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Safety Data Sheet EN

Nitrogen (0.0001 - 10%), Helium (Balance)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Nitrogen (0.0001 - 10%), Helium (Balance)
Product Code
M-23021/E-1

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Calibration Gas

Manufacturers & Suppliers

Air Liquide logo

Air Liquide

manufacturer

2700 Post Oak Blvd., Houston, TX 77056, United States

713-896-2896

http://www.us.airliquide.com

Emergency Contacts

CHEMTREC

800-424-9300

CHEMTREC (Outside United States)

+1 703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Press. Gas (Comp.) H280
Not Classified

GHS Pictograms

GHS04 - Compressed gas

GHS04

Hazard Statements

H280 Contains gas under pressure; may explode if heated
H280 May displace oxygen and cause rapid suffocation.

Precautionary Statements

P403 Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Nitrogen EC: 231-783-9 7727-37-9 0.0001 - 10% Yes
Helium EC: 231-168-5 7440-59-7 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. If signs/symptoms continue, get medical attention.

Symptoms: Anoxia

Skin contact

Although exposure is unlikely, in case of contact immediately flush skin with running water. If skin irritation develops get medical advice/attention.

Eye contact

First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. If irritation develops and persists, get medical attention.

Ingestion

Ingestion is not considered a potential route of exposure.

Immediate Medical Attention

Victim(s) who experience any adverse effect after overexposure to this gas mixture must be taken for medical attention.

Medical Treatment

All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. A potential health hazard associated with this gas is anoxia.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing agent suitable for type of surrounding fire.

Unsuitable media

None known.

Specific hazards

Containers may explode when heated. Ruptured cylinders may rocket.

Instructions

Move containers from fire area if you can do it without risk. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire.

Firefighter Protection

Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. Always wear thermal protective clothing when handling refrigerated/cryogenic liquids. Wear positive pressure self-contained breathing apparatus (SCBA).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Stop leak if you can do it without risk. Keep unauthorized personnel away. Keep out of low areas. Stay upwind. Do not direct water at spill or source of leak.

Large spill

Consider initial downwind evacuation for at least 500 meters (1/3 mile)

Environmental

Prevent spreading of vapors through sewers, ventilation systems and confined areas.

Cleanup methods

Use water spray to reduce vapors; do not put water directly on leak, spill area or inside container.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only with adequate ventilation. Ventilate closed spaces before entering. Be aware of any signs of dizziness or fatigue, especially if work is done in a poorly ventilated area; exposures to fatal concentrations of this gas mixture could occur without any significant warning symptoms, due to olfactory fatigue or oxygen deficiency. Cylinders should be firmly secured to prevent falling or being knocked-over. Do not attempt to repair, adjust, or in any other way modify cylinders. If there is a malfunction or another type of operational problem, contact nearest distributor immediately. Empty containers retain product residue and can be hazardous. Do not cut, weld, puncture or incinerate container.

Storage

Store in a cool, dry, well-ventilated place. Protect cylinders against physical damage. Cylinders should be firmly secured to prevent falling or being knocked-over.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Hands

Wear leather gloves when handling cylinders.

Eyes

Wear safety glasses.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or symptoms are experienced.

Skin/Body

Wear leather gloves when handling cylinders.

Environmental

Follow best practice for site management and disposal of waste. Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Colour Intensity
---
Relative Density
Data lacking
Softening Point
---
Freezing Point
---
Dynamic Viscosity
---
Colour
Colorless
Voc Content
---
Evaporation Rate
Data lacking
Odor Threshold
Data lacking
Flammability
Not flammable.
Bulk Density
---
Vapor Density
0.221 Air=1
Odor
Odorless
Physical State
Gas
Crystallisation Point
---
State Under Standard Conditions
---
Solidification Point
---
Upper Explosive Limit
Not relevant
Explosive Limits
---
Properties Status
---
Flash Point
Not relevant
Decomposition Temperature
Data lacking
Relative Evaporation Rate
---
Vapor Pressure
Data lacking
Solubility In Water
Slightly Soluble
Kinematic Viscosity
---
Density
---
Partition Coefficient
Data lacking
Molecular Weight
---
Form
---
Cloud Point
---
Metal Corrosion
---
Lower Explosive Limit
Not relevant
Solubility
---
Appearance
Colorless gas with no odor.
Boiling Point
-268.94 C(-452.092 F)
Melting Point
-272 C(-457.6 F)
Auto Ignition Temperature
Not relevant
Physical State Data
gas
Ph
Not relevant
Solubility In Fat
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal temperatures and pressures.

Reactivity

No dangerous reaction known under conditions of normal use.

Hazardous reactions

Hazardous polymerization will not occur.

Avoid

Excess heat.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.

Disposal

Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1956
Shipping Name
Compressed gas, n.o.s. (Helium, Nitrogen)
Transport Class
2.2
Packing Group
NDA
ADR

Cylinders should be transported in a secure position, in a well-ventilated vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles can present serious safety hazards. If transporting these cylinders in vehicles, ensure these cylinders are not exposed to extremely high temperatures (as may occur in an enclosed vehicle on a hot day). Additionally, the vehicle should be well-ventilated during transportation.

IMDG

Cylinders should be transported in a secure position, in a well-ventilated vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles can present serious safety hazards. If transporting these cylinders in vehicles, ensure these cylinders are not exposed to extremely high temperatures (as may occur in an enclosed vehicle on a hot day). Additionally, the vehicle should be well-ventilated during transportation.

IATA

Cylinders should be transported in a secure position, in a well-ventilated vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles can present serious safety hazards. If transporting these cylinders in vehicles, ensure these cylinders are not exposed to extremely high temperatures (as may occur in an enclosed vehicle on a hot day). Additionally, the vehicle should be well-ventilated during transportation.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Nitrogen (0.0001 - 10%), Helium (Balance)?

The signal word is warning.

What is the physical form of Nitrogen (0.0001 - 10%), Helium (Balance)?

Nitrogen (0.0001 - 10%), Helium (Balance) is a gas appearing as colorless gas with no odor. with colorless color. It has odorless odor.

What is Nitrogen (0.0001 - 10%), Helium (Balance) used for?

Calibration Gas

What are the hazard statements for Nitrogen (0.0001 - 10%), Helium (Balance)?

This substance has 2 hazard statements:

  • H280: Contains gas under pressure; may explode if heated
  • H280: May displace oxygen and cause rapid suffocation.

What is the melting point of Nitrogen (0.0001 - 10%), Helium (Balance)?

The melting point is -272 C(-457.6 F) and the boiling point is -268.94 C(-452.092 F).