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Safety Data Sheet EN

ANGLAMOL® 2000

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ANGLAMOL® 2000

Regulatory Identifiers

CAS Number
N/A
UFI Code
P6VS-64ED-K00U-1NDT

Identified Uses

Automotive gear oil additive

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

Emergency Contact

0858880596

National Vergiftigingen Informatie Centrum (NVIC)

(+31) 030 274 8888

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Sens. Cat. 1 H317
Persistent, bioaccumulative and toxic EUH440
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Polysulfides, di-tert-Bu EC: 273-103-3 --- 20 - 46% Yes
Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl EC: 931-384-6 --- 10 - 20% Yes
Mineral oil --- 10 - 20% Yes
O,O,O-triphenyl phosphorothioate EC: 209-909-9 --- 2.5 - 5% Yes
Magnesium metaborate EC: 237-235-5 --- 1 - 5% Yes
1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol EC: 293-927-7 --- 1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. Wash with soap and water. Launder contaminated clothing before reuse.

Eye contact

Flush thoroughly with water. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Rinse mouth.

Immediate Medical Attention

If irritation occurs, get medical assistance (Eye contact). If skin irritation or rash occurs, get medical attention. Get medical attention if symptoms occur (Ingestion).

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

Vapors may cause a flash fire or ignite explosively. Prevent buildup of vapors or gases to explosive concentrations. Vapors may travel considerable distance to a source of ignition and flash back. Container may rupture on heating. Material creates a special hazard because it floats on water. See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse. Avoid environmental contamination.

Storage

Keep cool. Store in a well-ventilated place. Store away from incompatible materials. Do not store near potential sources of ignition. Do not store in open, unlabeled or mislabeled containers.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No special requirements under ordinary conditions of use and with adequate ventilation. Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Chemical resistant gloves. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. Eye protection should meet the standards set out in EN 166.

Respiratory

Under normal use conditions, respirator is not usually required. Use appropriate respiratory protection if exposure to dust particles, mist or vapors is likely. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Wear apron or protective clothing in case of contact. Do not wear rings, watches or similar apparel that could entrap the material. Chemical resistant boots.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Dark
Colour
Dark
Colour Intensity
---
Form
liquid
Odor
Strong
Odor Threshold
No data available.
Ph
Not applicable
Melting Point
---
Boiling Point
No data available.
Flash Point
78 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
0.0531 PSI (76.67 °C)
Vapor Density
---
Relative Density
0.99 - 1.03 (15.6 °C)
Bulk Density
8.41 lb/gal (25 °C)
Density
---
Flammability
No data available.
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
49 mm2/s (40 °C); 97 mm2/s (25 °C) 8.8 mm2/s (100 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Heat, sparks, flames.

Incompatible

Strong oxidizing agents.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, sulfur oxides, mercaptans, sulfides, including hydrogen sulfide and other products of incomplete combustion. Thermal decomposition may generate phosphorus oxides and other phosphorus containing compounds.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

### Fish Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl LC 50 (Rainbow Trout, 4 Days): 24 mg/l LC 50 (Fathead Minnow, 4 Days): 8.5 mg/l

12.1 Toxicity

Fish Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Toxicity

Fish O,O,O-triphenyl phosphorothioate LC 50 (Zebra Fish, 4 d): > 100 mg/l No toxicity at solubility limit. NOEC (Rainbow Trout, 97 d): 0.0017 mg/l

12.1 Toxicity

Fish 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l

12.1 Toxicity

### Aquatic Invertebrates Polysulfides, di-tert-Bu EC 50 (Water flea (Daphnia magna), 2 d): 63 mg/l

12.1 Toxicity

Aquatic Invertebrates Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl EC 50 (Water flea (Daphnia magna), 2 d): 91.4 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.66 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.12 mg/l

12.1 Toxicity

Aquatic Invertebrates Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Toxicity

Aquatic Invertebrates O,O,O-triphenyl phosphorothioate EC 50 (Water Flea (Daphnia Magna), 2 d): > 100 mg/l No toxicity at solubility limit. NOEC (Water Flea (Daphnia Magna), 21 d): > 5.5 mg/l No toxicity at solubility limit.

12.1 Toxicity

Aquatic Invertebrates 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol EC 50 (Water flea (Daphnia magna), 2 d): 41 mg/l

12.1 Toxicity

EC 50 (Alga, 3 d): > 100 mg/l

12.2 Persistence and degradability

Not available

12.3 Bioaccumulative potential

Not available

12.4 Mobility in soil

Not available

12.5 Results of PBT and vPvB assessment

Not available

12.6 Endocrine disrupting properties

Not available

12.7 Other adverse effects

Not available

Toxicity to Aquatic Plants

Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl EC 50 (Green algae (selenastrum capricomutum), 4 Days): 6.4 mg/l NOEC (Green algae (selenastrum capricomutum), 4 Days): 1.7 mg/l

Toxicity

EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

Toxicity to Aquatic Plants

O,O,O-triphenyl phosphorothioate EC 50 (Green algae (Scenedesmus quadricauda), 3 d): > 100 mg/l

Toxicity to Aquatic Plants

1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol NOEC (Green algae (Selenastrum capricornutum), 3 Days): 100 mg/l EC 50 (Green algae (Selenastrum capricornutum), 3 Days): > 100 mg/l

Toxicity to microorganisms

EC 50 (Sludge, 0.1 d): > 10,000 mg/l

Toxicity

Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl EC 50 (Sludge, 0.1 Days): 2,433 mg/l

12.1 Toxicity

O,O,O-triphenyl phosphorothioate EC 50 (Sludge, 3 h): > 100 mg/l

Toxicity

1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol EC 50 (Pseudomonas putida, 0.7 Days): > 8,000 mg/l

12.2 Persistence and Degradability

Biodegradation Polysulfides, di-tert-Bu OECD TG 301 B, 13 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation **Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl** **Inherent Sludge, 3.6 %, 28 d, Not readily degradable.** OECD TG 301 B, 7.4 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation **Mineral oil** OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation **O,O,O-triphenyl phosphorothioate** OECD TG 301 B, 17.8 - 19.3 %, 28 d, Not readily degradable. OECD TG 302 C, 59.9 - 66.8 %, 28 d

12.2 Persistence and Degradability

Biodegradation 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol OECD TG 301 C, 2 %, 28 d, Not readily degradable.

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF) No data available

No data available

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF) O,O,O-triphenyl phosphorothioate Fish, Bioconcentration Factor (BCF): 2,551 (Flow Through)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) **Polysulfides, di-tert-Bu** Log Kow: 6 (Measured)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol Log Kow: 9.4 (Measured)

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

Product: This substance/mixture contains components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB). O,O,O-triphenyl phosphorothioate PBT: persistent, bioaccumulative and toxic substance.

12.6 Endocrine disrupting properties:

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

Product: Harmful to aquatic organisms. Very toxic to aquatic life with long lasting effects.

The product is classified as harmful to aquatic organisms and very toxic to aquatic life with long lasting effects.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

The information that was used to confirm the compliance status of this product may deviate from the chemical information shown in Section 3.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for ANGLAMOL® 2000?

The signal word is danger.

What is the physical form of ANGLAMOL® 2000?

ANGLAMOL® 2000 is a liquid appearing as dark with dark color. It has strong odor.

What is ANGLAMOL® 2000 used for?

Automotive gear oil additive

What are the hazard statements for ANGLAMOL® 2000?

This substance has 2 hazard statements:

  • H317: May cause an allergic skin reaction.
  • H410: Very toxic to aquatic life with long lasting effects.