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Safety Data Sheet EN

Octocure 567

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Octocure 567

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Vulcanisation agent

Uses advised against

No data available.

Manufacturers & Suppliers

T

Tiarco Chemical Europe GmbH

manufacturer

Am Gut Baarking 12, 46395 Bocholt

+49 2871 234760

Emergency Contacts

Giftinformationszentrum Nord

+49 (0)551 192 40

DE, EN

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Aquatic Chronic Cat. 2 H411
Repr. Cat. 2 H361
Skin Irrit. Cat. 2 H315
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H361 Suspected of damaging fertility or the unborn child.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P330 Rinse mouth.
P405 Store locked up.
P501 Dispose of contents/container to a facility in accordance with local and national regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
sulfur EC: 231-722-6 7704-34-9 10 - 25% Yes
zinc oxide EC: 215-222-5 1314-13-2 12% Yes
Quinoline, 1,2-dihydro-2,2,4-trimethyl-, homopolymer EC: 500-051-3 26780-96-1 2.5 - 10% Yes
Phenol, 4-methyl-, reaction products with dicyclopentadiene and isobutylene EC: 271-867-2 68610-51-5 2.5 - 10% Yes
1,3-diphenylguanidine EC: 203-002-1 102-06-7 10% Yes
zinc di(benzothiazol-2-yl) disulfide EC: 205-840-3 155-04-4 7% Yes
zinc bis(dibenzyldithiocarbamate) EC: 238-778-0 14726-36-4 6% Yes
benzothiazole-2-thiol EC: 205-736-8 149-30-4 1.5% Yes
2-methyl-2H-isothiazol-3-one EC: 220-239-6 2682-20-4 0.0015% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove affected persons from dangerous area by observing suitable respiratory protection measures. Ensure supply of fresh air.

Skin contact

Rinse with plenty of water.

Eye contact

Remove contact lenses. Rinse eye thoroughly under running water keeping eyelids wide open and protecting the unaffected eye (at least 10 to 15 minutes).

Ingestion

Rinse the mouth thoroughly with water. Do not induce vomiting. Never give anything by mouth to an unconscious person.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol-resistant foam.

Unsuitable media

High power water jet

Specific hazards

In the event of fire, the following can be released: Carbon oxides (COx); Sulphur oxides (SOx); Nitrogen oxides (NOx)

Firefighter Protection

Use self-contained breathing apparatus. Wear protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

For non-emergency personnel: Refer to protective measures listed in sections 7 and 8. For emergency responders: Personal protective equipment (PPE) - see section 8.

Environmental

Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil.

Cleanup methods

Contain and collect spillage with non-combustible absorbent materials and place in container for disposal according to local regulations (see section 13).

Materials: non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Risks inherent to handling the product must be minimised by applying the appropriate protective and preventive measures. Working processes should - so far as possible, according to the state of the art - be designed to rule out bodily contact or the release of hazardous substances.

Storage

Keep container tightly closed and dry in a cool, well-ventilated place.

Hygiene

Do not eat, drink or smoke during work time. Keep away from foodstuffs and beverages. Do not inhale vapours. Avoid contact with eyes and skin. Wash hands before breaks and after work. Remove contaminated clothing and shoes and launder thoroughly before reusing.

Fire prevention

Keep away from ignition sources and provide for good ventilation.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL (=Occupational Exposure Limit), suitable respiratory protection must be worn.

Hands

Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product. Before use, the protective gloves should be tested in any case for its specific workstation suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer's instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.

Eyes

Safety glasses with side protection shield (EN 166)

Respiratory

If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.

Skin/Body

Chemical-resistant work clothes.

Environmental

No data available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
light yellow
Colour Intensity
---
Form
Dispersion
Odor
characteristic
Odor Threshold
---
Ph
10 - 11
Melting Point
No data available
Boiling Point
~ 100 °C
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
~ 1.3 g/cm³
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
1.2 - 7.7 (Quinoline, 1,2-dihydro-2,2,4-trimethyl-, homopolymer); 7.93 (Phenol, 4-methyl-, reaction products with dicyclopentadiene and isobutylene); 2.42 (benzothiazole-2-thiol)
Solubility In Water
Completely miscible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
~ 300 mPa*s
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage and handling conditions (See section 7).

Reactivity

No data available.

Hazardous reactions

Dangerous reactions are not to be expected when handling product according to its intended use.

Avoid

No data available.

Incompatible

No data available.

Decomposition

No data available.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity to algae (acute): EC50 = 0.5 mg/l. Duration of exposure: 72 h. Species: Selenastrum capricornutum. Method: OECD 201. Source: ECHA.

12.1 Toxicity

Toxicity to algae (acute): EC50 > 100 mg/l, 72h, Pseudokirchneriella subcapitata, OECD 201, Source: ECHA

12.1 Toxicity

Toxicity to algae (acute): EC50 = 0.5 mg/l, Duration: 72 h, Species: Pseudokirchneriella subcapitata, Method: OECD 201, Source: ECHA

12.1 Toxicity

Bacteria toxicity: EC50 > 10000 (activated sludge, OECD 209, ECHA)

12.2 Persistence and degradability

Biodegradability: 0% in 28 days (aerobic). Method: EU Method C.4-E. Evaluation: not readily biodegradable.

12.2 Persistence and degradability

Biodegradability: No. Substance name: Phenol, 4-methyl-, reaction products with dicyclopentadiene and isobutylene. CAS no.: 68610-51-5. EC no.: 271-867-2. Type: aerobic biodegradation. Value: 1 %. Duration: 28 day(s). Method: OECD 301 B. Source: ECHA. Evaluation: not readily biodegradable.

Persistence and degradability

Biodegradability: 55 - 71 %; Duration: 28 day(s); Method: OECD 301 B; Source: ECHA; Evaluation: inherently biodegradable

12.2 Persistence and degradability

Biodegradability: 8% (28 days), OECD 301 F, not readily biodegradable

Persistence and degradability

Biodegradability: 2.5 % (14 days), OECD 301 C, not readily biodegradable

12.3 Bioaccumulative potential

Bioconcentration factor (BCF): 108 - 1300. Species: Cyprinus carpio. Method: OECD 305 C. Source: ECHA.

12.3 Bioaccumulative potential

Bioconcentration factor (BCF): < 20. Species: Cyprinus carpio. Method: OECD 305 C. Source: ECHA.

12.3 Bioaccumulative potential

Bioconcentration factor (BCF) for benzothiazole-2-thiol (CAS 149-30-4): BCF < 8, with reference to 0,01 mg/L. Method: OECD 305 C. Source: ECHA.

12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log value): 1.2 - 7.7. Reference temperature: 25 °C. Method: OECD 117. Source: ECHA.

12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log value): 7.93 (25 °C, pH 7, OECD 123, Source: ECHA)

12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log value): 2.42 (pH 7, EPA OPPTS 830.7550, Source: ECHA)

12.4 Mobility in soil

No data available.

12.5 Results of PBT and vPvB assessment

Results of PBT and vPvB assessment | | | --- | --- | | PBT assessment | According to the information provided in the supply chain, the mixture does not contain > 0.1% of a substance that is considered to be PBT. | | vPvB assessment | According to the information provided in the supply chain, the mixture does not contain > 0.1% of a substance that is considered to be vPvB. |

According to the information provided in the supply chain, the mixture does not contain > 0.1% of a substance that is considered to be PBT or vPvB.

12.6 Endocrine disrupting properties

No data available.

12.7 Other adverse effects

No data available.

12.1 Toxicity

| Toxicity to fish (acute) | | | | | --- | --- | --- | --- | | No | Substance name | CAS no. | EC no. | | 1 | Phenol, 4-methyl-, reaction products with dicyclopentadiene and isobutylene | 68610-51-5 | 271-867-2 | | LC50 | > | 0.2 | mg/l | | Duration of exposure | | 96 | h | | Species | Oncorhynchus mykiss | | | | Method | OECD 203 | | | | Source | ECHA | | |

12.1 Toxicity

| Toxicity to fish (acute) | | | | | --- | --- | --- | --- | | No | Substance name | CAS no. | EC no. | | 2 | 1,3-diphenylguanidine | 102-06-7 | 203-002-1 | | LC50 | | 4.2 | mg/l | | Duration of exposure | | 96 | h | | Species | Pimephales promelas | | | | Source | ECHA | | |

12.1 Toxicity

| Toxicity to fish (acute) | | | | | --- | --- | --- | --- | | No | Substance name | CAS no. | EC no. | | 3 | zinc di(benzothiazol-2-yl) disulfide | 155-04-4 | 205-840-3 | | LC50 | | 0.75 | mg/l | | Duration of exposure | | 96 | h | | Species | Oncorhynchus mykiss | | | | Source | ECHA | | |

12.1 Toxicity

Toxicity to fish (acute) No | Substance name | CAS no. | EC no. 4 | zinc bis(dibenzyldithiocarbamate) | 14726-36-4 | 238-778-0 LC50 | > | 10 | mg/l Duration of exposure | 96 | h Species | Poecilia reticulata Method | OECD 203 Source | ECHA

12.1 Toxicity

| Toxicity to fish (acute) | | | | | --- | --- | --- | --- | | No | Substance name | CAS no. | EC no. | | 5 | benzothiazole-2-thiol | 149-30-4 | 205-736-8 | | LC50 | | 0.73 | mg/l | | Duration of exposure | | 96 | h | | Species | Oncorhynchus mykiss | | | | Method | OECD 203 | | | | Source | ECHA | | |

12.1 Toxicity

Toxicity to fish (chronic): NOEC 0.041 mg/l, Duration of exposure 89 day(s), Species Oncorhynchus mykiss, Method OECD 210, Source ECHA

Toxicity

Toxicity to fish (chronic): NOEC > 10 mg/l, Duration of exposure 8 day(s), Species Danio rerio, Method OECD 210, Source ECHA

Toxicity

Toxicity to fish (chronic): benzothiazole-2-thiol (CAS 149-30-4). NOEC: 0.041 mg/l. Duration of exposure: 89 day(s). Species: Oncorhynchus mykiss. Method: OECD 210. Source: ECHA.

Persistence and degradability

Bioaccumulative potential

Mobility in soil

Results of PBT and vPvB assessment

Endocrine disrupting properties

Other adverse effects

Toxicity

Toxicity to Daphnia (acute): EL50 56 mg/l, 48h, Daphnia magna, Method: EU C.2, Source: ECHA

12.1 Toxicity

Toxicity to Daphnia (acute): EC50 > 0.2 mg/l, Duration of exposure: 48 h, Species: Daphnia magna, Method: OECD 202, Source: ECHA

Toxicity to Daphnia (acute)

No Substance name CAS no. EC no. 3 1,3-diphenylguanidine 102-06-7 203-002-1 EC50 17 mg/l Duration of exposure 48 h Species Daphnia magna Source ECHA

12.1 Toxicity

Toxicity to Daphnia (acute): EC50 = 0.71 mg/l, Duration = 48h, Species = Daphnia magna, Method = OECD 202, Source = ECHA

Toxicity to Daphnia (acute)

| 5 | zinc bis(dibenzyldithiocarbamate) | 14726-36-4 | 238-778-0 | | | EC50 | | 0.74 | mg/l | | | Duration of exposure | | 48 | h | | | Species | Daphnia magna | | | | Method | EPA 660/3-75-009 | | | | Source | ECHA | | |

12.1 Toxicity

Toxicity to Daphnia (acute): EC50 0.71 mg/l, Duration 48 h, Species Daphnia magna, Method OECD 202, Source ECHA.

12.1 Toxicity

Toxicity to Daphnia (chronic) No | Substance name | CAS no. | EC no. 1 | zinc di(benzothiazol-2-yl) disulfide | 155-04-4 | 205-840-3 NOEC | 0.08 | mg/l Duration of exposure | 21 | day(s) Species | Daphnia magna Method | OECD 211 Source | ECHA

12.1 Toxicity

Toxicity to Daphnia (chronic): NOEC 0.08 mg/l, Duration 21 days, Species Daphnia magna, Method OECD 211, Source ECHA

12.1 Toxicity

Toxicity to algae (acute): ErC50 0.2 mg/l, Duration of exposure 72 h, Species Pseudokirchneriella subcapitata, Method OECD 201, Source ECHA.

Toxicity to algae (acute)

No Substance name CAS no. EC no. 2 1,3-diphenylguanidine 102-06-7 203-002-1 EC50 2.6 mg/l Duration of exposure 72 h Species Desmodesmus subspicatus Source ECHA
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Disposal of the product should be carried out in accordance with all applicable regulations following consultation with the responsible local authority and the disposal company in an authorised and suitable disposal facility.

Disposal

Disposal of the product should be carried out in accordance with all applicable regulations following consultation with the responsible local authority and the disposal company in an authorised and suitable disposal facility.

Waste Codes

European Waste Catalogue EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The product is subject to REACH Annex XVII. It does not contain substances requiring authorization under REACH Annex XIV or SVHC.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Octocure 567?

The signal word is warning.

What is the physical form of Octocure 567?

Octocure 567 is a liquid with light yellow color. It has characteristic odor.

What is Octocure 567 used for?

Vulcanisation agent

What are the hazard statements for Octocure 567?

This substance has 5 hazard statements:

  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H361: Suspected of damaging fertility or the unborn child.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Octocure 567?

The melting point is No data available and the boiling point is ~ 100 °C.