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Safety Data Sheet EN

epple 30

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
epple 30
Product Code
1 00030 00000

Regulatory Identifiers

CAS Number
N/A
UFI Code
42M0-J007-A008-PTG0

Identified Uses

Sealing material for the sealing of different parts / buildinggroups

Manufacturers & Suppliers

E. Epple & Co. GmbH logo

E. Epple & Co. GmbH

manufacturer

Hertzstr. 8, 71083 Herrenberg

+49 7032 / 9771-17

http://www.epple-chemie.de

Emergency Contacts

Information center against poisoning Bonn

+49 (0) 228 / 19 240

DE

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H336

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing vapours.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

polyacrylate solution, filled

Chemical Name CAS Number Concentration Hazardous
ethyl acetate EC: 205-500-4 141-78-6 19.9 - 24.9% Yes
Titanium dioxide EC: 236-675-5 13463-67-7 0.1 - 0.9% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove casualty to fresh air and keep warm and at rest. In case of irregular breathing or respiratory arrest provide artificial respiration.

Skin contact

Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do not use solvents or thinners.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice immediately.

Ingestion

If swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. Keep victim calm. Do NOT induce vomiting.

Medical Treatment

First Aid, decontamination, treatment of symptoms.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

alcohol resistant foam, carbon dioxide, Powder, spray mist, (water)

Unsuitable media

strong water jet

Specific hazards

Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.

Instructions

Cool closed containers that are near the source of the fire.

Firefighter Protection

Provide a conveniently located respiratory protective device.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours.

Environmental

Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent authorities in accordance with local regulations.

Cleanup methods

Clean using cleansing agents. Do not use solvents.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid formation of flammable and explosive vapour concentrations in the air and exceeding the exposure limit values. Only use the material in places where open light, fire and other flammable sources can be kept away. Avoid contact with skin, eyes and clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using do not eat, drink or smoke. Personal protection equipment: refer to section 8. Do not empty containers with pressure - no pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal protection and safety regulations.

Storage

Store in a well-ventilated and dry room at temperatures between 5 °C and 30 °C. Protect from heat and direct sunlight. Keep container tightly closed.

Hygiene

When using do not eat, drink or smoke.

Fire prevention

Only use the material in places where open light, fire and other flammable sources can be kept away. Keep away from heat sources, sparks and open flames. Use only spark proof tools.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide good ventilation. This can be achieved with local or room suction. If this should not be sufficient to keep aerosol and solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used.

Hands

For prolonged or repeated handling the following glove material must be used: NBR (Nitrile rubber) Thickness of the glove material > 0,4 mm; Breakthrough time: > 480 min. Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended glove articles EN ISO 374 Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.

Eyes

Wear eye glasses with side protection according to EN 166.

Respiratory

If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection must be used. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection apparatus (BGR 190). Use only respiratory protection equipment with CE-symbol including four digit test number. Use filter / combination filter according to EN 14387. Suitable respiratory protection apparatus: ABEK-P2

Skin/Body

Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers.

Environmental

Do not allow to enter into surface water or drains. See section 7. No additional measures necessary.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Paste
Colour
grey
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
not applicable
Ph
not relevant
Melting Point
-83 °C (ethyl acetate)
Boiling Point
77 °C (ethyl acetate)
Flash Point
-4 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
98,4 mbar (ethyl acetate)
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,39 g/cm³
Flammability
---
Upper Explosive Limit
12,8 Vol-% (ethyl acetate)
Lower Explosive Limit
2 Vol-% (ethyl acetate)
Explosive Limits
---
Auto Ignition Temperature
470 °C (ethyl acetate)
Decomposition Temperature
not applicable
Solubility
---
Partition Coefficient
---
Solubility In Water
insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
130 - 190 Pa*s
Kinematic Viscosity
> 64748,2 mm²/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable when applying the recommended regulations for storage and handling.

Reactivity

No information available.

Hazardous reactions

Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.

Avoid

Hazardous decomposition byproducts may form with exposure to high temperatures.

Incompatible

not applicable

Decomposition

Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide, smoke, nitrogen oxides.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Do not allow to enter into surface water or drains.

12.1. Toxicity

ethyl acetate Fish toxicity, LC50, Pimephales promelas (fathead minnow): 230 mg/L (96 h) Flow test Daphnia toxicity, EC50, Daphnia cucullata: 165 mg/L (48 h) aquatic, freshwater Algae toxicity, ErC50, Desmodesmus subspicatus: > 100 mg/L (72 h) Method: OECD 201 Bacteria toxicity, NOEC.; Pseudomonas putida: 650 mg/L (16 h) Method: DIN 38412 Fish toxicity, EC50: 220 mg/L (96 h) Daphnia toxicity, EC50, Artemia salina: 346 mg/L (24 h)

12.1. Toxicity

Titanium dioxide Algae toxicity, EC50, Pseudokirchneriella subcapitata: 61 mg/L (72 h) Method: EPA-600/9-78-018 Bacterial toxicity: EC50; Activated sludge: > 1000 (3 h) Method: OECD 209

12.1. Toxicity

Long-term Ecotoxicity ethyl acetate Fish toxicity, NOEC, Pimephales promelas (fathead minnow): < 9,65 mg/L (32 d) Daphnia toxicity, NOEC, Daphnia magna (Big water flea): 2,4 mg/L (21 d) Bacteria toxicity, NOEC, Pseudomonas putida: 650 mg/L (16 h) Method: DIN 38412

12.2. Persistence and degradability

12.2. Persistence and degradability

ethyl acetate Biodegradation, aerobic: 69 % (20 d); Evaluation Readily biodegradable oxygen consumption: 62 % (5 d)

12.3. Bioaccumulative potential

12.3. Bioaccumulative potential

ethyl acetate Partition coefficient: n-octanol/water: 0,68 ### Bioconcentration factor (BCF) ethyl acetate Bioconcentration factor (BCF), Leuciscus idus (golden orfe): 30

12.4. Mobility in soil

soil, Adsorption: Evaluation Due to the low n-octanol/water distribution coefficient, adsorption on the ground is not to be expected.

12.5. Results of PBT and vPvB assessment

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

12.6. Endocrine disrupting properties

No information available.

12.7. Other adverse effects

No information available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste disposal according to directive 2008/98/EC, covering waste and dangerous waste.

Disposal

Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way.

Waste Codes

080409* Waste adhesives and sealants containing organic solvents or other dangerous substances EWC
15 01 10* packaging containing residues of or contaminated by hazardous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1866
Shipping Name
Resin solution
Transport Class
3
Packing Group
III
ADR

Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8

IMDG

Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8

IATA

Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

For professional use only. Product is not intended for consumer use.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for epple 30?

The signal word is danger.

What is the physical form of epple 30?

epple 30 is a liquid appearing as paste with grey color. It has characteristic odor.

What is epple 30 used for?

Sealing material for the sealing of different parts / buildinggroups

What are the hazard statements for epple 30?

This substance has 3 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H319: Causes serious eye irritation.
  • H336: May cause drowsiness or dizziness.

What is the melting point of epple 30?

The melting point is -83 °C (ethyl acetate) and the boiling point is 77 °C (ethyl acetate).