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Safety Data Sheet EN

Ethanol ≥98 %, technical, denatured

CAS 64-17-5
EC 200-578-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ethanol ≥98 %, technical, denatured
Product Code
1Y81
Chemical Name
Ethanol
Synonyms
Ethyl alcohol

Regulatory Identifiers

CAS Number
64-17-5 Check regulations →
EC Number
200-578-6 Check regulations →
REACH No.
01-2119457610-43-xxxx
UFI Code
YRY3-H0D4-D00C-1WCM

Identified Uses

Laboratory chemical Laboratory and analytical use Formulation [mixing] of preparations and/or re-packaging (excluding alloys)

Uses advised against

Do not use for private purposes (household). Food, drink and animal feedingstuffs. Authorisations and/or restrictions on use see section 15 "restrictions".

Manufacturers & Suppliers

Carl Roth GmbH + Co. KG logo

Carl Roth GmbH + Co. KG

manufacturer

Schoemperlenstr. 3-5, D-76185 Karlsruhe, Germany

+49 (0) 721 - 56 06 0

http://www.carlroth.de

Emergency Contacts

National Poisons Information Centre Beaumont Hospital

+353 1 809 2166

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapour
H319 Causes serious eye irritation

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P233 Keep container tightly closed
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethanol EC: 200-578-6 64-17-5 --- No
2-Propanol EC: 200-661-7 67-63-0 1 - 2% No
2-Butanone EC: 201-159-0 78-93-3 1 - 2% No
Bitrex 3734-33-6 0.1% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Symptoms: Breathing difficulties, Vertigo, Drowsiness, Narcosis

Skin contact

Rinse skin with water/shower. In all cases of doubt, or when symptoms persist, seek medical advice.

Symptoms: Irritation

Eye contact

Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. In case of eye irritation consult an ophthalmologist.

Symptoms: Irritation

Ingestion

Rinse mouth. Call a doctor if you feel unwell.

Symptoms: Nausea, Vomiting, Abdominal pain

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

co-ordinate firefighting measures to the fire surroundings! water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)

Unsuitable media

water jet

Specific hazards

Combustible. In case of insufficient ventilation and/or in use, may form flammable/explosive vapour-air mixture. Solvent vapours are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures. Vapours are heavier than air, spread along floors and form explosive mixtures with air. Vapours may form explosive mixtures with air.

Instructions

Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

Wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

Cleanup methods

Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents). Place in appropriate containers for disposal.

Materials: sand, diatomaceous earth, acid- or universal binding agents

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Provision of sufficient ventilation. Use extractor hood (laboratory). Keep away from sources of ignition - No smoking. Use only in well-ventilated areas. Take precautionary measures against static discharge. Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools.

Storage

Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight.

Hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs. When using do not smoke.

Fire prevention

Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Ground/bond container and receiving equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The times are approximate values from measurements at 22 °C and permanent contact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effective layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred to substance mixtures, they may only be considered as a guide. Type of material: Butyl caoutchouc (butyl rubber). Material thickness: 0,7 mm. Breakthrough times of the glove material: >480 minutes (permeation: level 6)

Eyes

Use safety goggle with side protection.

Respiratory

Respiratory protection necessary at: Aerosol or mist formation. Type: A (against organic gases and vapours with a boiling point of > 65 °C, colour code: Brown).

Skin/Body

Flame-retardant protective clothing.

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
---
Odor
pungent
Odor Threshold
0,1 - 5.058 ppm
Ph
7 (in aqueous solution: 10 g/l, 20 °C) (neutral)
Melting Point
-114 °C
Boiling Point
78 °C at 1.013 hPa
Flash Point
12 °C (c.c.)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
57,26 hPa at 19,6 °C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0,79 g/cm³ at 20 °C
Flammability
flammable liquid in accordance with GHS criteria
Upper Explosive Limit
13,5 vol%
Lower Explosive Limit
2,5 vol%
Explosive Limits
---
Auto Ignition Temperature
455 °C at 1.013 hPa (ECHA) (auto-ignition temperature (liquids and gases))
Decomposition Temperature
not relevant
Solubility
completely miscible with water
Partition Coefficient
-0,35 (pH value: 7,4, 24 °C) (ECHA)
Solubility In Water
≥1.000 g/l at 20 °C (ECHA)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0,544 - 0,59 mPa s at 25 °C
Kinematic Viscosity
not determined
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Reactivity

It's a reactive substance. Risk of ignition. Vapours may form explosive mixtures with air.

Hazardous reactions

Violent reaction with: strong oxidiser, Alkali metals, Alkaline earth metal, Acetic anhydride, Peroxides, Phosphorus oxides (e.g. P2O5), Nitric acid, Nitrate, Perchlorates, => Explosive properties

Avoid

If heated

Incompatible

Rubber articles, different plastics

Decomposition

Hazardous combustion products: see section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Shall not be classified as hazardous to the aquatic environment. Aquatic toxicity (acute) | Endpoint | Value | Species | Source | Exposure time | | --- | --- | --- | --- | --- | | LC50 | 15.400 mg/l | fish | ECHA | 96 h | | EC50 | >10.000 mg/l | aquatic invertebrates | ECHA | 48 h | | ErC50 | 22.000 mg/l | algae | ECHA | 96 h | Aquatic toxicity (acute) of components | Name of substance | CAS No | Endpoint | Value | Species | Exposure time | | --- | --- | --- | --- | --- | --- |

Shall not be classified as hazardous to the aquatic environment.

12.1 Toxicity

Aquatic toxicity (acute) of components | Name of substance | CAS No | Endpoint | Value | Species | Exposure time | | 2-Butanone | 78-93-3 | LC50 | 2.993 mg/l | fish | 96 h | | 2-Butanone | 78-93-3 | EC50 | 308 mg/l | aquatic invertebrates | 48 h | | 2-Butanone | 78-93-3 | ErC50 | 1.972 mg/l | algae | 72 h |

12.1 Toxicity

Aquatic toxicity (acute) of components: 2-Propanol (67-63-0), LC50, 10.000 mg/l, fish, 96 h. Aquatic toxicity (chronic): NOEC, 250 mg/l, fish, 120 h; NOEC, 2 mg/l, aquatic invertebrates, 10 d. Aquatic toxicity (chronic) of components: 2-Propanol (67-63-0), NOELR, >1.000 mg/l, fish, 28 d.

12.2 Persistence and degradability

Theoretical Oxygen Demand: 2,084 mg/mg Theoretical Carbon Dioxide: 1,911 mg/mg ## Biodegradation The substance is readily biodegradable. Process of degradability | Process | Degradation rate | Time | | --- | --- | --- | | biotic/abiotic | 94 % | d | | oxygen depletion | 69 % | 5 d | Degradability of components | Name of substance | CAS No | Process | Degradation rate | Time | Method | Source | | --- | --- | --- | --- | --- | --- | --- |

The substance is readily biodegradable.

12.2 Persistence and degradability

Degradability of components | Name of substance | CAS No | Process | Degradation rate | Time | Method | Source | | 2-Butanone | 78-93-3 | oxygen depletion | 98 % | 28 d | | ECHA |

12.2 Persistence and degradability

Degradability of components | Name of substance | CAS No | Process | Degradation rate | Time | Method | Source | | 2-Propanol | 67-63-0 | biotic/abiotic | 95 % | 21 d | modifizierter OECD Screening Test | | | 2-Propanol | 67-63-0 | oxygen depletion | 53 % | 5 d | | ECHA |

12.3 Bioaccumulative potential

Does not significantly accumulate in organisms. | n-octanol/water (log KOW) | -0,35 (pH value: 7,4, 24 °C) (ECHA) | | --- | --- | Bioaccumulative potential of components | Name of substance | CAS No | BCF | Log KOW | BOD5/COD | | --- | --- | --- | --- | --- |

Does not significantly accumulate in organisms.

Bioaccumulative potential of components

Bioaccumulative potential of components | Name of substance | CAS No | BCF | Log KOW | BOD5/COD | | 2-Butanone | 78-93-3 | | 0,3 (pH value: 7, 40 °C) | |

Bioaccumulative potential of components

Bioaccumulative potential of components | Name of substance | CAS No | BCF | Log KOW | BOD5/COD | | 2-Propanol | 67-63-0 | | 0,05 | |

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

According to the results of its assessment, this substance is not a PBT or a vPvB.

The substance is not a PBT or a vPvB.

12.6 Endocrine disrupting properties

Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

12.7 Other adverse effects

Data are not available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of contents/container in accordance with local/regional/national/international regulations.

Disposal

This material and its container must be disposed of as hazardous waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1170
Shipping Name
ETHANOL
Transport Class
3
Packing Group
II
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Ethanol ≥98 %, technical, denatured known by?

Ethanol ≥98 %, technical, denatured is also known as: Ethyl alcohol

What is the hazard signal word for Ethanol ≥98 %, technical, denatured?

The signal word is danger.

What is the physical form of Ethanol ≥98 %, technical, denatured?

Ethanol ≥98 %, technical, denatured is a liquid with colourless color. It has pungent odor.

What is the solubility of Ethanol ≥98 %, technical, denatured?

completely miscible with water

What is Ethanol ≥98 %, technical, denatured used for?

Laboratory chemical Laboratory and analytical use Formulation [mixing] of preparations and/or re-packaging (excluding alloys)

What are the hazard statements for Ethanol ≥98 %, technical, denatured?

This substance has 2 hazard statements:

  • H225: Highly flammable liquid and vapour
  • H319: Causes serious eye irritation

What is the melting point of Ethanol ≥98 %, technical, denatured?

The melting point is -114 °C and the boiling point is 78 °C at 1.013 hPa.