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Safety Data Sheet EN

PR 1564 BLK Part A

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
PR 1564 BLK Part A
Product Code
PR 1564 BLK Part A

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial applications. Sealants

Uses advised against

Product is not intended, labelled or packaged for consumer use.

Manufacturers & Suppliers

P

PPG Coatings S.A.

manufacturer

7, Allée de la Plaine, Gonfreville l'Orcher, 76700 HARFLEUR, France

+33 (0)2 3553 5400

P

PPG Industries (UK) Ltd

manufacturer

3 Darlington Road, Shildon, Co Durham DL4 2QP, England

+44 (0) 1388 772 541

Emergency Contacts

Emergency Contact

+33 (0)3 27 19 35 00

0800-1700

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Repr. Cat. 1B H360
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H336 May cause drowsiness or dizziness.
H360 May damage fertility or the unborn child.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye or face protection.
P308 + P313 IF exposed or concerned: Get medical advice or attention.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
propylidynetrimethanol EC: 201-074-9 77-99-6 25 - 50% Yes
butane-1,4-diol EC: 203-786-5 110-63-4 25 - 50% Yes
Terphenyl, hydrogenated EC: 262-967-7 61788-32-7 1 - 5% Yes
2-methylimidazole EC: 211-765-7 693-98-1 1% Yes
terphenyl EC: 247-477-3 26140-60-3 0.3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced foetal weight increase in foetal deaths skeletal malformations

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners.

Symptoms: No known significant effects or critical hazards. Adverse symptoms may include the following: reduced foetal weight increase in foetal deaths skeletal malformations

Eye contact

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Symptoms: No known significant effects or critical hazards. No specific data.

Ingestion

If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: Can cause central nervous system (CNS) depression. Adverse symptoms may include the following: reduced foetal weight increase in foetal deaths skeletal malformations

Immediate Medical Attention

Seek immediate medical advice for eye contact and ingestion.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

None known.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Collect spillage.

Materials: sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapour or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. When prolonged or frequently repeated contact may occur, a glove with a protection class of 6 (breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30 minutes according to EN 374) is recommended. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use, as included in the user's risk assessment. For prolonged or repeated handling, use the following type of gloves: Recommended: nitrile rubber, natural rubber (latex)

Eyes

Safety glasses with side shields. Use eye protection according to EN 166.

Respiratory

Use with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wear a respirator conforming to EN140. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Mask type: full-face mask half-face mask Filter type: organic vapour filter (Type A) particulate filter P3 Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Black
Colour Intensity
---
Form
---
Odor
Not available.
Odor Threshold
Not available.
Ph
insoluble in water.
Melting Point
May start to solidify at the following temperature: 19.4 to 21.2°C (66.9 to 70.2°F ) This is based on data for the following ingredient: butane-1,4-diol. Weighted average: 16.02°C (60.8°F)
Boiling Point
228.89 to 288.89°C
Flash Point
Closed cup: 93.33°C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
butane-1,4-diol: <0.08 mm Hg (<0.011 kPa)
Vapor Density
Highest known value: 7.95 (Air = 1) (Terphenyl, hydrogenated). Weighted average: 3.57 (Air = 1)
Relative Density
1.06
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
Terphenyl, hydrogenated: 374 °C (705.2 °F)
Decomposition Temperature
---
Solubility
---
Partition Coefficient
Not applicable.
Solubility In Water
Insoluble in the following materials: cold water.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (40°C): >21 mm²/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

When exposed to high temperatures may produce hazardous decomposition products. Refer to protective measures listed in sections 7 and 8.

Incompatible

Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strong acids.

Decomposition

Depending on conditions, decomposition products may include the following materials: carbon oxides Formaldehyde.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | propylidynetrimethanol | Acute LC50 >1000 mg/l | Fish | 96 hours |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | terphenyl | Acute EC50 0.022 mg/l | Daphnia | 48 hours | | | Chronic NOEC 0.00322 mg/l | Daphnia | 72 hours |

12.2 Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | terphenyl | - | - | Not readily |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | propylidynetrimethanol | -0.47 | - | low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | butane-1,4-diol | -0.88 | - | low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | 2-methylimidazole | 0.24 | - | low |

12.4 Mobility in soil

Soil/water partition : Not available. coefficient (Koc) Mobility : Not available.

12.5 Results of PBT and vPvB assessment

Product/ingredient name | PBT | P | B | T | vPvB | vP | vB

12.5 Results of PBT and vPvB assessment

| Product/ingredient name | PBT | P | B | T | vPvB | vP | vB | | Butane-1,4-diol | No | N/A | N/A | No | N/A | N/A | N/A |

The substance Butane-1,4-diol is not considered to be PBT or vPvB.

12.5 Results of PBT and vPvB assessment

| Product/ingredient name | PBT | P | B | T | vPvB | vP | vB | | Terphenyl, hydrogenated | No | N/A | N/A | No | SVHC (Candidate) | Specified | Specified |

The substance Terphenyl, hydrogenated is not classified as PBT, but is identified as an SVHC (Candidate) for vPvB.

12.6 Other adverse effects

No known significant effects or critical hazards.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Waste Codes

08 04 10 waste adhesives and sealants other than those mentioned in 08 04 09 EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Terphenyl, hydrogenated)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for PR 1564 BLK Part A?

The signal word is danger.

What is the physical form of PR 1564 BLK Part A?

PR 1564 BLK Part A is a liquid with black color. It has not available. odor.

What is PR 1564 BLK Part A used for?

Industrial applications. Sealants

What are the hazard statements for PR 1564 BLK Part A?

This substance has 3 hazard statements:

  • H336: May cause drowsiness or dizziness.
  • H360: May damage fertility or the unborn child.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of PR 1564 BLK Part A?

The melting point is May start to solidify at the following temperature: 19.4 to 21.2°C (66.9 to 70.2°F ) This is based on data for the following ingredient: butane-1,4-diol. Weighted average: 16.02°C (60.8°F) and the boiling point is 228.89 to 288.89°C.