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Safety Data Sheet EN

Methanol TECHNICAL

CAS 67-56-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methanol TECHNICAL
Product Code
20903
Chemical Name
Methanol
Synonyms
Carbinol, Hydroxy methane, Methyl alcohol, Wood alcohol

Regulatory Identifiers

CAS Number
67-56-1 Check regulations →
REACH No.
01-2119433307-44-XXXX

Identified Uses

General chemical reagent

Manufacturers & Suppliers

V

VWR International Ltd.

national supplier

Hunter Boulevard, Magna Park, Lutterworth, LE17 4XN

0800 22 33 44

Emergency Contacts

CareChem24

+44 (0) 1270 502894

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
STOT SE Cat. 1 H370
Acute Tox. Cat. 3 H301 + H311 + H331

GHS Pictograms

GHS02 - Flammable

GHS02

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H370 Causes damage to organs.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P243 Take precautionary measures against static discharge.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water/...
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF exposed or concerned: Immediately call a POISON CENTER/doctor.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Methanol EC: 200-659-6 67-56-1 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Immediately call a POISON CENTRE/doctor. Remove casualty to fresh air and keep warm and at rest. If breathing is irregular or stopped, administer artificial respiration.

Symptoms: Headache. Dizziness. Nausea. Respiratory disorders.

Skin contact

After contact with skin, wash immediately with plenty of water and soap. Remove contaminated, saturated clothing immediately. In case of skin reactions, consult a physician.

Eye contact

In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye. Remove contact lenses, if present and easy to do. Continue rinsing.

Symptoms: Risk of blindness.

Ingestion

Immediately call a POISON CENTRE/doctor. Do NOT induce vomiting. Rinse mouth thoroughly with water. Give nothing to eat or drink.

Symptoms: Nausea. Acidosis.

Immediate Medical Attention

Immediately call a POISON CENTRE/doctor.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, ABC-powder, Carbon dioxide (CO2), Nitrogen

Unsuitable media

Full water jet

Specific hazards

In case of fire may be liberated: Carbon monoxide, Carbon dioxide (CO2)

Instructions

DO NOT fight fire when fire reaches explosives. Use water spray jet to protect personnel and to cool endangered containers.

Firefighter Protection

Wear a self-contained breathing apparatus and chemical protective clothing. In case of fire and/or explosion do not breathe fumes. Do not inhale explosion and combustion gases.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid contact with skin, eyes and clothes. Avoid inhalation of the product. Take off immediately all contaminated clothing.

Environmental

Discharge into the environment must be avoided.

Cleanup methods

Collect in closed and suitable containers for disposal.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid inhalation of the product. Avoid contact with eyes and skin. Wear protective gloves/protective clothing and eye/face protection.

Storage

Keep container tightly closed and in a well-ventilated place. Keep cool. Protect from sunlight. Store in a place accessible by authorized persons only.

Hygiene

Wash hands before breaks and after work. Avoid contact with eyes and skin. When using do not eat, drink or smoke.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Usual measures for fire prevention.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and the application of suitable work processes have priority over personal protection equipment. If handled uncovered, arrangements with local exhaust ventilation have to be used.

Hands

When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. Recommended glove articles DIN-/EN-Norms EN ISO 374 in the case of wanting to use the gloves again, clean them before taking off and air them well. By short-term hand contact: Suitable material: NBR (Nitrile rubber), Thickness of the glove material: 0,38 mm, Recommended glove articles: VWR 112-1381. By long-term hand contact: Suitable material: Butyl caoutchouc (butyl rubber), Thickness of the glove material: 0,30 mm, Breakthrough time: > 480 min, Recommended glove articles: VWR 112-3779.

Eyes

Eye glasses with side protection DIN-/EN-Norms DIN EN 166. Recommendation: VWR 111-0432

Respiratory

Respiratory protection necessary at: aerosol or mist formation. Suitable respiratory protection apparatus: Full-/half-/quarter-face masks (DIN EN 136/140). Recommendation: VWR 111-0206. Suitable material: AXP3. Recommendation: VWR 111-8932.

Skin/Body

Wear suitable protective clothing. When handling with chemical substances, protective clothing with CE-labels including the four control digits must be worn.

Environmental

no data available

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid, colourless
Colour
colourless
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
no data available
Ph
7 (20 °C)
Melting Point
-98 °C
Boiling Point
64.6 °C (1013 hPa)
Flash Point
11 °C (closed cup)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
no data available
Vapor Pressure
128 hPa (20 °C)
Vapor Density
1.11 (20 °C)
Relative Density
---
Bulk Density
no data available
Density
0.7918 g/cm³ (20 °C)
Flammability
Highly flammable liquid and vapour.
Upper Explosive Limit
36.5 % (v/v)
Lower Explosive Limit
5.5 % (v/v)
Explosive Limits
---
Auto Ignition Temperature
455 °C (DIN 51794)
Decomposition Temperature
not applicable
Solubility
---
Partition Coefficient
-0.77 (20 °C)
Solubility In Water
soluble (20 °C)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.614 mPa*s (20 °C)
Kinematic Viscosity
no data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Vapour can form explosive mixtures with air.

Reactivity

This material is non-reactive under normal conditions.

Hazardous reactions

Formation of explosive mixtures with: Oxidising agent, Nitrogen oxides (NOx), Chlorates, Nitric acid, Sulphuric acid. Exothermic reaction with: Reducing agent, Acid, Acid halides, Alkali (lye), concentrated. Violent reaction with: Alkali metals, Alkaline earth metal. Formation of: Hydrogen.

Avoid

UV-radiation/sunlight, Heat, Sparks, Flame

Incompatible

Acids, Alkali metals, Oxidising agent

Decomposition

Formaldehyde

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Fish toxicity: LC50: 24000 mg/l (96 h) - Poirier, S.H., M.L. Knuth, C.D. Anderson-Buchou, L.T. Brooke, A.R. Lima, and P.J. Shubat 1986. Comparative Toxicity of Methanol and N,N-Dimethylformamide to Freshwater Fish and Invertebrates. Bull.Environ.Contam.Toxicol. 37(4):615-621 Daphnia toxicity: LC50: 3290 mg/l (48 h) - Guilhermino, L., T. Diamantino, M.C. Silva, and A.M.V.M. Soares 2000. Acute Toxicity Test with Daphnia magna: An Alternative to Mammals in the Prescreening of Chemical Toxicity?. Ecotoxicol.Environ.Saf. 46(3):357-362 EC50: 24500 mg/l (48 h) - Randall, T.L., and P.V. Knopp 1980. Detoxification of Specific Organic Substances by Wet Oxidation. J.Water Pollut.Control Fed. 52(8):2117-2130 Algae toxicity: EC50: 22 000 mg/l (96 h) Pseudokirchneriella subcapitata - IUCLID

12.2 Persistence and degradability

Biodegradable.

12.3 Bioaccumulative potential

12.3 Bioaccumulative potential

Partition coefficient: n-octanol/water: -0.77 (20 °C)

12.4 Mobility in soil

no data available

no data available

12.5 Results of PBT/vPvB assessment

This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

The substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

12.6 Other adverse effects

no data available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose according to local legislation. Consult the appropriate local waste disposal expert about waste disposal.

Disposal

Dispose according to local legislation.

Waste Codes

070104 EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1230
Shipping Name
METHANOL
Transport Class
3 (6.1)
Packing Group
II
ADR

Passage forbidden through tunnels of category D when carried in bulk or in tanks. Passage forbidden through tunnels of category E.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The product is subject to EU regulations including REACH (Regulation (EC) No 1907/2006) and CLP (Regulation (EC) No 1272/2008), along with their respective amendments.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Methanol TECHNICAL known by?

Methanol TECHNICAL is also known as: Carbinol, Hydroxy methane, Methyl alcohol, Wood alcohol

What is the hazard signal word for Methanol TECHNICAL?

The signal word is danger.

What is the physical form of Methanol TECHNICAL?

Methanol TECHNICAL is a liquid appearing as liquid, colourless with colourless color. It has characteristic odor.

What is Methanol TECHNICAL used for?

General chemical reagent

What are the hazard statements for Methanol TECHNICAL?

This substance has 3 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
  • H370: Causes damage to organs.

What is the melting point of Methanol TECHNICAL?

The melting point is -98 °C and the boiling point is 64.6 °C (1013 hPa).