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Safety Data Sheet EN

0B20909

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
0B20909

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Automotive gear oil additive

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Sens. Cat. 1B H317
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P391 Collect spillage.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl EC: 931-384-6 --- 10 - 25% Yes
(Z)-octadec-9-enylamine, C16-18-(even numbered, saturated and unsaturated)-alkylamines EC: 627-034-4 --- 5 - 10% Yes
Reaction product of 1,3,4-thiadiazolidine-2,5-dithione, formaldehyde and phenol, heptyl derivs. EC: 939-460-0 --- 1 - 3% Yes
Phenol, heptyl derivatives EC: 276-743-1 --- 0.1 - 0.25% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Wash skin thoroughly with soap and water. Launder contaminated clothing before reuse.

Eye contact

Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses.

Ingestion

Treat symptomatically.

Immediate Medical Attention

If skin irritation or rash occurs: Get medical attention. Get medical attention (for ingestion).

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Not determined.

Specific hazards

Vapors may cause a flash fire or ignite explosively. Prevent buildup of vapors or gases to explosive concentrations. Vapors may travel considerable distance to a source of ignition and flash back. Water may cause splattering. Container may rupture on heating. See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Open container in a well ventilated area. Avoid breathing vapors. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Wear appropriate personal protective equipment.

Storage

Keep cool. Store in a well-ventilated place. Odorous and toxic fumes may form from decomposition if stored above 113 deg F (45 deg C) for extended periods of time.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air. Adequate ventilation should be provided so that exposure limits are not exceeded.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Chemical resistant gloves. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For short-term, transient exposures and splash protection, gloves with shorter breakthrough times may commonly be used. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. Eye protection should meet the standards set out in EN 166.

Respiratory

Consult with an industrial hygienist to determine the appropriate respiratory protection for your specific use of this material. A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Use respirator with a combination organic vapor and dust/mist cartridge. Use respirator with an organic vapor cartridge if exposure limit is exceeded. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Wear apron or protective clothing in case of contact. Do not wear rings, watches or similar apparel that could entrap the material.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Amber
Colour
Amber
Colour Intensity
---
Form
liquid
Odor
Slight mercaptan
Odor Threshold
No data available.
Ph
No data available.
Melting Point
---
Boiling Point
No data available.
Flash Point
63 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
0.0113 PSI (20 °C)
Vapor Density
No data available.
Relative Density
1.05 - 1.08 (15.6 °C)
Bulk Density
1,000 kg/m3
Density
---
Flammability
No data available.
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
0.95 lb/gal
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
68 mm2/s (40 °C); 8.2 mm2/s (100 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Heat, sparks, flames. Do not expose to excessive heat, ignition sources, or oxidizing materials.

Incompatible

oxidizing materials

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, sulfur oxides, mercaptans, sulfides, including hydrogen sulfide and other products of incomplete combustion. Thermal decomposition may generate phosphorus oxides and other phosphorus containing compounds.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Fish LC 50 (Rainbow Trout, 4 Days): 24 mg/l NOEC (Rainbow Trout, 4 Days): 3.2 mg/l LC 50 (Fathead Minnow, 4 Days): 8.5 mg/l

12.1 Ecotoxicity

### Fish LC 50 (Fathead Minnow, 4 d): 0.11 mg/l LC 50 (Rainbow Trout, 4 d): 1.3 mg/l LC 50 (Sheepshead Minnow, 4 d): 0.9 mg/l

12.1 Ecotoxicity

### Fish LC 50 (Fathead Minnow, 4 d): 40 mg/l

12.1 Ecotoxicity

Fish LC 50 (Rainbow Trout, 96 h): 2.4 mg/l

12.1 Toxicity

Aquatic Invertebrates EC 50 (Water flea (Daphnia magna), 2 d): 91.4 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.66 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.12 mg/l

12.1 Toxicity

Aquatic Invertebrates EC 50 (Water flea (Daphnia magna), 2 d): 0.011 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.27 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.013 mg/l

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

Aquatic Invertebrates EC 50 (Water flea (Daphnia magna), 2 d): 75 mg/l

12.1 Toxicity

EC 50 (Water flea (Daphnia magna), 48 h): 0.36 mg/l

Toxicity to Aquatic Plants

## Toxicity to Aquatic Plants EC 50 (Green algae (selenastrum capricomutum), 4 Days): 6.4 mg/l NOEC (Green algae (selenastrum capricomutum), 4 Days): 1.7 mg/l

Toxicity to Aquatic Plants

EC 50 (Alga, 3 d): > 0.13 mg/l

Toxicity to Aquatic Plants

EC 50 (Green algae (Selenastrum capricornutum), 4 d): 25 mg/l

Toxicity to Aquatic Plants

LC 50 (Green algae (Scenedesmus quadricauda), 72 h): 1.2 mg/l LC 50 (Green algae (Scenedesmus quadricauda), 72 h): 0.25 mg/l NOEC (Green algae (Scenedesmus quadricauda), 72 h): 0.048 mg/l

12.1 Toxicity

Toxicity to soil dwelling organisms No data available Sediment Toxicity No data available Toxicity to Terrestrial Plants No data available Toxicity to Above-Ground Organisms No data available Toxicity to microorganisms Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl

No data available for soil, sediment, terrestrial plants, or above-ground organisms. Substance identified for microorganism toxicity testing.

12.1 Toxicity

Toxicity to microorganisms: EC 50 (Sludge, 0.1 Days): 2,433 mg/l

Toxicity

Toxicity to microorganisms EC 50 (Sludge, 0.1 d): 15.5 mg/l

Toxicity to microorganisms

LC 50 (Sludge, 0.1 h): 58 mg/l

12.2 Persistence and Degradability

Biodegradation Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified with diphosphorus pentaoxide, and salted by amines, C12-14- tert-alkyl

12.2 Persistence and Degradability

## Biodegradation Dissolved organic carbon (DOC) 3.6 % (28 d, Inherent Sludge) Carbon dioxide generation 7.4 % (28 d, OECD TG 301 B)

12.2 Persistence and Degradability

Biodegradation Oxygen depletion 44 % (28 d, OECD TG 301 D) Carbon dioxide generation 66 % (28 d, OECD TG 301 B)

12.2 Persistence and Degradability

Biodegradation Dissolved organic carbon (DOC) 17.4 % (28 d, Miscellaneous)

12.2 Persistence and Degradability

Biodegradation Oxygen depletion 1.6 % (28 d, OECD TG 301 D) Carbon dioxide generation 25.4 % (28 d, OECD TG 301 B)

BOD/COD Ratio

No data available

12.3 Bioaccumulative Potential Bioconcentration Factor (BCF)

(Z)-octadec-9-enylamine, C16-18-(even numbered, saturated and unsaturated)-alkylamines

12.3 Bioaccumulative Potential Bioconcentration Factor (BCF)

Bioconcentration Factor (BCF): 500 (calculated)

12.3 Bioaccumulative Potential Bioconcentration Factor (BCF)

Phenol, heptyl derivatives Bioconcentration Factor (BCF): 549.5 (calculated)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) Log Kow: 4.33 25 °C

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) Log Kow: > 9.4 (calculated)

12.4 Mobility:

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Other Adverse Effects:

No data available.

No data available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Alkenyl amine, Phosphoric acid esters/amine salt)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Regulatory compliance status for the product across various international inventories and EU directives.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 0B20909?

The signal word is warning.

What is the physical form of 0B20909?

0B20909 is a liquid appearing as amber with amber color. It has slight mercaptan odor.

What is 0B20909 used for?

Automotive gear oil additive

What are the hazard statements for 0B20909?

This substance has 2 hazard statements:

  • H317: May cause an allergic skin reaction.
  • H410: Very toxic to aquatic life with long lasting effects.