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Safety Data Sheet EN

Perfluorobutylsulphonamide

CAS 30334-69-1*

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Perfluorobutylsulphonamide
Chemical Name
perfluoro-1-butanesulfonamide
Synonyms
Not Available

Regulatory Identifiers

CAS Number
30334-69-1* Check regulations →

Identified Uses

Not Available

Manufacturers & Suppliers

Apollo Scientific logo

Apollo Scientific

manufacturer

Whitefield Road, Bredbury SK62QR United Kingdom

01614060505

http://www.apolloscientific.co.uk/

Apollo Scientific Ltd logo

Apollo Scientific Ltd

manufacturer

Whitefield Road, Bredbury Cheshire SK 2QR United Kingdom (NI)

+44(0) 161 406 0505

apolloscientific.co.uk

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H312
Acute Tox. Cat. 4 H332
STOT SE Cat. 3 H335
Acute Tox. Cat. 4 H302
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/fumes.
P264 Wash all exposed external body areas thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing, eye protection and face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P330 Rinse mouth.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Perfluorobutylsulphonamide 30334-69-1 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor.

Skin contact

Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Eye contact

Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Ingestion

IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY. For advice, contact a Poisons Information Centre or a doctor. Urgent hospital treatment is likely to be needed. In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive measures as indicated by the patient's condition. If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a copy of the SDS should be provided. Further action will be the responsibility of the medical specialist. If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the SDS. Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless instructed otherwise: INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.

Immediate Medical Attention

IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY. Urgent hospital treatment is likely to be needed.

Medical Treatment

Establish a patent airway with suction where necessary. Watch for signs of respiratory insufficiency and assist ventilation as necessary. Administer oxygen by non-rebreather mask at 10 to 15 L/min. Monitor and treat, where necessary, for pulmonary oedema. Monitor and treat, where necessary, for shock. Anticipate seizures. Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred. Positive-pressure ventilation using a bag-valve mask might be of use. Monitor and treat, where necessary, for arrhythmias. Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications. Drug therapy should be considered for pulmonary oedema. Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Treat seizures with diazepam. Proparacaine hydrochloride should be used to assist eye irrigation.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area.

Specific hazards

Non combustible. Not considered a significant fire risk, however containers may burn. May emit poisonous fumes. May emit corrosive fumes.

Instructions

Alert Fire Brigade and tell them location and nature of hazard. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.

Firefighter Protection

Wear breathing apparatus plus protective gloves in the event of a fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Minor Spills: Remove all ignition sources. Clean up all spills immediately. Avoid contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Use dry clean up procedures and avoid generating dust. Place in a suitable, labelled container for waste disposal. Major Spills: Moderate hazard. CAUTION: Advise personnel in area. Alert Emergency Services and tell them location and nature of hazard. Control personal contact by wearing protective clothing. Prevent, by any means available, spillage from entering drains or water courses. Recover product wherever possible. IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and place in sealed plastic bags or other containers for disposal. IF WET: Vacuum/shovel up and place in labelled containers for disposal. ALWAYS: Wash area down with large amounts of water and prevent runoff into drains. If contamination of drains or waterways occurs, advise Emergency Services.

Small spill

Remove all ignition sources. Clean up all spills immediately. Avoid contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Use dry clean up procedures and avoid generating dust. Place in a suitable, labelled container for waste disposal.

Large spill

Moderate hazard. CAUTION: Advise personnel in area. Alert Emergency Services and tell them location and nature of hazard. Control personal contact by wearing protective clothing. Prevent, by any means available, spillage from entering drains or water courses. Recover product wherever possible. IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and place in sealed plastic bags or other containers for disposal. IF WET: Vacuum/shovel up and place in labelled containers for disposal. ALWAYS: Wash area down with large amounts of water and prevent runoff into drains. If contamination of drains or waterways occurs, advise Emergency Services.

Environmental

See section 12

Cleanup methods

Use dry clean up procedures and avoid generating dust. Vacuum/shovel up and place in labelled containers for disposal. Wash area down with large amounts of water and prevent runoff into drains.

Materials: sealed plastic bags or other containers

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. DO NOT allow material to contact humans, exposed food or food utensils. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.

Storage

Store in original containers. Keep containers securely sealed. Store in a cool, dry area protected from environmental extremes. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks.

Hygiene

When handling, DO NOT eat, drink or smoke. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Local exhaust ventilation usually required. Provide adequate ventilation in warehouse or closed storage area.

Hands

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes) is recommended. For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended. Suitable polymers: polychloroprene, nitrile rubber, butyl rubber, fluorocaoutchouc, polyvinyl chloride.

Eyes

Safety glasses with side shields. Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent].

Respiratory

Type -P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent). If risk of overexposure exists, wear approved respirator. Supplied-air type respirator may be required in special circumstances. An approved self contained breathing apparatus (SCBA) may be required in some situations.

Skin/Body

Overalls. P.V.C apron. Barrier cream. Skin cleansing cream.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Not Available
Colour
---
Colour Intensity
---
Form
---
Odor
Not Available
Odor Threshold
Not Available
Ph
Not Available
Melting Point
64-69 °C
Boiling Point
Not Available
Flash Point
Not Available
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not Available
Vapor Pressure
Not Available
Vapor Density
Not Available
Relative Density
Not Available
Bulk Density
---
Density
---
Flammability
Not Available
Upper Explosive Limit
Not Available
Lower Explosive Limit
Not Available
Explosive Limits
---
Auto Ignition Temperature
Not Available
Decomposition Temperature
Not Available
Solubility
---
Partition Coefficient
Not Available
Solubility In Water
Not Available
Solubility In Fat
---
Molecular Weight
Not Available
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Not Available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

• Unstable in the presence of incompatible materials. • Product is considered stable. • Hazardous polymerisation will not occur.

Reactivity

See section 7

Hazardous reactions

See section 7

Avoid

See section 7

Incompatible

See section 7

Decomposition

See section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Perfluorobutylsulphonamide known by?

Perfluorobutylsulphonamide is also known as: Not Available

What is the hazard signal word for Perfluorobutylsulphonamide?

The signal word is warning.

What is the physical form of Perfluorobutylsulphonamide?

Perfluorobutylsulphonamide is a solid appearing as not available . It has not available odor.

What is Perfluorobutylsulphonamide used for?

Not Available

What are the hazard statements for Perfluorobutylsulphonamide?

This substance has 7 hazard statements:

  • H302: Harmful if swallowed.
  • H312: Harmful in contact with skin.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of Perfluorobutylsulphonamide?

The melting point is 64-69 °C and the boiling point is Not Available.