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Safety Data Sheet EN

GA 3064

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
GA 3064

Regulatory Identifiers

CAS Number
N/A
UFI Code
282W-84XH-100X-DKV8

Identified Uses

Marine Diesel Engine

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H317 May cause an allergic skin reaction.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/ container to an approved facility in accordance with local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Mineral oil --- 20 - 50% Yes
Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts EC: 947-519-7 --- 10 - 20% Yes
zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC: 224-235-5 --- 1 - 3% Yes
Phenol, dodecyl-, branched EC: 310-154-3 --- 0.1 - 0.3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Wash skin thoroughly with soap and water. Wash with soap and water. If skin irritation or rash occurs: Get medical attention. Get medical attention if symptoms occur. Launder contaminated clothing before reuse.

Eye contact

Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses.

Ingestion

Treat symptomatically. Get medical attention.

Immediate Medical Attention

Get medical attention if symptoms occur. Get medical attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Not determined.

Specific hazards

See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

In case of spills, beware of slippery floors and surfaces. Use grounding and bonding connection when transferring material. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures. Keep container closed when not in use and use with adequate ventilation. Avoid inhalation of vapors upon opening container. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse.

Storage

Store away from incompatible materials. Do not store product at temperature in excess of 45°C (113°F) for extended periods of time, 1 week or more; or, using a heat source, such as steam, at a temperature in excess of 100°C (212°F).

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse.

Fire prevention

Use grounding and bonding connection when transferring material. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No special requirements under ordinary conditions of use and with adequate ventilation. Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air. Use material in well ventilated area only.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Gloves are recommended when handling this material. Unless material is used in a process where the use of gloves would pose sufficient risk of injury to the user/operator. Consult with an industrial hygienist to determine the appropriate clothing protection for your specific use of this material. Gloves should always be inspected before each use and discarded if they show tears, pinholes, or signs of wear. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered.

Eyes

If contact is likely, safety glasses with side shields are recommended. Eye protection should meet the standards set out in EN 166.

Respiratory

Consult with an industrial hygienist to determine the appropriate respiratory protection for your specific use of this material. A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Use disposable dust/mist mask if the recommended exposure limit is exceeded. Use respirator with an organic vapor cartridge if exposure limit is exceeded. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Gloves, coveralls, apron, boots as necessary to minimize contact. Do not wear rings, watches or similar apparel that could entrap the material. Chemical resistant boots.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Dark amber
Colour Intensity
---
Form
liquid
Odor
Characteristic
Odor Threshold
No data available.
Ph
Not applicable
Melting Point
---
Boiling Point
No data available.
Flash Point
145 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
---
Relative Density
1.023 (15.6 °C)
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
1100 mm2/s (40 °C);
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Excessive heat, ignition sources

Incompatible

oxidizing materials

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, sulfur oxides, mercaptans, sulfides, including hydrogen sulfide and other products of incomplete combustion.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

### Fish Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Toxicity

Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts LC 50 (Rainbow Trout, 96 h): > 100.1 mg/l LC 50 (Fathead Minnow, 96 h): > 1,000 mg/l LC 50 (Sheepshead Minnow, 96 h): > 10,000 mg/l

12.1 Toxicity

### Fish zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) LC 50 (Rainbow Trout, 4 d): 4.4 mg/l

12.1 Toxicity

### Fish Phenol, dodecyl-, branched LC 50 (Fathead Minnow, 4 d): 40 mg/l

12.1 Toxicity

Aquatic Invertebrates Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Toxicity

### Aquatic Invertebrates Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l

12.1 Toxicity

Aquatic Invertebrates zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC 50 (Water flea (Daphnia magna), 2 d): 75 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 0.8 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.4 mg/l

12.1 Toxicity

Aquatic Invertebrates Phenol, dodecyl-, branched EC 50 (Water flea (Daphnia magna), 2 d): 0.037 mg/l EC 50 (Shrimp (Mysidopsis Bahia), 4 d): > 0.58 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.0079 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.0037 mg/l

12.1 Toxicity

### Toxicity to Aquatic Plants Mineral oil EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Toxicity

### Toxicity to Aquatic Plants Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 410 mg/l NOEC (Green algae (Scenedesmus quadricauda), 3 d): 220 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants Phenol, dodecyl-, branched EC 50 (Green algae (Scenedesmus quadricauda), 72 h): 0.36 mg/l

12.1 Toxicity

Toxicity to microorganisms Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts EC 50 (Sludge, 0.1 d): > 10,000 mg/l

12.1 Toxicity

Toxicity to microorganisms zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC 50 (Pseudomonas putida, 0.1 d): 380 mg/l

12.1 Toxicity

**Toxicity to microorganisms** Phenol, dodecyl-, branched EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.2 Persistence and Degradability

Biodegradation

12.2 Persistence and Degradability

Biodegradation Mineral oil OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts OECD TG 301 D, 8 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) OECD TG 301 D, < 5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Phenol, dodecyl-, branched Miscellaneous, 10 %, 56 d, Not readily degradable. OECD TG 301 B, 25 %, 28 d, Not readily degradable.

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF): 794.33 (Measured)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) Reaction products of benzenesulfonic acid, mono-C20-24 (even)-sec-alkyl derivs. para-, calcium salts Log Kow: 10.88 (Read across)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) Log Kow: 3.6 (Measured)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) Phenol, dodecyl-, branched Log Kow: 7.14 (Measured)

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties:

Product: This substance/mixture contains components considered to have endocrine disrupting properties for environment, according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. Phenol, dodecyl-, branched The substance is considered to have endocrine disrupting properties according to REACH Article 57(f) for the environment.

The product contains components with endocrine disrupting properties for the environment, specifically Phenol, dodecyl-, branched.

12.7 Other adverse effects

No data available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for GA 3064?

The signal word is warning.

What is the physical form of GA 3064?

GA 3064 is a liquid with dark amber color. It has characteristic odor.

What is GA 3064 used for?

Marine Diesel Engine

What are the hazard statements for GA 3064?

This substance has 1 hazard statement:

  • H317: May cause an allergic skin reaction.