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Safety Data Sheet EN

LUBRIZOL® MF9143CK

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LUBRIZOL® MF9143CK

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Research and Development

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

Emergency Contact

09.75.18.14.07

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H335
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash face, hands and any exposed skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
P331 Do NOT induce vomiting.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/ container to an approved facility in accordance with local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, less than 2% aromatics EC: 918-481-9 --- 20 - 50% Yes
2-Ethylhexan-1-ol EC: 203-234-3 --- 20 - 50% Yes
2-Ethylhexyl nitrate EC: 248-363-6 --- 10 - 20% Yes
Octamethylcyclotetrasiloxane EC: 209-136-7 --- 0.01 - 0.1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air and keep at rest in a position comfortable for breathing.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water.

Eye contact

Rinse cautiously with water for several minutes. Flush thoroughly with water. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Do NOT induce vomiting. If vomiting occurs naturally, the casualty should lean forward to reduce the risk of aspiration. Rinse mouth. Immediately call a POISON CENTER or doctor/ physician.

Symptoms: Aspiration of material due to vomiting can cause chemical pneumonitis which can be fatal.

Immediate Medical Attention

If irritation occurs, get medical assistance. If eye irritation persists: Get medical advice/attention. If skin irritation occurs, get medical attention. Get medical attention if symptoms occur. Immediately call a POISON CENTER or doctor/ physician.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

Vapors may cause a flash fire or ignite explosively. Prevent buildup of vapors or gases to explosive concentrations. Vapors may travel considerable distance to a source of ignition and flash back. Water may cause splattering. Container may rupture on heating. Material creates a special hazard because it floats on water. See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ventilate closed spaces before entering them. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep upwind. Keep unauthorized personnel away.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin. Avoid contact with eyes. Observe good industrial hygiene practices. Use only in well-ventilated areas. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Launder contaminated clothing before reuse. Avoid environmental contamination.

Storage

Keep cool. Store in a well-ventilated place. Store away from incompatible materials. See section 10 for incompatible materials. Do not store near potential sources of ignition.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Launder contaminated clothing before reuse.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use grounding and bonding connection when transferring material. Static ignition hazard can result from handling and use. Electrically bond and ground all containers and equipment before transfer or use of material. Always transfer product by means which avoid static buildup.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No special requirements under ordinary conditions of use and with adequate ventilation. Adequate ventilation should be provided so that exposure limits are not exceeded. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Chemical resistant gloves. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm. Glove selection should also be based on consideration of the task requirements and knowledge of breakthrough times.

Eyes

Wear tight-fitting goggles or face shield. Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. Eye protection should meet the standards set out in EN 166.

Respiratory

Use respirator with an organic vapor and dust/mist cartridge if the recommended exposure limit is exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Wear apron or protective clothing in case of contact. Do not wear rings, watches or similar apparel that could entrap the material. Gloves, coveralls, apron, boots as necessary to minimize contact.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid
Colour
Amber
Colour Intensity
---
Form
liquid
Odor
Characteristic
Odor Threshold
No data available.
Ph
Not applicable
Melting Point
---
Boiling Point
No data available.
Flash Point
62 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
---
Relative Density
0.858 (15.6 °C)
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
---
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
8.9 mm2/s (40 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Heat, sparks, flames. Do not expose to excessive heat, ignition sources. Excessive heat.

Incompatible

oxidizing materials, strong caustic agents, acids

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, and other products of incomplete combustion.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Aquatic Invertebrates Octamethylcyclotetrasiloxane NOEC (Water flea (Daphnia magna), 21 d): 0.0079 mg/l

Toxicity to Aquatic Plants

2-Ethylhexan-1-ol EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 16.6 mg/l

Toxicity to Aquatic Plants

2-Ethylhexyl nitrate EC 50 (Alga, 72 h): > 2.53 mg/l EC 10 (Alga, 72 h): 2.22 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants Octamethylcyclotetrasiloxane NOEC (Alga, 96 h): < 0.022 mg/l

Toxicity

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, less than 2% aromatics EC 50 (Algae (Pseudokirchneriella subcapitata), 72 h): > 1,000 mg/l

Persistence and degradability

Bioaccumulative potential

Mobility in soil

Results of PBT and vPvB assessment

Endocrine disrupting properties

Other adverse effects

12.1 Toxicity

2-Ethylhexan-1-ol EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 16.6 mg/l

Toxicity to Aquatic Plants

2-Ethylhexyl nitrate EC 50 (Alga, 72 h): > 2.53 mg/l EC 10 (Alga, 72 h): 2.22 mg/l

Toxicity to Aquatic Plants

Octamethylcyclotetrasiloxane NOEC (Alga, 96 h): < 0.022 mg/l

Toxicity to microorganisms

2-Ethylhexan-1-ol EC 50 (Pseudomonas putida, 0.1 d): 540 mg/l EC 50 (Sludge, 0.5 d): > 100 mg/l

Toxicity

2-Ethylhexyl nitrate EC 50 (Sludge, 0.3 d): > 1,000 mg/l

12.1 Toxicity

2-Ethylhexan-1-ol EC 50 (Pseudomonas putida, 0.1 d): 540 mg/l EC 50 (Sludge, 0.5 d): > 100 mg/l

Toxicity

2-Ethylhexyl nitrate EC 50 (Sludge, 0.3 d): > 1,000 mg/l

12.2 Persistence and Degradability

### Biodegradation

12.2 Persistence and Degradability

### Biodegradation Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, less than 2% aromatics OECD TG 301 F, 80 %, 28 d, Readily biodegradable

12.2 Persistence and Degradability

Biodegradation 2-Ethylhexan-1-ol OECD TG 302 B, 95 %, 5 d, Readily biodegradable OECD TG 301 C, 100 %, 14 d, Readily biodegradable

12.2 Persistence and Degradability

2-Ethylhexyl nitrate Miscellaneous, 0 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Octamethylcyclotetrasiloxane Miscellaneous, 3.7 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, less than 2% aromatics OECD TG 301 F, 80 %, 28 d, Readily biodegradable

12.2 Persistence and Degradability

### Biodegradation 2-Ethylhexan-1-ol OECD TG 302 B, 95 %, 5 d, Readily biodegradable OECD TG 301 C, 100 %, 14 d, Readily biodegradable

12.2 Persistence and Degradability

2-Ethylhexyl nitrate Miscellaneous, 0 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation Octamethylcyclotetrasiloxane Miscellaneous, 3.7 %, 28 d, Not readily degradable.

12.2 Persistence and degradability

BOD/COD Ratio: No data available

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF)

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF): 25.35 (calculated)

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF) Octamethylcyclotetrasiloxane Bioconcentration Factor (BCF): 12,302.69 (Measured)

12.3 Bioaccumulative potential

### Bioconcentration Factor (BCF) 2-Ethylhexan-1-ol Bioconcentration Factor (BCF): 25.35 (calculated)

12.3 Bioaccumulative potential

### Bioconcentration Factor (BCF) Octamethylcyclotetrasiloxane Bioconcentration Factor (BCF): 12,302.69 (Measured)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) 2-Ethylhexan-1-ol Log Kow: 2.9 (Measured)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) 2-Ethylhexyl nitrate Log Kow: 5.24 (Measured)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) Octamethylcyclotetrasiloxane Log Kow: 6.488 (Measured)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) 2-Ethylhexan-1-ol Log Kow: 2.9 (Measured)

Toxicity to Aquatic Plants

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, less than 2% aromatics EC 50 (Algae (Pseudokirchneriella subcapitata), 72 h): > 1,000 mg/l

12.1 Ecotoxicity

Fish Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, less than 2% aromatics LL 50 (Oncorhynchus mykiss, 96 h): > 1,000 mg/l

12.1 Ecotoxicity

Fish 2-Ethylhexan-1-ol LC 50 (Fathead Minnow, 4 d): 28.2 mg/l LC 50 (Golden Orfe, 4 d): 17.1 mg/l

12.1 Ecotoxicity

Fish 2-Ethylhexyl nitrate LC 50 (Zebra Fish, 4 d): 2 mg/l

12.1 Ecotoxicity

Fish Octamethylcyclotetrasiloxane NOEC (Rainbow Trout, 14 d): 0.0044 mg/l

12.1 Ecotoxicity

Fish Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, less than 2% aromatics LL 50 (Oncorhynchus mykiss, 96 h): > 1,000 mg/l

12.1 Ecotoxicity

Fish 2-Ethylhexan-1-ol LC 50 (Fathead Minnow, 4 d): 28.2 mg/l LC 50 (Golden Orfe, 4 d): 17.1 mg/l

12.1 Ecotoxicity

Fish 2-Ethylhexyl nitrate LC 50 (Zebra Fish, 4 d): 2 mg/l

12.1 Ecotoxicity

Fish Octamethylcyclotetrasiloxane NOEC (Rainbow Trout, 14 d): 0.0044 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, less than 2% aromatics EC 50 (Water Flea (Daphnia Magna), 48 h): > 1,000 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates 2-Ethylhexan-1-ol EC 50 (Water flea (Daphnia magna), 2 d): 39 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates 2-Ethylhexyl nitrate EC 50 (Water flea (Daphnia magna), 48 h): 0.83 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Octamethylcyclotetrasiloxane NOEC (Water flea (Daphnia magna), 21 d): 0.0079 mg/l

12.1 Ecotoxicity

#### Aquatic Invertebrates Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, less than 2% aromatics EC 50 (Water Flea (Daphnia Magna), 48 h): > 1,000 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates 2-Ethylhexan-1-ol EC 50 (Water flea (Daphnia magna), 2 d): 39 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates 2-Ethylhexyl nitrate EC 50 (Water flea (Daphnia magna), 48 h): 0.83 mg/l

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) 2-Ethylhexyl nitrate Log Kow: 5.24 (Measured)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) Octamethylcyclotetrasiloxane Log Kow: 6.488 (Measured)

12.4 Mobility:

2-Ethylhexan-1-ol soil - 1.42 2-Ethylhexyl nitrate soil - 3.75 2-Ethylhexan-1-ol soil - 1.42 2-Ethylhexyl nitrate soil - 3.75

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine Disruption:

Product: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

Product: Harmful to aquatic life with long lasting effects.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(2-Ethylhexanol, 2-Ethylhexyl nitrate)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LUBRIZOL® MF9143CK?

The signal word is danger.

What is the physical form of LUBRIZOL® MF9143CK?

LUBRIZOL® MF9143CK is a liquid appearing as liquid with amber color. It has characteristic odor.

What is LUBRIZOL® MF9143CK used for?

Research and Development

What are the hazard statements for LUBRIZOL® MF9143CK?

This substance has 6 hazard statements:

  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H411: Toxic to aquatic life with long lasting effects.