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Safety Data Sheet EN

Phenylmethanesulfonyl fluoride solution

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Phenylmethanesulfonyl fluoride solution
Product Code
93482

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV

manufacturer

Ildefonse Vandammestraat 5/7B, B-1560 HOEILAART

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
ethanol EC: 200-578-6 64-17-5 90 - 100% Yes
phenylmethanesulfonyl fluoride EC: 206-350-2 329-98-6 1 - 3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.

Instructions

Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Full contact: Material: butyl-rubber, Minimum layer thickness: 0,3 mm, Break through time: 480 min, Material tested: Butoject® (KCL 897 / Aldrich Z677647, Size M). Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,2 mm, Break through time: 30 min, Material tested: Dermatril® P (KCL 743 / Aldrich Z677388, Size M). data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type ABEK. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
clear, liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colorless
Colour Intensity
---
Form
---
Odor
No data available
Odor Threshold
---
Ph
No data available
Melting Point
No data available
Boiling Point
No data available
Flash Point
12 °C - closed cup
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
No data available
Vapor Density
---
Relative Density
No data available
Bulk Density
---
Density
0,797 g/mL at 20 °C
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
No data available
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapors may form explosive mixture with air.

Hazardous reactions

Risk of explosion/exothermic reaction with: hydrogen peroxide, perchlorates, perchloric acid, Nitric acid, mercury(II) nitrate, permanganic acid, Nitriles, peroxi compounds, Strong oxidizing agents, nitrosyl compounds, Peroxides, sodium, Potassium, halogen oxides, calcium hypochlorite, nitrogen dioxide, metallic oxides, uranium hexafluoride, iodides, Chlorine, Alkali metals, Alkaline earth metals, alkali oxides, Ethylene oxide, silver with Nitric acid, silver compounds with Ammonia, potassium permanganate with conc. sulfuric acid. Risk of ignition or formation of inflammable gases or vapours with: halogen-halogen compounds, chromium(VI) oxide, chromyl chloride, Fluorine, hydrides, Oxides of phosphorus, platinum, Nitric acid with potassium permanganate.

Avoid

Warming.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Mixture No data available

No data available

12.2 Persistence and degradability

No data available

No data available

12.3 Bioaccumulative potential

No data available

No data available

12.4 Mobility in soil

No data available

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

No data available

12.1 Toxicity

Toxicity to fish flow-through test LC50 - Pimephales promelas (fathead minnow) - 15.300 mg/l - 96 h (US-EPA) Toxicity to daphnia and other aquatic invertebrates static test LC50 - Ceriodaphnia dubia (water flea) - 5.012 mg/l - 48 h Remarks: (ECHA) Toxicity to algae static test ErC50 - Chlorella vulgaris (Fresh water algae) - 275 mg/l - 72 h (OECD Test Guideline 201) Toxicity to bacteria static test IC50 - activated sludge - > 1.000 mg/l - 3 h (OECD Test Guideline 209) Toxicity to fish(Chronic toxicity) semi-static test NOEC - Danio rerio (zebra fish) - 250 mg/l - 120 h Remarks: (ECHA) Toxicity to daphnia and other aquatic invertebrates(Chronic toxicity) semi-static test NOEC - Daphnia magna (Water flea) - 9,6 mg/l - 9 d Remarks: (ECHA)
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

No data available

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1170
Shipping Name
ETHANOL SOLUTION
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Phenylmethanesulfonyl fluoride solution?

The signal word is danger.

What is the physical form of Phenylmethanesulfonyl fluoride solution?

Phenylmethanesulfonyl fluoride solution is a clear, liquid with colorless color. It has no data available odor.

What is Phenylmethanesulfonyl fluoride solution used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Phenylmethanesulfonyl fluoride solution?

This substance has 3 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.

What is the melting point of Phenylmethanesulfonyl fluoride solution?

The melting point is No data available and the boiling point is No data available.