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Safety Data Sheet EN

p-Phenylenediamine

CAS 106-50-3
EC 203-404-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
p-Phenylenediamine
Product Code
A15680, L02688
Chemical Name
p-Phenylenediamine

Regulatory Identifiers

CAS Number
106-50-3 Check regulations →
EC Number
203-404-7 Check regulations →

Identified Uses

SU24 Scientific research and development

Manufacturers & Suppliers

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc. logo

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

800-343-0660

http://www.alfa.com

Emergency Contacts

Emergency Contact

(800) 343-0660

Monday-Friday, 8am-7pm EST

Carechem 24

(866) 928-0789

After normal business hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
Eye Irrit. Cat. 2A H319
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS07 - Health hazard

GHS07

Hazard Statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

CAS# Description: 106-50-3 p-Phenylenediamine

Chemical Name CAS Number Concentration Hazardous
p-Phenylenediamine EC: 203-404-7 106-50-3 100% No

Notes

Concentration: ≥100%

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Symptoms: Toxic if inhaled.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Symptoms: Toxic in contact with skin. May cause an allergic skin reaction.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Symptoms: Causes serious eye irritation.

Ingestion

Do not induce vomiting; immediately call for medical help.

Symptoms: Toxic if swallowed.

Immediate Medical Attention

No further relevant information available.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Specific hazards

If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide, Nitrogen oxides (NOx)

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away.

Environmental

Do not allow material to be released to the environment without proper governmental permits.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep container tightly sealed. Open and handle container with care.

Storage

Store in cool, dry place in tightly closed containers.

Fire prevention

No information known.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Material of gloves Nitrile rubber, NBR. Penetration time of glove material (in minutes) 480. Glove thickness: 0.11 mm.

Eyes

Safety glasses with side shields / NIOSH (US) or EN 166(EU).

Respiratory

Use self-contained respiratory protective device in emergency situations. Recommended filter device for short term use: Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
---
Physical State Data
---
State Under Standard Conditions
---
Appearance
Crystalline
Colour
---
Colour Intensity
---
Form
---
Odor
Weak
Odor Threshold
Not determined.
Ph
Not applicable.
Melting Point
138-142 °C (280-288 °F)
Boiling Point
267-271 ℃ (513-520 °F)
Flash Point
156 °C (313 ºF)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable.
Vapor Pressure
1.4 hPa (1 mm Hg)
Vapor Density
Not applicable.
Relative Density
Not determined.
Bulk Density
---
Density
Not determined
Flammability
Not determined.
Upper Explosive Limit
9.8 Vol %
Lower Explosive Limit
1.3 Vol %
Explosive Limits
---
Auto Ignition Temperature
620 °C (1148 °F)
Decomposition Temperature
Not determined
Solubility
---
Partition Coefficient
Not determined.
Solubility In Water
47 g/l
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not applicable.
Kinematic Viscosity
Not applicable.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Aquatic toxicity: No further relevant information available. Ecotoxical effects: Remark: Very toxic for aquatic organisms

The substance is noted as being very toxic for aquatic organisms.

12.2 Persistence and degradability

No further relevant information available.

No further relevant information available.

12.3 Bioaccumulative potential

No further relevant information available.

No further relevant information available.

12.4 Mobility in soil

No further relevant information available.

No further relevant information available.

12.5 Results of PBT and vPvB assessment

PBT: Not applicable. vPvB: Not applicable.

The substance is not considered PBT or vPvB.

12.6 Endocrine disrupting properties

No further relevant information available.

No further relevant information available.

12.7 Other adverse effects

No further relevant information available.

No further relevant information available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1673
Shipping Name
Phenylenediamines
Transport Class
6.1
Packing Group
III
ADR

Warning: Toxic substances

IMDG

Warning: Toxic substances

IATA

Warning: Toxic substances

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for p-Phenylenediamine?

The signal word is danger.

What is p-Phenylenediamine used for?

SU24 Scientific research and development

What are the hazard statements for p-Phenylenediamine?

This substance has 3 hazard statements:

  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.

What is the melting point of p-Phenylenediamine?

The melting point is 138-142 °C (280-288 °F) and the boiling point is 267-271 ℃ (513-520 °F).