p-Phenylenediamine

Remove to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Symptoms: trouble breathing, dizziness, lightheadedness, chest pain

Wash off immediately with plenty of water for at least 15 minutes.

Symptoms: allergic skin reaction, rash, itching, swelling, tingling of the hands and feet, muscle pain, flushing

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Do NOT induce vomiting. Call a physician or poison control center immediately.

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

No information available.

Thermal decomposition can lead to release of irritating gases and vapors.

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas.

Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains.

Sweep up and shovel into suitable containers for disposal.

Do not get in eyes, on skin, or on clothing. Wear personal protective equipment/face protection. Avoid dust formation. Use only under a chemical fume hood. Do not breathe (dust, vapor, mist, gas). Do not ingest. If swallowed then seek immediate medical assistance.

Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Material darkens in color during storage. Keep under nitrogen.

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Protective gloves. Glove material: Natural rubber, Nitrile rubber, Neoprene, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement). Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

Wear safety glasses with side shields (or goggles) Goggles (European standard - EN 166)

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particulates filter conforming to EN 143. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141 When RPE is used a face piece Fit Test should be conducted

Long sleeved clothing.

Prevent product from entering drains. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained.

Air sensitive.

None known, based on information available

Hazardous polymerization does not occur. None under normal processing.

Exposure to air. Incompatible products.

Acids. Strong oxidizing agents. Acid anhydrides. Acid chlorides.

Nitrogen oxides (NOx). Carbon monoxide (CO). Carbon dioxide (CO₂).

Should not be released into the environment. Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Should not be released into the environment. Waste is classified as hazardous.