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Safety Data Sheet EN

Methanol

CAS 67-56-1
EC 200-659-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methanol
Product Code
A412-1; A412-4; A412-4LC; A412-20; A412-200; A412200-001; A412-200LC; A412-500; A412CU-1300; A412P-4; A412SK-4; A412FB-19; A412FB-50; A412FB-115; A412FB-200; A412POP-19; A412POPB-200; A412RB50; A412RB-115; A412RB-200; A412RS-19; A412RS-28; A412RS-50; A412RS-115; A412RS-200; A412SS-115; XXA412ETU200LI; NC1282211; XXA412ETWD200LI; NC1380933; A412RS-1350ASME; NC1561769; A412RS200ASME; NC1568698; NC1822351; XXA412ETU20LI
Chemical Name
Methanol, anhydrous
Synonyms
carbinol, MEOH, methyl hydroxide, monohydroxy methane

Regulatory Identifiers

CAS Number
67-56-1 Check regulations →
EC Number
200-659-6 Check regulations →
REACH No.
01-2119433307-44-0135

Identified Uses

Laboratory chemicals.

Manufacturers & Suppliers

F

Fisher Scientific Company

national supplier

One Reagent Lane Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC

800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
Acute Tox. Cat. 3
Acute Tox. Cat. 3
Acute Tox. Cat. 3
STOT SE Cat. 1
STOT RE Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
Causes damage to organs
Causes damage to organs through prolonged or repeated exposure

Precautionary Statements

Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool
IF exposed: Call a POISON CENTER or doctor/physician
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician
Call a POISON CENTER or doctor/physician if you feel unwell Wash contaminated clothing before reuse IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth
In case of fire: Use CO2, dry chemical, or foam for extinction
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Methylalcohol 67-56-1 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required.

Symptoms: Difficulty in breathing. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required.

Symptoms: May cause blindness

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

Water may be ineffective

Specific hazards

Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Vapors may form explosive mixtures with air.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Use personal protective equipment as required. Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges.

Environmental

Should not be released into the environment. See Section 12 for additional Ecological Information.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not breathe mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not ingest. If swallowed then seek immediate medical assistance.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Flammables area.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Evaporation Rate
5.2 (ether = 1)
Solubility
Miscible with water
Dynamic Viscosity
0.55 cP at 20 °C
Odor Threshold
No information available
Relative Evaporation Rate
---
Kinematic Viscosity
---
Flash Point
9.7 °C / 49.5 °F
Solidification Point
---
Physical State
Liquid
Odor
Alcohol-like
Flammability
Not applicable
Bulk Density
---
Lower Explosive Limit
6.0 vol %
Relative Density
0.791
Crystallisation Point
---
Cloud Point
---
Colour
Colorless
Solubility In Water
Miscible with water
Appearance
Colorless
Vapor Pressure
128 hPa @ 20 °C
Explosive Limits
---
Form
---
Melting Point
-98 °C / -144.4 °F
Boiling Point
64.7 °C / 148.5 °F
Physical State Data
liquid
Partition Coefficient
No data available
Upper Explosive Limit
31.00 vol %
Softening Point
---
Freezing Point
---
Colour Intensity
---
Properties Status
---
Vapor Density
2.5
Auto Ignition Temperature
455 °C / 851 °F
Density
---
Solubility In Fat
---
Ph
Not applicable
Decomposition Temperature
No information available
Metal Corrosion
---
Molecular Weight
32.04
Voc Content
100
State Under Standard Conditions
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Heat, flames and sparks. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents, Strong acids, Acid anhydrides, Acid chlorides, Strong bases, Metals, Peroxides

Decomposition

Carbon monoxide (CO), Formaldehyde

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Other adverse effects

No information available.

No information available.

Ecotoxicity

Ecotoxicity | Component | Freshwater Algae | Freshwater Fish | Microtox | Water Flea | | --- | --- | --- | --- | --- | | Methyl alcohol | Not listed | Pimephales promelas: LC50 > 10000 mg/L 96h | EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min | EC50 > 10000 mg/L 24h |

Methyl alcohol shows low acute toxicity to freshwater fish (LC50 > 10000 mg/L for Pimephales promelas) and water fleas (EC50 > 10000 mg/L). It also exhibits moderate toxicity to microorganisms in Microtox tests with EC50 values ranging from 39000 to 43000 mg/L over different durations. No specific data is listed for freshwater algae.

Persistence and Degradability

Persistence and Degradability Persistence is unlikely based on information available.

Persistence of the substance is unlikely based on available information.

Bioaccumulation/ Accumulation

Bioaccumulation/ Accumulation No information available.

No information regarding bioaccumulation or accumulation is available.

Mobility

Mobility Will likely be mobile in the environment due to its volatility. | Component | log Pow | | --- | --- | | Methyl alcohol | -0.74 |

The substance is likely to be mobile in the environment due to its volatility. Methyl alcohol has a log Pow of -0.74.

Results of PBT and vPvB assessment

No information available.

No information available.

Endocrine disrupting properties

No information available.

No information available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Should not be released into the environment.

Waste Codes

U154 Methyl alcohol RCRA
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1230
Shipping Name
METHANOL
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Mexico - Grade Serious risk, Grade 3

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Methanol known by?

Methanol is also known as: carbinol, MEOH, methyl hydroxide, monohydroxy methane

What is the hazard signal word for Methanol?

The signal word is danger.

What is the physical form of Methanol?

Methanol is a liquid appearing as colorless with colorless color. It has alcohol-like odor.

What is the solubility of Methanol?

Miscible with water

What is Methanol used for?

Laboratory chemicals.

What are the hazard statements for Methanol?

This substance has 4 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
  • Causes damage to organs
  • Causes damage to organs through prolonged or repeated exposure

What is the melting point of Methanol?

The melting point is -98 °C / -144.4 °F and the boiling point is 64.7 °C / 148.5 °F.

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