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Safety Data Sheet EN

ANGLAMOL® 2010

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ANGLAMOL® 2010

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Automotive gear oil additive

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

Emergency Contact

09.75.18.14.07

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Sens. Cat. 1 H317
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H304 May be fatal if swallowed and enters airways.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P331 Do NOT induce vomiting.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Polysulfides, di-tert-Bu EC: 273-103-3 --- 20 - 46% Yes
Dec-1-ene, homopolymer, hydrogenated Dec-1-ene, oligomers, hydrogenated EC: 500-183-1 --- 20 - 50% Yes
Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl EC: 931-384-6 --- 10 - 20% Yes
1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol EC: 293-927-7 --- 1 - 5% Yes
1H-Imidazole-1-ethanol, 2-(8-heptadecenyl)-4,5-dihydro- EC: 202-414-9 --- 0.25 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. If skin irritation or rash occurs: Get medical attention. Launder contaminated clothing before reuse.

Eye contact

Flush thoroughly with water. If irritation occurs, get medical assistance. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Do NOT induce vomiting. Aspiration of material due to vomiting can cause chemical pneumonitis which can be fatal. If vomiting occurs naturally, the casualty should lean forward to reduce the risk of aspiration. Rinse mouth. Immediately call a POISON CENTER/doctor.

Immediate Medical Attention

If irritation occurs, get medical assistance. If skin irritation or rash occurs: Get medical attention. Immediately call a POISON CENTER/doctor.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

Vapors may cause a flash fire or ignite explosively. Prevent buildup of vapors or gases to explosive concentrations. Vapors may travel considerable distance to a source of ignition and flash back. Water may cause splattering. Container may rupture on heating. Material creates a special hazard because it floats on water. See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse. Avoid environmental contamination.

Storage

Keep cool. Store in a well-ventilated place. Do not store above 113 deg F (45 deg C) for extended periods of time.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Chemical resistant gloves. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. For tasks involving thermal hazards, the standards set out in EN 407 should be considered. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. Eye protection should meet the standards set out in EN 166.

Respiratory

A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Under normal use conditions, respirator is not usually required. Use appropriate respiratory protection if exposure to dust particles, mist or vapors is likely. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Wear apron or protective clothing in case of contact. Do not wear rings, watches or similar apparel that could entrap the material.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Amber
Colour Intensity
---
Form
liquid
Odor
Strong
Odor Threshold
No data available.
Ph
No data available.
Melting Point
---
Boiling Point
No data available.
Flash Point
88 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
-53 °C
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
0.0594 PSI (76.67 °C)
Vapor Density
---
Relative Density
0.932 - 0.972 (15.6 °C)
Bulk Density
7.93 lb/gal (25 °C)
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
16.5 mm2/s (40 °C); 3.8 mm2/s (100 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Heat, sparks, flames.

Incompatible

Strong oxidizing agents.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, sulfur oxides, mercaptans, sulfides, including hydrogen sulfide and other products of incomplete combustion. Thermal decomposition may generate phosphorus oxides and other phosphorus containing compounds.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Fish Dec-1-ene, homopolymer, hydrogenated Dec-1-ene, oligomers, hydrogenated LC 50 (Rainbow Trout, 4 h): > 1,000 mg/l

12.1 Ecotoxicity

Fish Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl LC 50 (Rainbow Trout, 4 Days): 24 mg/l NOEC (Rainbow Trout, 4 Days): 3.2 mg/l LC 50 (Fathead Minnow, 4 Days): 8.5 mg/l

12.1 Ecotoxicity

### Fish LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l NOEC (Fathead Minnow, 4 d): 1,000 mg/l

12.1 Ecotoxicity

Fish LC 50 (Zebra Fish, 4 d): 0.3 mg/l

12.1 Toxicity

## Aquatic Invertebrates EC 50 (Water flea (Daphnia magna), 2 d): 63 mg/l EC 50 (Water flea (Daphnia magna), 2 d): > 1,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 125 mg/l NOEC (Water flea (Daphnia magna), 21 d): 125 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 91.4 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.66 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.12 mg/l

Aquatic Invertebrates

EC 50 (Water flea (Daphnia magna), 2 d): 41 mg/l NOEC (Water flea (Daphnia magna), 2 d): 32 mg/l EC 50 (Water flea (Daphnia Magna), 2 d): 0.163 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 0.34 mg/l

Toxicity to Aquatic Plants

Polysulfides, di-tert-Bu EC 50 (Alga, 3 d): > 100 mg/l EC 50 (Green algae (Scenedesmus quadricauda), 3 h): > 1,000 mg/l NOEC (Green algae (Scenedesmus quadricauda), 3 h): > 1,000 mg/l EC 50 (Green algae (selenastrum capricomutum), 4 Days): 6.4 mg/l NOEC (Green algae (selenastrum capricomutum), 4 Days): 1.7 mg/l

Toxicity to Aquatic Plants

NOEC (Green algae (Selenastrum capricornutum), 3 Days): 100 mg/l EC 50 (Green algae (Selenastrum capricornutum), 3 Days): > 100 mg/l NOEC (Alga, 3 d): 0.011 mg/l EC 50 (Alga, 3 d): 0.03 mg/l

Toxicity to microorganisms

Polysulfides, di-tert-Bu EC 50 (Sludge, 0.1 d): > 10,000 mg/l

Toxicity to microorganisms

Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl EC 50 (Sludge, 0.1 Days): 2,433 mg/l

12.1 Toxicity

Toxicity to microorganisms: 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol. EC 50 (Pseudomonas putida, 0.7 Days): > 8,000 mg/l

Toxicity

1H-Imidazole-1-ethanol, 2-(8-heptadecenyl)-4,5-dihydro- EC 50 (Sludge, 0.1 d): 26 mg/l

12.2 Persistence and Degradability

Biodegradation

12.2 Persistence and Degradability

Biodegradation Polysulfides, di-tert-Bu Carbon dioxide generation 13 % (28 d, OECD TG 301 B)

12.2 Persistence and Degradability

Dec-1-ene, homopolymer, hydrogenated Dec-1-ene, oligomers, hydrogenated Oxygen depletion 2 % (28 d, OECD TG 301 D)

12.2 Persistence and Degradability

## Biodegradation Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl Dissolved organic carbon (DOC) 3.6 % (28 d, Inherent Sludge) Carbon dioxide generation 7.4 % (28 d, OECD TG 301 B)

12.2 Persistence and Degradability

Biodegradation 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol Oxygen depletion 2 % (28 d, OECD TG 301 C)

12.2 Persistence and Degradability

Biodegradation 1H-Imidazole-1-ethanol, 2-(8-heptadecenyl)-4,5-dihydro- Carbon dioxide generation 1 % (28 d, OECD TG 301 B)

12.2 Persistence and degradability

BOD/COD Ratio No data available

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF) No data available Partition Coefficient n-octanol / water (log Kow)

12.3 Bioaccumulative Potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow)

Polysulfides, di-tert-Bu Log Kow: 6 (Measured)

12.3 Bioaccumulative Potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow)

Dec-1-ene, homopolymer, hydrogenated Dec-1-ene, oligomers, hydrogenated Log Kow: > 6.5 20 °C (Measured)

12.3 Bioaccumulative Potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow)

1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol Log Kow: 9.4 (Measured)

12.3 Bioaccumulative Potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow)

1H-Imidazole-1-ethanol, 2-(8-heptadecenyl)-4,5-dihydro- Log Kow: > 7

12.4 Mobility:

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Other Adverse Effects:

No data available.

No data available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

All components are in compliance with chemical notification requirements in their respective regions.

Chemical Safety Assessment Not performed

The information that was used to confirm the compliance status of this product may deviate from the chemical information shown in Section 3.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for ANGLAMOL® 2010?

The signal word is danger.

What is the physical form of ANGLAMOL® 2010?

ANGLAMOL® 2010 is a liquid with amber color. It has strong odor.

What is ANGLAMOL® 2010 used for?

Automotive gear oil additive

What are the hazard statements for ANGLAMOL® 2010?

This substance has 3 hazard statements:

  • H304: May be fatal if swallowed and enters airways.
  • H317: May cause an allergic skin reaction.
  • H412: Harmful to aquatic life with long lasting effects.