Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- 1,4-Diazabicyclo[2.2.2]octane
- Product Code
- D27802
Regulatory Identifiers
- CAS Number
- 280-57-9 Check regulations →
- REACH No.
- 01-2119980944-22-XXXX
Identified Uses
Laboratory chemicals, Manufacture of substances
Manufacturers & Suppliers
Sigma-Aldrich Chemie GmbH
manufacturer
Eschenstrasse 5, D-82024 TAUFKIRCHEN
+49 (0)89 6513-1130
Emergency Contacts
CHEMTREC Deutschland
0800 181 7059
CHEMTREC weltweit
+49 (0)696 43508409
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS05
GHS07
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| 1,4-Diazabicyclo[2.2.2]octane EC: 205-999-9 | 280-57-9 | 100% | Yes |
First Aid Measures
Emergency procedures for chemical exposure incidents
After inhalation: fresh air.
Take off immediately all contaminated clothing. Rinse skin with water/ shower.
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Water, Foam, Carbon dioxide (CO2), Dry powder
For this substance/mixture no limitations of extinguishing agents are given.
Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.
Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet.
Firefighter Protection
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.
Do not let product enter drains. Risk of explosion.
Take up dry. Clean up affected area.
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Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Tightly closed. Keep away from heat and sources of ignition.
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Keep away from open flames, hot surfaces and sources of ignition.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Flame retardant antistatic protective clothing.
Do not let product enter drains. Risk of explosion.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The product is chemically stable under standard ambient conditions (room temperature).
Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.
Violent reactions possible with: mineral acids, Strong oxidizing agents, peroxi compounds, iron/iron-containing compounds, acids. Risk of explosion with: hydrogen peroxide
Exposure to moisture. Strong heating.
Aluminum, Iron, Copper, Zinc
In the event of fire: see section 5
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulative potential
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
The substance/mixture does not contain PBT or vPvB components at levels of 0.1% or higher.
12.6 Endocrine disrupting properties
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
12.7 Other adverse effects
No data available
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
No data available
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- 1325
- Shipping Name
- FLAMMABLE SOLID, ORGANIC, N.O.S. (1,4-Diazabicyclo[2.2.2]octane)
- Transport Class
- 4.1
- Packing Group
- II
Regulatory Information
Chemical regulations, safety assessments, and compliance status
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for 1,4-Diazabicyclo[2.2.2]octane?
The signal word is danger.
What is the physical form of 1,4-Diazabicyclo[2.2.2]octane?
1,4-Diazabicyclo[2.2.2]octane is a crystalline with white color. It has ammonia odor odor.
What is 1,4-Diazabicyclo[2.2.2]octane used for?
Laboratory chemicals, Manufacture of substances
What are the hazard statements for 1,4-Diazabicyclo[2.2.2]octane?
This substance has 4 hazard statements:
- H228: Flammable solid.
- H302: Harmful if swallowed.
- H315: Causes skin irritation.
- H318: Causes serious eye damage.
What is the melting point of 1,4-Diazabicyclo[2.2.2]octane?
The melting point is 156 - 159 °C and the boiling point is 173,4 °C at 1.000 hPa.