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Safety Data Sheet EN

Ethanol ≥70 %, denatured

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ethanol ≥70 %, denatured
Product Code
T913
Chemical Name
Ethanol

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemical Laboratory and analytical use

Uses advised against

Do not use for products which come into contact with foodstuffs. Do not use for private purposes (household).

Manufacturers & Suppliers

Carl Roth GmbH + Co KG logo

Carl Roth GmbH + Co KG

manufacturer

Schoemperlenstr. 3-5, D-76185 Karlsruhe, Germany

+49 (0) 721 - 56 06 0

http://www.carlroth.de

Emergency Contacts

National Poisons Information Service City Hospital

844 892 0111

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapour
H319 Causes serious eye irritation

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P233 Keep container tightly closed
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethanol EC: 200-578-6 64-17-5 70% Yes
2-Propanol EC: 200-661-7 67-63-0 1 - 2% Yes
2-Butanone EC: 201-159-0 78-93-3 1 - 2% Yes
Bitrex 3734-33-6 0.1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Symptoms: Breathing difficulties, Vertigo, Drowsiness, Narcosis, Loss of righting reflex, and ataxia

Skin contact

Rinse skin with water/shower. In all cases of doubt, or when symptoms persist, seek medical advice.

Symptoms: Irritation

Eye contact

Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. In case of eye irritation consult an ophthalmologist.

Symptoms: Irritation

Ingestion

Rinse mouth. Call a doctor if you feel unwell.

Symptoms: Nausea, Vomiting, Abdominal pain

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

co-ordinate firefighting measures to the fire surroundings, water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)

Unsuitable media

water jet

Specific hazards

Combustible. In case of insufficient ventilation and/or in use, may form flammable/explosive vapour-air mixture. Solvent vapours are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures. Vapours may form explosive mixtures with air.

Instructions

Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

In case of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray.

Environmental

Keep away from drains, surface and ground water. Danger of explosion.

Cleanup methods

Absorb with liquid-binding material

Materials: sand, diatomaceous earth, acid- or universal binding agents

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Provision of sufficient ventilation. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches.

Storage

Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight.

Hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs. When using do not smoke.

Fire prevention

Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The times are approximate values from measurements at 22 °C and permanent contact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effective layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred to substance mixtures, they may only be considered as a guide. Type of material: Butyl caoutchouc (butyl rubber), material thickness: 0,5 mm, breakthrough times of the glove material: >480 minutes (permeation: level 6)

Eyes

Use safety goggle with side protection.

Respiratory

Respiratory protection necessary at: Aerosol or mist formation. Type: A (against organic gases and vapours with a boiling point of > 65 °C, colour code: Brown).

Skin/Body

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Flame-retardant protective clothing.

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
---
Odor
like: - alcohol
Odor Threshold
---
Ph
7 (20 °C)
Melting Point
-114 °C
Boiling Point
78 °C
Flash Point
>22 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
59 hPa at 20 °C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0,88 g/cm³ at 20 °C
Flammability
flammable liquid in accordance with GHS criteria
Upper Explosive Limit
15 vol% (UEL)
Lower Explosive Limit
3,5 vol% (LEL)
Explosive Limits
---
Auto Ignition Temperature
455 °C
Decomposition Temperature
not relevant
Solubility
---
Partition Coefficient
this information is not available
Solubility In Water
miscible in any proportion
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1,2 mPa s at 20 °C
Kinematic Viscosity
1,364 mm²/s at 20 °C
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Reactivity

The mixture contains reactive substance(s). Risk of ignition. Vapours may form explosive mixtures with air. If heated Risk of ignition.

Hazardous reactions

Violent reaction with: strong oxidiser, Alkali metals, Alkaline earth metal, Acetic anhydride, Peroxides, Phosphorus oxides (e.g. P2O5), Nitric acid, Nitrate, Perchlorates, => Explosive properties

Avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Incompatible

Rubber articles, different plastics

Decomposition

Hazardous combustion products: see section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Shall not be classified as hazardous to the aquatic environment. Aquatic toxicity (acute) of components of the mixture | Name of sub-stance | CAS No | Endpoint | Value | Species | Exposure time |

12.1 Toxicity

| Name of sub-stance | CAS No | Endpoint | Value | Species | Exposure time | | --- | --- | --- | --- | --- | --- | | Ethanol | 64-17-5 | LC50 | 8.140 mg/l | orfe (Leuciscus idus) | 96 h | | Ethanol | 64-17-5 | EC50 | 9.000 – 14.000 mg/l | daphnia magna | 48 h |

12.1 Toxicity

| Name of sub-stance | CAS No | Endpoint | Value | Species | Exposure time | | --- | --- | --- | --- | --- | --- | | 2-Butanone | 78-93-3 | LC50 | 2.993 mg/l | fish | 96 h | | 2-Butanone | 78-93-3 | EC50 | 308 mg/l | aquatic invertebrates | 48 h | | 2-Butanone | 78-93-3 | ErC50 | 2.029 mg/l | algae | 96 h |

12.1 Toxicity

| Name of sub-stance | CAS No | Endpoint | Value | Species | Exposure time | | --- | --- | --- | --- | --- | --- | | 2-Propanol | 67-63-0 | LC50 | 9.640 mg/l | Pimephales promelas | 96 h |

12.1 Toxicity

Aquatic toxicity (chronic) of components of the mixture | Name of sub-stance | CAS No | Endpoint | Value | Species | Exposure time | | --- | --- | --- | --- | --- | --- | | 2-Propanol | 67-63-0 | LC50 | >10.000 mg/l | aquatic invertebrates | 24 h |

12.2 Process of degradability

| Name of substance | CAS No | Process | Degradation rate | Time | Method | Source | | --- | --- | --- | --- | --- | --- | --- | | Ethanol | 64-17-5 | biotic/abiotic | 94 % | d | | |

12.2 Process of degradability

12.2 Process of degradability | Name of substance | CAS No | Process | Degradation rate | Time | Method | Source | | --- | --- | --- | --- | --- | --- | --- | | 2-Butanone | 78-93-3 | oxygen depletion | 98 % | 28 d | | ECHA |

12.2 Process of degradability

| Name of substance | CAS No | Process | Degradation rate | Time | Method | Source | | --- | --- | --- | --- | --- | --- | --- | | 2-Propanol | 67-63-0 | biotic/abiotic | 95 % | 21 d | modifizierter OECD Screening Test | | | 2-Propanol | 67-63-0 | oxygen depletion | 53 % | 5 d | | ECHA |

12.3 Bioaccumulative potential

Data are not available.

12.3 Bioaccumulative potential

| Name of substance | CAS No | BCF | Log KOW | BOD5/COD | | Ethanol | 64-17-5 | | -0,31 | |

12.3 Bioaccumulative potential

| Name of substance | CAS No | BCF | Log KOW | BOD5/COD | | 2-Butanone | 78-93-3 | | 0,3 (pH value: 7, 40 °C) | |

12.3 Bioaccumulative potential

| Name of substance | CAS No | BCF | Log KOW | BOD5/COD | | 2-Propanol | 67-63-0 | | 0,05 | |

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

Data are not available.

12.6 Endocrine disrupting properties

None of the ingredients are listed.

12.7 Other adverse effects

Data are not available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of contents/container in accordance with local/regional/national/international regulations.

Disposal

This material and its container must be disposed of as hazardous waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1170
Shipping Name
ETHANOL SOLUTION
Transport Class
3
Packing Group
II
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Ethanol ≥70 %, denatured?

The signal word is danger.

What is the physical form of Ethanol ≥70 %, denatured?

Ethanol ≥70 %, denatured is a liquid with colourless color. It has like: - alcohol odor.

What is Ethanol ≥70 %, denatured used for?

Laboratory chemical Laboratory and analytical use

What are the hazard statements for Ethanol ≥70 %, denatured?

This substance has 2 hazard statements:

  • H225: Highly flammable liquid and vapour
  • H319: Causes serious eye irritation

What is the melting point of Ethanol ≥70 %, denatured?

The melting point is -114 °C and the boiling point is 78 °C.