50 (Sludge, 3 h): > 100 mg/l. Mineral oil: EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l. zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate): EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 410 mg/l, NOEC (Green algae (Scenedesmus quadricauda), 3 d): 220 mg/l, EC 50 (Pseudomonas putida, 0.1 d): 380 mg/l.

12.2 Persistence and Degradability Biodegradation

Mineral oil: OECD TG 301 B, 31 %, 28 d, Not readily degradable. zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate): OECD TG 301 D, < 5 %, 28 d, Not readily degradable. Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl: Inherent Sludge, 3.6 %, 28 d, Not readily degradable; OECD TG 301 B, 7.4 %, 28 d, Not readily degradable. Reaction products of Benzeneamine, N-phenyl- with nonene (branched): OECD TG 301 B, 0 %, 28 d, Not readily degradable. C14-18 alpha-olefin epoxide, reaction products with boric acid: Miscellaneous, 17.3 %, 28 d, Not readily degradable; Miscellaneous, 26.7 %, 28 d, Not readily degradable. Triphenyl phosphite: OECD TG 301 D, 0.14 %, 28 d, Not readily degradable. O,O,O-triphenyl phosphorothioate: OECD TG 301 B, 17.8 - 19.3 %, 28 d, Not readily degradable; OECD TG 302 C, 59.9 - 66.8 %, 28 d.

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF): O,O,O-triphenyl phosphorothioate: Fish, Bioconcentration Factor (BCF): 2,551 (Flow Through). Partition Coefficient n-octanol / water (log Kow): zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate): Log Kow: 3.6 (Measured). Dibutyl phosphonate: Log Kow: estimated 1.81 25 °C.

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine disrupting properties

No data available

12.7 Other adverse effects

No data available

12.3 Bioaccumulative potential

Reaction products of Benzeneamine, N-phenyl- with nonene (branched) Log Kow: > 7 Experimental result, Weight of Evidence study C14-18 alpha-olefin epoxide, reaction products with boric acid, Log Kow: 9.4 (calculated) Triphenyl phosphite Log Kow: 6.62 25 °C (calculated)

12.4 Mobility:

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Other adverse effects

Product: Toxic to aquatic life with long lasting effects.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Zinc alkyldithiophosphate, Phosphoric acid esters/amine salt)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for B105151?

The signal word is warning.

What is the physical form of B105151?

B105151 is a liquid appearing as dark with dark color. It has mild odor.

What is B105151 used for?

Automotive gear oil additive

What are the hazard statements for B105151?

This substance has 3 hazard statements:

  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H411: Toxic to aquatic life with long lasting effects.