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Safety Data Sheet EN

GOODBYE GRAFFITI

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
GOODBYE GRAFFITI

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Graffiti remover

Uses advised against

Uses other than those identified are not recommended

Manufacturers & Suppliers

Diversey Australia Pty. Limited logo

Diversey Australia Pty. Limited

national supplier

Unit 8, 55 Newton Road, Whetherill Park, NSW, 2164; 1-7 Bell Grove, Braeside, VIC 3195

1800 647 779

https://diversey.com.au

Emergency Contacts

Emergency Contact

1800 033 111

24hrs

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 4
Asp. Tox. Cat. 1
Skin Corr. Cat. 1B
Eye Dam. Cat. 1
Skin Sens. Cat. 1
Met. Corr. Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapour.
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P234 Keep only in original packaging.
P260 Do not breathe spray.
P264 Wash face, hands and any exposed skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves, protective clothing and eye or face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE, doctor or physician.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTRE, doctor or physician.
P321 Specific treatment (see supplemental first aid instructions on this label).
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P406 Store in corrosive-resistant container with a resistant inner liner.
P501 Dispose of unused content as chemical waste.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Non-hazardous ingredients are the remainder and add up to 100%.

Chemical Name CAS Number Concentration Hazardous
benzyl alcohol EC: 202-859-9 100-51-6 30 - 60% No
ethanol EC: 200-578-6 64-17-5 10 - 30% No
d-limonene EC: 227-813-5 5989-27-5 10 - 30% No
alkyl alcohol alkoxylate 68439-51-0 2 - 10% No
potassium hydroxide EC: 215-181-3 1310-58-3 3 - 10% No

Notes

[4] Polymer.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove person to fresh air and keep comfortable for breathing. Get medical attention or advice if you feel unwell.

Symptoms: May be fatal if swallowed and enters airways.

Skin contact

Wash skin with plenty of lukewarm, gently flowing water. Take off immediately all contaminated clothing and wash it before reuse. Immediately call a POISON CENTRE, doctor or physician. If skin irritation occurs: Get medical advice or attention.

Symptoms: skin irritation

Eye contact

Hold eyelids apart and flush eyes with plenty of lukewarm water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTRE, doctor or physician.

Symptoms: Causes severe or permanent damage.

Ingestion

Rinse mouth. Immediately drink 1 glass of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Keep at rest. Immediately call a POISON CENTRE, doctor or physician.

Symptoms: May be fatal if swallowed and enters airways. Ingestion will lead to a strong caustic effect on mouth and throat and to the danger of perforation of oesophagus and stomach.

Immediate Medical Attention

Immediately call a POISON CENTRE, doctor or physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide. Dry powder. Sand. Alcohol-resistant foam.

Unsuitable media

Do not use water.

Specific hazards

No special hazards known.

Firefighter Protection

As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Large spill

Dyke to collect large liquid spills.

Environmental

Do not allow to enter drainage system, surface or ground water.

Cleanup methods

Absorb with liquid-binding material. Collect in closed and suitable containers for disposal.

Materials: sand, diatomite, universal binders, sawdust

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Follow general hygiene considerations recognised as common good workplace practices. Keep away from food, drink and animal feeding stuffs. Keep out of reach of children. Do not mix with other products unless advised by Diversey. Wash hands thoroughly after handling. Wash face, hands and any exposed skin thoroughly after handling. Take off immediately all contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with skin and eyes. Do not breathe spray. Do not eat, drink or smoke when using this product. Use only with adequate ventilation.

Storage

Store in accordance with local and national regulations. Store in a closed container. Keep only in original packaging. Keep locked up and out of the reach of children.

Hygiene

Follow general hygiene considerations recognised as common good workplace practices. Keep away from food, drink and animal feeding stuffs. Keep out of reach of children. Do not mix with other products unless advised by Diversey. Wash hands thoroughly after handling. Wash face, hands and any exposed skin thoroughly after handling. Take off immediately all contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with skin and eyes. Do not breathe spray. Do not eat, drink or smoke when using this product.

Fire prevention

No special precautions required.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only in well ventilated areas. Where possible: use in automated/closed system and cover open containers. Transport over pipes. Filling with automatic systems. Use tools for manual handling of product.

Hands

Chemical-resistant protective gloves (AS/NZS 2161.10). Verify instructions regarding permeability and breakthrough time, as provided by the gloves supplier. Consider specific local use conditions, such as risk of splashes, cuts, contact time and temperature. Suggested gloves for prolonged contact: Material: butyl rubber Penetration time: ≥ 480 min Material thickness: ≥ 0.7 mm Suggested gloves for protection against splashes: Material: nitrile rubber Penetration time: ≥ 30 min Material thickness: ≥ 0.4 mm In consultation with the supplier of protective gloves a different type providing similar protection may be chosen.

Eyes

Safety glasses or goggles (AS/NZS 1337.1). The use of a full-face shield or other full-face protection is strongly recommended when handling open containers or if splashes may occur.

Respiratory

Apply technical measures to comply with the occupational exposure limits, if available. If exposure to liquid particles or splashes cannot be avoided use: half mask (EN 140) with particle filter P2 (EN 143) or full-face mask (EN 136) with particle filter P1 (EN 143) Consider specific local use conditions. In consultation with the supplier of respiratory protection equipment a different type providing similar protection may be chosen. Specific applications tools may be available to limit exposure. Please refer to the product information sheet for the possibilities.

Skin/Body

Wear chemical-resistant clothing and boots in case direct dermal exposure and/or splashes may occur (EN 14605).

Environmental

Should not reach sewage water or drainage ditch undiluted or unneutralised.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Clear, Light Tan
Colour Intensity
---
Form
---
Odor
Product specific
Odor Threshold
Not applicable
Ph
≈ 12.5
Melting Point
Not determined
Boiling Point
Not determined
Flash Point
≈ 26 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined
Vapor Pressure
Not determined
Vapor Density
---
Relative Density
≈ 0.96 (20 °C)
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
Not determined
Lower Explosive Limit
Not determined
Explosive Limits
---
Auto Ignition Temperature
Not determined
Decomposition Temperature
Not applicable.
Solubility
---
Partition Coefficient
No information available.
Solubility In Water
Not miscible or difficult to mix
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
Corrosive
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal storage and use conditions.

Reactivity

No reactivity hazards known under normal storage and use conditions.

Hazardous reactions

No hazardous reactions known under normal storage and use conditions.

Avoid

None known under normal storage and use conditions.

Incompatible

May be corrosive to metals. Reacts with acids.

Decomposition

None known under normal storage and use conditions.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

No data is available on the mixture. Substance data, where relevant and available, are listed below: ## Aquatic short-term toxicity Aquatic short-term toxicity - fish | Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) | | --- | --- | --- | --- | --- | --- |

No data is available on the mixture.

12.1 Toxicity

Aquatic short-term toxicity: benzyl alcohol | LC 50 | 460 | Fish | Method not given | 96

Aquatic short-term toxicity

Aquatic short-term toxicity | Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) | | ethanol | LC 50 | 8150 | Alburnus alburnus | Method not given | 96 |

Aquatic short-term toxicity

Aquatic short-term toxicity | Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) | | d-limonene | LC 50 | 0.72 | Pimephales promelas | OECD 203 (EU C.1) | 96 |

Aquatic short-term toxicity

Aquatic short-term toxicity: LC 50 = 80 mg/l, Various species, Weight of evidence, 24h

12.1 Toxicity

Aquatic short-term toxicity - crustacea | Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) | | benzyl alcohol | EC 50 | 230 | Daphnia magna Straus | Method not given | 48 |

12.1 Toxicity

Aquatic short-term toxicity - crustacea | Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) | | ethanol | EC 50 | 5012 | Daphnia magna Straus | Method not given | 48 |

12.1 Toxicity

Aquatic short-term toxicity - crustacea | Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) | | d-limonene | EC 50 | 0.36 | Daphnia magna Straus | OECD 202 (EU C.2) | 48 |

12.1 Toxicity

Aquatic short-term toxicity - crustacea | Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) | | potassium hydroxide | EC 50 | 30 - 1000 | Daphnia magna Straus | Weight of evidence | |

12.1 Toxicity

Aquatic short-term toxicity - algae | Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) | | benzyl alcohol | EC 50 | 640 | Scenedesmus quadricauda | Method not given | 96 |

12.1 Toxicity

Aquatic short-term toxicity - algae | Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) | | ethanol | EC 50 | 675 | Scenedesmus quadricauda Not specified | Method not given | 72 |

12.1 Toxicity

Aquatic short-term toxicity - algae Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (h) d-limonene | E1 C 50 | 150 | Desmodesmus subspicatus | OECD 201 (EU C.3) | 72

12.1 Toxicity

Aquatic short-term toxicity - marine species Ingredient(s) | Endpoint | Value (mg/l) | Species | Method | Exposure time (days) benzyl alcohol | No data available ethanol | No data available d-limonene | No data available alkyl alcohol alkoxylate | No data available potassium hydroxide | No data available Impact on sewage plants - toxicity to bacteria Ingredient(s) | Endpoint | Value (mg/l) | Inoculum | Method | Exposure time benzyl alcohol | No data available

12.1 Toxicity

Impact on sewage plants - toxicity to bacteria | Ingredient(s) | Endpoint | Value (mg/l) | Inoculum | Method | Exposure time | | ethanol | EC_{5} | 6500 | Pseudomonas putida | Method not given | 16 hour(s) |

12.1 Toxicity

Impact on sewage plants - toxicity to bacteria | Ingredient(s) | Endpoint | Value (mg/l) | Inoculum | Method | Exposure time | | potassium hydroxide | EC_{50} | 22 | Photobacterium phosphoreum | Method not given | 15 minute(s) |

Persistence and degradability

Biodegradation | Ingredient(s) | Inoculum | Analytical method | DT 50 | Method | Evaluation | | benzyl alcohol | | Method not given | 95 - 97% % in 21 day(s) | Method not given | Readily biodegradable |

Persistence and degradability

Biodegradation Ingredient(s) | Inoculum | Analytical method | DT 50 | Method | Evaluation ethanol | Activated sludge, aerobe | Oxygen depletion | > 60% in 10 day(s) | OECD 301B | Readily biodegradable

Biodegradation

| Ingredient(s) | Inoculum | Analytical method | DT 50 | Method | Evaluation | | d-limonene | | | 80 % in 28 day(s) | OECD 301D | Readily biodegradable |

12.3 Bioaccumulative potential

| Ingredient(s) | Value | Method | Evaluation | Remark | | benzyl alcohol | 1.05 | Method not given | Low potential for bioaccumulation | |

12.3 Bioaccumulative potential

| Ingredient(s) | Value | Method | Evaluation | Remark | | ethanol | -0.31 | Weight of evidence | No bioaccumulation expected | |

12.3 Bioaccumulative potential

| Ingredient(s) | Value | Method | Evaluation | Remark | | d-limonene | No data available | | High potential for bioaccumulation | |

12.3 Bioaccumulative potential

| Ingredient(s) | Value | Method | Evaluation | Remark | | potassium hydroxide | No data available | | Not relevant, does not bioaccumulate | |

12.3 Bioaccumulative potential

Bioconcentration factor (BCF) | Ingredient(s) | Value | Species | Method | Evaluation | Remark | | benzyl alcohol | No data available | | | Low potential for bioaccumulation | |

12.3 Bioaccumulative potential

Bioconcentration factor (BCF) | Ingredient(s) | Value | Species | Method | Evaluation | Remark | | ethanol | 0.5 | | Weight of evidence | No bioaccumulation expected | |

12.3 Bioaccumulative potential

Bioconcentration factor (BCF) | Ingredient(s) | Value | Species | Method | Evaluation | Remark | | d-limonene | 683.1 | | Method not given | High potential for bioaccumulation | |

12.4 Mobility in soil

Adsorption/Desorption to soil or sediment | Ingredient(s) | Adsorption coefficient Log Koc | Desorption coefficient Log Koc(des) | Method | Soil/sediment type | Evaluation | | --- | --- | --- | --- | --- | --- | | benzyl alcohol | No data available | | | | Potential for mobility in soil, soluble in water | | ethanol | No data available | | | | | | d-limonene | No data available | | | | High potential for mobility in soil | | alkyl alcohol alkoxylate | No data available | | | | | | potassium hydroxide | No data available | | | | Low potential for adsorption to soil |

12.5 Other adverse effects

No other adverse effects known.

No other adverse effects known.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The concentrated contents or contaminated packaging should be disposed of by a certified handler or according to the site permit.

Disposal

The concentrated contents or contaminated packaging should be disposed of by a certified handler or according to the site permit.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2924
Shipping Name
Flammable liquid, corrosive, n.o.s. ( d-limonene , ethanol )
Transport Class
3(8)
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for GOODBYE GRAFFITI?

The signal word is danger.

What is the physical form of GOODBYE GRAFFITI?

GOODBYE GRAFFITI is a liquid with clear, light tan color. It has product specific odor.

What is GOODBYE GRAFFITI used for?

Graffiti remover

What are the hazard statements for GOODBYE GRAFFITI?

This substance has 6 hazard statements:

  • H226: Flammable liquid and vapour.
  • H290: May be corrosive to metals.
  • H302: Harmful if swallowed.
  • H304: May be fatal if swallowed and enters airways.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.

What is the melting point of GOODBYE GRAFFITI?

The melting point is Not determined and the boiling point is Not determined.