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Safety Data Sheet EN

21.7-50% Oxygen in Helium

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
21.7-50% Oxygen in Helium

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial and professional use for chemical analysis, calibration, (routine) quality control, laboratory use, under controlled conditions.

Uses advised against

Consumer use. Uses other than those listed above are not supported, contact your supplier for more information on other uses.

Manufacturers & Suppliers

A

Air Liquide Oil & Gas Services Ltd.

national supplier

Greenbank Road, AB12 3BQ Aberdeen, United Kingdom

Emergency Contacts

Emergency Contact

01675 462695

Available 24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Ox. Gas Cat. 1 H270
Press. Gas (Comp.) H280

GHS Pictograms

GHS03 - Oxidizing

GHS03

GHS04 - Compressed gas

GHS04

Hazard Statements

H270 May cause or intensify fire; oxidiser.
H280 Contains gas under pressure; may explode if heated.

Precautionary Statements

P220 Keep away from combustible materials.
P244 Keep valves and fittings free from oil and grease.
P370 + P376 In case of fire: Stop leak if safe to do so.
P403 Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Contains no other components or impurities which will influence the classification of the product.

Chemical Name CAS Number Concentration Hazardous
Oxygen EC: 231-956-9 7782-44-7 21.7 - 50% Yes
Helium EC: 231-168-5 7440-59-7 50% Yes

*1: Listed in Annex IV / V REACH, exempted from registration. *3: Registration not required: Substance manufactured or imported < 1t/y.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to uncontaminated area. Keep victim warm and rested. Call a doctor. Perform cardiopulmonary resuscitation if breathing stopped.

Skin contact

Adverse effects not expected from this product.

Eye contact

Adverse effects not expected from this product.

Ingestion

Ingestion is not considered a potential route of exposure.

Immediate Medical Attention

None.

Medical Treatment

None.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray or fog. Product does not burn, use fire control measures appropriate for the surrounding fire.

Unsuitable media

Do not use water jet to extinguish.

Specific hazards

Supports combustion. Exposure to fire may cause containers to rupture/explode.

Instructions

Use fire control measures appropriate for the surrounding fire. Cool endangered receptacles with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems. If possible, stop flow of product. Use water spray or fog to knock down fire fumes if possible. Move containers away from the fire area if this can be done without risk.

Firefighter Protection

Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fighters. Standard EN 137 - Self-contained open-circuit compressed air breathing apparatus with full face mask. Standard EN 469 - Protective clothing for firefighters. Standard - EN 659: Protective gloves for firefighters. EN 15090 Footwear for firefighters. EN 443 Helmets for fire fighting in buildings and other structures.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Act in accordance with local emergency plan. Try to stop release. Evacuate area. Eliminate ignition sources. Ensure adequate air ventilation. Stay upwind. Monitor concentration of released product.

Environmental

Try to stop release.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not breathe gas. Avoid release of product into atmosphere. The product must be handled in accordance with good industrial hygiene and safety procedures. Only experienced and properly instructed persons should handle gases under pressure. Do not smoke while handling product. Keep equipment free from oil and grease. Use no oil or grease. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Use only oxygen approved lubricants and oxygen approved sealings. Avoid suck back of water, acid and alkalis. Refer to supplier's container handling instructions. Do not allow backfeed into the container. Protect containers from physical damage; do not drag, roll, slide or drop. When moving cylinders, use a cart. Leave valve protection caps in place until secured. If difficulty operating valve, discontinue use and contact supplier. Never attempt to repair or modify container valves or safety relief devices. Damaged valves should be reported immediately. Keep container valve outlets clean and free from contaminants. Replace valve outlet caps or plugs. Close container valve after each use and when empty. Never attempt to transfer gases. Never use direct flame or electrical heating devices. Do not remove or deface labels. Suck back of water into the container must be prevented. Open valve slowly to avoid pressure shock.

Storage

Protect containers from physical damage; do not drag, roll, slide or drop. Keep container valve outlets clean and free from contaminants particularly oil and water. Close container valve after each use and when empty.

Hygiene

The product must be handled in accordance with good industrial hygiene and safety procedures.

Fire prevention

Do not smoke while handling product. Keep equipment free from oil and grease. Use no oil or grease. Never use direct flame or electrical heating devices to raise the pressure of a container.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide adequate general and local exhaust ventilation. Systems under pressure should be regularly checked for leakages. Gas detectors should be used when oxidising gases may be released. Consider the use of a work permit system e.g. for maintenance activities.

Hands

Wear working gloves when handling gas containers. Standard EN 388 - Protective gloves against mechanical risks, performance level 1 or higher. Recommended types include wrist gloves from leather or synthetic material with equivalent performance, fabric gloves, fabric gloves with leather palms.

Eyes

Wear safety glasses with side shields.

Respiratory

Standard EN 137 - Self-contained open-circuit compressed air breathing apparatus with full face mask. When indicated by a risk assessment, Respiratory Protective Equipment must be used. The selection of the Respiratory Protective Device (RPD) must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected RPD. Self contained breathing apparatus is recommended, where unknown exposure may be expected, e.g. during maintenance activities on installation systems.

Skin/Body

Standard EN 166 - Personal eye-protection - specifications. Wear safety shoes while handling containers. Standard EN ISO 20345 - Personal protective equipment - Safety footwear.

Environmental

Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for specific methods for waste gas treatment.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Gas.
Physical State Data
gas
State Under Standard Conditions
---
Appearance
---
Colour
Colourless.
Colour Intensity
---
Form
---
Odor
Odourless.
Odor Threshold
---
Ph
Not applicable for gases and gas mixtures.
Melting Point
Not applicable for gases and gas mixtures.
Boiling Point
Component with lowest boiling point: Helium -269 °C
Flash Point
Not applicable for gases and gas mixtures.
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
Not applicable for compressed gases and gas mixtures.
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
Not applicable for gases and gas mixtures.
Flammability
Non flammable.
Upper Explosive Limit
Not applicable.
Lower Explosive Limit
Not applicable.
Explosive Limits
---
Auto Ignition Temperature
Non flammable.
Decomposition Temperature
Not applicable.
Solubility
---
Partition Coefficient
Not applicable for gas mixtures.
Solubility In Water
Not applicable for gases and gas mixtures.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Not applicable for gases and gas mixtures.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

Violently oxidises organic material.

Hazardous reactions

Violently oxidises organic material.

Avoid

Avoid moisture in installation systems.

Incompatible

May react violently with combustible materials. May react violently with reducing agents. Keep equipment free from oil and grease.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Assessment: No ecological damage caused by this product. EC50 48h - Daphnia magna [mg/l]: No data available. EC50 72h - Algae [mg/l]: No data available. LC50 96 h - Fish [mg/l]: No data available. | Oxygen (7782-44-7) | | | --- | --- | | EC50 48h - Daphnia magna [mg/l] | No data available. | | EC50 72h - Algae [mg/l] | No data available. | | Oxygen (7782-44-7) | | | --- | --- | | LC50 96 h - Fish [mg/l] | No data available. | | Helium (7440-59-7) | | | --- | --- | | EC50 48h - Daphnia magna [mg/l] | No data available. | | EC50 72h - Algae [mg/l] | No data available. | | LC50 96 h - Fish [mg/l] | No data available. |

No ecological damage caused by this product. No data available for individual components.

12.2. Persistence and degradability

Assessment : No ecological damage caused by this product.

12.3. Bioaccumulative potential

Assessment : No ecological damage caused by this product.

12.4. Mobility in soil

Assessment : No ecological damage caused by this product.

12.5. Results of PBT and vPvB assessment

Assessment : Not classified as PBT or vPvB.

Not classified as PBT or vPvB.

12.6. Endocrine disrupting properties

Assessment : The substance/mixture has no endocrine disrupting properties.

The substance/mixture has no endocrine disrupting properties.

12.7. Other adverse effects

Other adverse effects : No known effects from this product. Effect on the ozone layer : No effect on the ozone layer. Effect on global warming : No known effects from this product.

No known adverse effects, no effect on the ozone layer, and no known effects on global warming.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

May be vented to atmosphere in a well ventilated place.

Disposal

Contact supplier if guidance is required. Return unused product in original container to supplier.

Waste Codes

16 05 04 * Gases in pressure containers (including halons) containing hazardous substances. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3156
Shipping Name
COMPRESSED GAS, OXIDIZING, N.O.S. (Oxygen, Helium)
Transport Class
2
Packing Group
Not applicable
ADR

Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

IMDG

Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

IATA

Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Ensure all national/local regulations are observed.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 21.7-50% Oxygen in Helium?

The signal word is danger.

What is the physical form of 21.7-50% Oxygen in Helium?

21.7-50% Oxygen in Helium is a gas. with colourless. color. It has odourless. odor.

What is 21.7-50% Oxygen in Helium used for?

Industrial and professional use for chemical analysis, calibration, (routine) quality control, laboratory use, under controlled conditions.

What are the hazard statements for 21.7-50% Oxygen in Helium?

This substance has 2 hazard statements:

  • H270: May cause or intensify fire; oxidiser.
  • H280: Contains gas under pressure; may explode if heated.

What is the melting point of 21.7-50% Oxygen in Helium?

The melting point is Not applicable for gases and gas mixtures. and the boiling point is Component with lowest boiling point: Helium -269 °C.