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Safety Data Sheet EN

PR 1564 BLK Part B

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
PR 1564 BLK Part B
Product Code
PR 1564 BLK Part B

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial applications. Sealants

Uses advised against

Product is not intended, labelled or packaged for consumer use.

Manufacturers & Suppliers

P

PPG Coatings S.A.

manufacturer

7, Allée de la Plaine, Gonfreville l'Orcher, 76700 HARFLEUR, France

+33 (0)2 3553 5400

P

PPG Industries (UK) Ltd

manufacturer

3 Darlington Road, Shildon, Co Durham DL4 2QP, England

+44 (0) 1388 772 541

Emergency Contacts

Emergency Contact

+33 (0)3 27 19 35 00

0800-1700

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Acute Tox. Cat. 3 H331
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
Carc. Cat. 2 H351
STOT SE Cat. 3 H335

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 + H312 Harmful if swallowed or in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing vapour.
P280 Wear protective gloves, protective clothing and eye or face protection.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Poly[oxy(methyl-1,2-ethanediyl)], α-hydro-ω-hydroxy-, polymer with 1,3-diisocyanatomethylbenzene 9057-91-4 90% Yes
m-tolylidene diisocyanate EC: 247-722-4 26471-62-5 1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Toxic if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Adverse symptoms may include the following: respiratory tract irritation, coughing, wheezing and breathing difficulties, asthma

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners.

Symptoms: Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: irritation, redness

Eye contact

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Symptoms: Causes serious eye irritation. Adverse symptoms may include the following: pain or irritation, watering, redness

Ingestion

If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: Harmful if swallowed.

Immediate Medical Attention

Seek immediate medical advice for eye contact and ingestion.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

None known.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material.

Materials: non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitisation problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. When prolonged or frequently repeated contact may occur, a glove with a protection class of 6 (breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30 minutes according to EN 374) is recommended. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use, as included in the user's risk assessment. Gloves: butyl rubber

Eyes

Chemical splash goggles. Use eye protection according to EN 166.

Respiratory

Use with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wear a respirator conforming to EN140. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Mask type: full-face mask half-face mask Filter type: organic vapour filter (Type A) particulate filter P3 Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Not available.
Colour Intensity
---
Form
---
Odor
Not available.
Odor Threshold
Not available.
Ph
Not applicable. insoluble in water.
Melting Point
May start to solidify at the following temperature: 4°C (39.2°F) This is based on data for the following ingredient: m-tolylidene diisocyanate.
Boiling Point
>37.78°C
Flash Point
Closed cup: 204.44°C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
0.01 mm Hg (at 20°C) (m-tolylidene diisocyanate)
Vapor Density
Highest known value: 6 (Air = 1) (m-tolylidene diisocyanate).
Relative Density
1.06
Bulk Density
---
Density
---
Flammability
liquid
Upper Explosive Limit
Greatest known range: Upper: 9.5% (m-tolylidene diisocyanate)
Lower Explosive Limit
Greatest known range: Lower: 0.9% (m-tolylidene diisocyanate)
Explosive Limits
---
Auto Ignition Temperature
>595°C
Decomposition Temperature
Stable under recommended storage and handling conditions (see Section 7).
Solubility
---
Partition Coefficient
Not applicable.
Solubility In Water
Insoluble in the following materials: cold water.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (40°C): >21 mm²/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

In a fire, hazardous decomposition products may be produced. Refer to protective measures listed in sections 7 and 8.

Incompatible

oxidising agents, strong alkalis, strong acids, amines, alcohols, water

Decomposition

Depending on conditions, decomposition products may include the following materials: Cyanate and isocyanate. carbon oxides nitrogen oxides hydrogen cyanide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | m-tolylidene diisocyanate | Acute EC50 12.5 mg/l | Daphnia | 48 hours |

12.2 Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | m-tolylidene diisocyanate | - | - | Not readily |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | m-tolylidene diisocyanate | 3.43 | - | low |

12.4 Mobility in soil

Soil/water partition coefficient $(K_{oc})$ : Not available. Mobility : Not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

The mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects

No known significant effects or critical hazards.

No known significant effects or critical hazards.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2810
Shipping Name
TOXIC LIQUID, ORGANIC, N.O.S. (m-tolylidene diisocyanate)
Transport Class
6.1
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

EU Regulation (EC) No. 1907/2006 (REACH)

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for PR 1564 BLK Part B?

The signal word is danger.

What is the physical form of PR 1564 BLK Part B?

PR 1564 BLK Part B is a liquid. with not available. color. It has not available. odor.

What is PR 1564 BLK Part B used for?

Industrial applications. Sealants

What are the hazard statements for PR 1564 BLK Part B?

This substance has 8 hazard statements:

  • H302 + H312: Harmful if swallowed or in contact with skin.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H331: Toxic if inhaled.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H335: May cause respiratory irritation.
  • H351: Suspected of causing cancer.

What is the melting point of PR 1564 BLK Part B?

The melting point is May start to solidify at the following temperature: 4°C (39.2°F) This is based on data for the following ingredient: m-tolylidene diisocyanate. and the boiling point is >37.78°C.