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Safety Data Sheet EN

Ethanol 70% V/V denatured

CAS 64-17-5
EC 200-578-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ethanol 70% V/V denatured
Synonyms
Ethanolum 70% V/V denaturus, Ethanol 70% V/V gedenatureerd, Ethanol 70% V/V dénaturé, Ethanol 70% V/V vergällt

Regulatory Identifiers

CAS Number
64-17-5 Check regulations →
EC Number
200-578-6 Check regulations →

Identified Uses

Active Pharmaceutical Ingredient or Excipient.

Manufacturers & Suppliers

FRAVER NV logo

FRAVER NV

manufacturer

Keizershoek 336, 2550 Kontich, Belgium

(+32) (0)3 457 11 76

http://www.magis-pharma.be

Emergency Contacts

Belgisch Antigifcentrum / Centre Antipoisons Belge

(+32) (0)70 245 245

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 1 H225
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/...
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P370 + P378 In case of fire: Use powder, alcohol resistant foam, lots of water, carbon dioxide to extinguish.
P403 + P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/international regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethanol EC: 200-578-6 64-17-5 70% No
Diethyl ether EC: 200-467-2 60-29-7 1 - 5% No
Water EC: 231-791-2 7732-18-5 25 - 29% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air, provide ventilation if necessary and keep the person warm. If the person is unconscious, the patient should be placed lying on his/her side.

Symptoms: Irritating to mucous membranes

Skin contact

Rinse with plenty of water. Remove contaminated clothing.

Symptoms: redness of the skin

Eye contact

Rinse the eye with plenty of water in the open eyelids for several minutes. Remove contact lenses.

Symptoms: Irritating to mucous membranes

Ingestion

Rinse mouth and drink plenty of water. If the person is unconscious, the patient should be placed lying on his/her side.

Symptoms: nausea due to intake of larger amounts

Immediate Medical Attention

Consult a doctor if the complaints persist. Consult an ophthalmologist.

Medical Treatment

Not necessary.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Alcohol resistant foam, ABC powder, BC powder, carbon dioxide, water mist.

Unsuitable media

Water jet, alcohol unresistant foam.

Specific hazards

Formation of explosive gas-air mixtures. Extreme heat build-up in case of larger fires.

Instructions

Use water jet to cool exposed containers in the surridings. In case of larger fires: block the area in question.

Firefighter Protection

Independent respiratory protective equipment, complete protective suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

In case of large quantities: use personal protective equipment to prevent contamination of skin, eyes and personal clothing. Remove possible sources of ignition. Do not smoke. Take measures against static discharges. Provide adequate ventilation. Use only suitable and explosion-proof tools and devices. If available, the business plans for hazard reduction and emergency plans should be taken into account. For emergency responders: If available, the internal and external safety management plans should be taken into account.

Small spill

In case of smaller quantities: no special measures required.

Large spill

In case of large quantities: use personal protective equipment to prevent contamination of skin, eyes and personal clothing. Remove possible sources of ignition. Do not smoke. Take measures against static discharges. Provide adequate ventilation. Use only suitable and explosion-proof tools and devices.

Environmental

Prevent the product from entering drains, surface water or ground water.

Cleanup methods

In case of smaller quantities: no additional cleaning procedures are required. In case of larger quantities: use water for final purification.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use in a well-ventilated area. Take measures to prevent static electricity discharges. Do not store with incompatible materials.

Storage

Store in dry, tightly sealed and preferably well-filled containers in a sufficiently ventilated place at a temperature of +15°C to +25°C.

Hygiene

Avoid inhalation of vapours and direct contact with the skin, eyes and clothing.

Fire prevention

Take measures to prevent static electricity discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

To the extent required by the determination of the exposure scenario, an efficient local exhaust system must be provided. Measures to prevent an explosion must be taken into account.

Hands

Suitable gloves in case of prolonged direct contact (breakthrough time according to EN 374 > 480 min): Butyl rubber (butyl), recommended glove thickness: 0.7 mm.

Eyes

Safety protection for eyes, e.g. safety glasses (EN 166).

Respiratory

Necessary if vapours or aerosols are formed. Use filter A. respirator (according to DIN 3181) suitable for vapours from organic compounds.

Skin/Body

Protective clothing that is resistant to solvents.

Environmental

Remove polluted air from local exhaust and waste water in accordance with environmental regulations. EC legislation Water (76/464/EEC): not listed Air (1999/30/EC): not listed Risk management measures: See section 15.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State Data
liquid
Vapor Density
Not available.
Relative Evaporation Rate
---
Solidification Point
---
Freezing Point
-114 °C (ethanol)
Solubility In Water
Completely miscible.
Solubility In Fat
---
Physical State
liquid
Molecular Weight
---
Metal Corrosion
---
Explosive Limits
---
Bulk Density
---
Odor
Characteristic odour of alcohol and ether
Softening Point
---
Properties Status
---
Odor Threshold
Not available.
Cloud Point
---
Form
liquid
Flammability
Not available.
Partition Coefficient
Not available.
Dynamic Viscosity
---
Vapor Pressure
57.3 hPa (20 °C)
Lower Explosive Limit
2.5 Vol % (ethanol)
Voc Content
---
Kinematic Viscosity
---
Colour
Colourless
Density
---
Appearance
Colourless, clear liquid
Auto Ignition Temperature
363 °C (ethanol)
Solubility
Not available.
Evaporation Rate
Not available.
Flash Point
15 °C (ethanol)
Relative Density
0,88 (20 °C)
Decomposition Temperature
Not available.
Melting Point
-114 °C (ethanol)
Upper Explosive Limit
13.5 Vol % (ethanol)
Boiling Point
78 °C (ethanol)
Colour Intensity
---
Ph
Not available.
Crystallisation Point
---
State Under Standard Conditions
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal storage conditions. No stabilizers required.

Reactivity

No hazardous reactions if the instructions/advice on storage and handling of the substance have been properly applied. Not corrosive to metals.

Hazardous reactions

Exothermic, partly violent reaction with alkali and alkaline earth metals, strong acids and oxidizing agents possible. No spontaneous polymerization. Diethyl ether can cause dangerous reactions with peroxides.

Avoid

Storage temperatures > 40 °C (increase in pressure, deformation of the packaging), static electricity, explosion hazard in the vicinity of product/air mixtures.

Incompatible

alkali and alkaline earth metals, eg sodium (laboratory) with acids, eg sulfuric acid or strong oxidizing agents.

Decomposition

In the event of fire, formation of carbon monoxide is possible.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Aquatic compartment and sediment (ethanol): LC50 (fish, 96 hours) (mg/l): 11 200 EC50 (Daphnia, 48 hours) (mg/l): 5 012 (Ceriodaphnia dubia) IC50 (algae, 72 hours) (mg/l): 275 Aquatic compartment and sediment (diethyl ether): LC50 (fish, 48 hours) (mg/l): 2 840 (Leuciscus idus)

12.2 Persistence and degradability

Degradation reactions of abiotics (diethyl ether): Hydrolysis: Resistant to hydrolysis, t ½ (20 °C, pH 7) > 1 - <36 years Photolysis: t ½ (air) = 38 d; t ½ (air, 100 ppm NO2) = 11.5 h Biodegradability (diethyl ether): Biodegradable in fresh water: Easily biodegradable, degradability (%): 4d: 80 ; 8d: 88 ; 15d: 90 ; 28d: 97 Anaerobic degradability: Easily biodegradable (expert judgment) Biodegradable in salt water: Intrinsically biodegradable, degradability (%): 5d: 45 *); 10d: 68 ; 15d: 72 ; 28d: 75 *) Mixture of salt water and waste water, O2 consumption

12.3 Bioaccumulative potential

Aquatic bioaccumulation (diethyl ether): No test data available. BFC = 3.2 (estimate based on a calculation method). No remarkable bioaccumulation capacity (log Kow <4 and BCF <500).

No remarkable bioaccumulation capacity (log Kow <4 and BCF <500).

12.4 Mobility in soil

Diethyl ether: Mobility/leaching: Henry's law (Henry constant): 3.3. 10-6 atm. M3/mol, without dimensions: 1.38. 10-4 (calculation). Distribution: Model calculation according to Mackay, EPIWIN: air 45.0% ; water 33.1% ; soil 13.7% ; sediment 0.1%

12.5 Results of PBT and vPvB assessment

Does not meet the PBT and vPvB criteria according to Annex XIII of Regulation (EC) No. 1907/2006.

The substance does not meet the PBT and vPvB criteria according to Annex XIII of Regulation (EC) No. 1907/2006.

12.6 Other adverse effects

Chemical oxygen demand: COD = 1 900 mg/g Biochemical oxygen demand: BOD5 = 1 000 mg/g Other information: The product should not be allowed in water without pre-treatment.

The product has a COD of 1 900 mg/g and a BOD5 of 1 000 mg/g. It should not be discharged into water without pre-treatment.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not dispose of waste together with household waste. Prevent waste from entering the sewage system. (Dirt) incineration is recommended.

Disposal

National or regional regulations must be observed.

Waste Codes

07 01 04 EURAL
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1170
Shipping Name
ETHANOL (ETHYL ALCOHOL)
Transport Class
3
Packing Group
II
ADR

Individual transport: In case of transport in cars: observe national regulations or guidelines. Transportation within or outside the company premises: No additional measures required.

IMDG

Individual transport: In case of transport in cars: observe national regulations or guidelines. Transportation within or outside the company premises: No additional measures required.

IATA

Individual transport: In case of transport in cars: observe national regulations or guidelines. Transportation within or outside the company premises: No additional measures required.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Not applicable.

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Ethanol 70% V/V denatured known by?

Ethanol 70% V/V denatured is also known as: Ethanolum 70% V/V denaturus, Ethanol 70% V/V gedenatureerd, Ethanol 70% V/V dénaturé, Ethanol 70% V/V vergällt

What is the hazard signal word for Ethanol 70% V/V denatured?

The signal word is danger.

What is the physical form of Ethanol 70% V/V denatured?

Ethanol 70% V/V denatured is a liquid appearing as colourless, clear liquid with colourless color. It has characteristic odour of alcohol and ether odor.

What is the solubility of Ethanol 70% V/V denatured?

Not available.

What is Ethanol 70% V/V denatured used for?

Active Pharmaceutical Ingredient or Excipient.

What are the hazard statements for Ethanol 70% V/V denatured?

This substance has 2 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H319: Causes serious eye irritation.

What is the melting point of Ethanol 70% V/V denatured?

The melting point is -114 °C (ethanol) and the boiling point is 78 °C (ethanol).