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Safety Data Sheet EN

B003232

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
B003232

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Additive for Off-Highway.

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX. 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Sens. Cat. 1 H317
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P391 Collect spillage.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Mineral oil --- 20 - 50% Yes
zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC: 224-235-5 --- 10 - 25% Yes
C14-18 alpha-olefin epoxide, reaction products with boric acid EC: 939-580-3 --- 5 - 10% Yes
Triphenyl phosphite EC: 202-908-4 --- 1 - 2.5% Yes
O,O,O-triphenyl phosphorothioate EC: 209-909-9 --- 0.1 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. Wash with soap and water. Launder contaminated clothing before reuse.

Eye contact

Flush thoroughly with water. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Rinse mouth.

Immediate Medical Attention

If irritation occurs, get medical assistance (eyes). If skin irritation or rash occurs: Get medical attention. Get medical attention if symptoms occur (skin/ingestion).

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Not determined.

Specific hazards

See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse. Avoid environmental contamination.

Storage

Store away from incompatible materials. Odorous and toxic fumes may form from the decomposition of this product if stored at temperatures in excess of 113 deg F (45 deg C) for extended periods of time or if heat sources in excess of 250 deg F (121 deg C) are used.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse.

Fire prevention

Use grounding and bonding connection when transferring material. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Gloves should always be inspected before each use and discarded if they show tears, pinholes, or signs of wear. Chemical resistant gloves. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or >480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

If contact is likely, safety glasses with side shields are recommended. Eye protection should meet the standards set out in EN 166.

Respiratory

A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Under normal use conditions, respirator is not usually required. Use appropriate respiratory protection if exposure to dust particles, mist or vapors is likely. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Use disposable dust/mist mask if the recommended exposure limit is exceeded. Use respirator with an organic vapor cartridge if exposure limit is exceeded. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Gloves, coveralls, apron, boots as necessary to minimize contact. Do not wear rings, watches or similar apparel that could entrap the material. Long sleeve shirt is recommended. Chemical resistant boots.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Dark
Colour Intensity
---
Form
liquid
Odor
Pungent
Odor Threshold
---
Ph
---
Melting Point
---
Boiling Point
---
Flash Point
115 °C (Pensky-Martens Closed Cup)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
0.0004 PSI (20 °C)
Vapor Density
---
Relative Density
1.035 - 1.075 (15.6 °C)
Bulk Density
8.79 lb/gal (25 °C)
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
552.7 cP (20 °C); 50 cP (68.9 °C)
Kinematic Viscosity
250 mm2/s (40 °C); 20 mm2/s (100 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Do not expose to excessive heat, ignition sources, or oxidizing materials. Excessive heat.

Incompatible

oxidizing materials

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, sulfur oxides, mercaptans, sulfides, including hydrogen sulfide and other products of incomplete combustion. Thermal decomposition may generate phosphorus oxides and other phosphorus containing compounds. Thermal decomposition may generate zinc oxides and other zinc containing compounds.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

## Fish Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Ecotoxicity

Fish zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) LC 50 (Rainbow Trout, 4 d): 4.4 mg/l NOEC (Rainbow Trout, 4 d): 3.2 mg/l

12.1 Ecotoxicity

## Fish C14-18 alpha-olefin epoxide, reaction products with boric acid LC 50 (Rainbow Trout, 4 d): > 100 mg/l

12.1 Ecotoxicity

## Fish ++ O,O,O-triphenyl phosphorothioate LC 50 (Zebra Fish, 4 d): > 100 mg/l No toxicity at solubility limit.

12.1 Ecotoxicity

Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Ecotoxicity

## 12.1 Ecotoxicity ## Aquatic Invertebrates zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC 50 (Water flea (Daphnia magna), 2 d): 75 mg/l NOEC (Water flea (Daphnia magna), 2 d): 32 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 0.8 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.4 mg/l

12.1 Ecotoxicity

C14-18 alpha-olefin epoxide, reaction products with boric acid EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l NOEC (Water flea (Daphnia magna), 2 d): 100 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 20 mg/l NOEC (Water flea (Daphnia magna), 21 d): 10 mg/l

12.1 Ecotoxicity

## Aquatic Invertebrates Triphenyl phosphite EC 50 (Water flea (Daphnia magna), 2 d): 0.94 mg/l

12.1 Ecotoxicity

## Aquatic Invertebrates ++ O,O,O-triphenyl phosphorothioate EC 50 (Water Flea (Daphnia Magna), 2 d): > 100 mg/l No toxicity at solubility limit. NOEC (Water Flea (Daphnia Magna), 21 d): > 5.5 mg/l No toxicity at solubility limit.

12.1 Ecotoxicity

Toxicity to Aquatic Plants Mineral oil EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 410 mg/l NOEC (Green algae (Scenedesmus quadricauda), 3 d): 220 mg/l

12.1 Ecotoxicity

## 12.1 Ecotoxicity ## Toxicity to Aquatic Plants C14-18 alpha-olefin epoxide, reaction products with boric acid EC 50 (Green algae (selenastrum capricomutum), 3 d): > 100 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants ++ O,O,O-triphenyl phosphorothioate EC 50 (Green algae (Scenedesmus quadricauda), 3 d): > 100 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC 50 (Pseudomonas putida, 0.1 d): 380 mg/l

12.1 Ecotoxicity

## 12.1 Ecotoxicity ## Toxicity to microorganisms C14-18 alpha-olefin epoxide, reaction products with boric acid EC 50 (Sludge, 0.1 d): > 10,000 mg/l

12.1 Ecotoxicity

## 12.1 Ecotoxicity ## Toxicity to microorganisms ++ O,O,O-triphenyl phosphorothioate EC 50 (Sludge, 3 h): > 100 mg/l

12.2 Persistence and Degradability

Biodegradation Mineral oil OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) OECD TG 301 D, < 5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation C14-18 alpha-olefin epoxide, reaction products with boric acid Miscellaneous, 17.3 %, 28 d, Not readily degradable. Miscellaneous, 26.7 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Triphenyl phosphite OECD TG 301 D, 0.14 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation ++ O,O,O-triphenyl phosphorothioate OECD TG 301 B, 17.8 - 19.3 %, 28 d, Not readily degradable. OECD TG 302 C, 59.9 - 66.8 %, 28 d

12.3 Bioaccumulative potential

### Bioconcentration Factor (BCF) No data available

12.3 Bioaccumulative potential

### Bioconcentration Factor (BCF) ++ O,O,O-triphenyl phosphorothioate Fish, Bioconcentration Factor (BCF): 2,551 (Flow Through)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) Log Kow: 3.6 (Measured)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) C14-18 alpha-olefin epoxide, reaction products with boric acid Log Kow: 9.4 (calculated)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) Triphenyl phosphite Log Kow: 6.62 25 °C (calculated)

12.4 Mobility:

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Other adverse effects

Product: Toxic to aquatic life with long lasting effects.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Zinc alkyldithiophosphate, Aryl phosphite)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

The information that was used to confirm the compliance status of this product may deviate from the chemical information shown in Section 3.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for B003232?

The signal word is warning.

What is the physical form of B003232?

B003232 is a liquid with dark color. It has pungent odor.

What is B003232 used for?

Additive for Off-Highway.

What are the hazard statements for B003232?

This substance has 2 hazard statements:

  • H317: May cause an allergic skin reaction.
  • H411: Toxic to aquatic life with long lasting effects.