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Safety Data Sheet EN

dialox™

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
dialox™

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Disinfectant for medical device

Uses advised against

Reserved for industrial and professional use.

Manufacturers & Suppliers

B

BIOXAL SA - AIR LIQUIDE Group

manufacturer

Route des Varennes - BP 72, 71103 Chalon-sur-Saône Cedex, France

+33 (0) 3 85 92 30 00

S

Schülke France SARL

distributor

22, Terrasse Bellini, 92800 Puteaux, France

+33 (0) 1 42 91 42 42

Emergency Contacts

UK Poisons Emergency number

0870 600 6266

Schülke & Mayr UK Ltd.

+44-1142543500

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Corr. Cat. 1C H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H314 Causes severe skin burns and eye damage.

Precautionary Statements

P260 Do not breathe vapours, aerosols.
P280 Wear protective gloves/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Solution of the following substances with harmless additives.

Chemical Name CAS Number Concentration Hazardous
Peracetic acid EC: 201-186-8 79-21-0 0.5% Yes
Acetic acid EC: 200-580-7 64-19-7 1 - 5% Yes
Hydrogen peroxide EC: 231-765-0 7722-84-1 5 - 8% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move the victim to fresh air and keep him calm. If symptoms persist, call a physician.

Skin contact

Wash off immediately with plenty of water. If symptoms persist, call a physician.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist.

Ingestion

Do NOT induce vomiting. Call a physician immediately. Rinse mouth with water. Give small amounts of water to drink.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Dry powder, Foam, Water spray jet

Unsuitable media

Carbon dioxide (CO2), High volume water jet

Specific hazards

Specific hazards during firefighting: No information available. Specific risk from the substance or the product itself, its combustion products or evolved gases: Oxygen

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Handle in accordance with good industrial hygiene and safety practice.

Environmental

Avoid subsoil penetration. Do not flush into surface water or sanitary sewer system.

Cleanup methods

Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly. Flush with water.

Materials: Kieselguhr, Universal binder

—

Related Products

Similar products with comparable safety profiles

A

ALOX® 2296

---

B

Barlox™ 12

---

O

OXY-TITE®

---

B

Boreox

CAS: 9004-34-6

A

ALOX® MT1000

---

T

TIOXIDE® TR88

---

C

CELLEOX, BOREOX

CAS: 9004-34-6

S

Shell DONAX TM

---

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Provide sufficient air exchange and/or exhaust in work rooms. Handle and open container with care. Never return unused material to storage receptacle.

Storage

Keep away from heat. Keep away from direct sunlight. Store in cool place. Do not keep the container sealed. Keep in a dry place.

Hygiene

When using do not eat or drink.

Fire prevention

Normal measures for preventive fire protection.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Remarks: Prolonged contact: Nitrile rubber gloves e.g. Camatril (>120 Min., layer thickness: 0.40 mm) or butyl rubber gloves e.g. Butoject (>480 Min., layer thickness: 0.70 mm) made by KCL or gloves from other manufacturers offering the same protection. Splash protection: disposable nitrile rubber gloves e.g. Dermatril (layer thickness: 0.11 mm) made by KCL or gloves from other manufacturers offering the same protection.

Eyes

Safety glasses with side-shields conforming to EN166

Respiratory

If the occupational exposure limits cannot be met, in exceptional cases suitable respiratory equipment should be worn only for a short period of time. Combination filter: A2B2E2K2 Hg NO P3 P D/ CO 20 P3 R D

Skin/Body

Choose body protection according to the amount and concentration of the dangerous substance at the work place. Wear as appropriate: Chemical resistant apron Boots Neoprene

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid
Colour
colourless
Colour Intensity
---
Form
---
Odor
pungent
Odor Threshold
not determined
Ph
ca. 1,1, 20 °C, concentrate
Melting Point
ca. -15 °C
Boiling Point
ca. 98 °C
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
32 hPa, ca. 20 °C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,03 g/cm3, 20 °C
Flammability
Not applicable
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
not determined
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
Not applicable
Solubility In Water
completely soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
not determined
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable.

Reactivity

No dangerous reaction known under conditions of normal use.

Hazardous reactions

Thermal decomposition

Avoid

Do not overheat

Incompatible

Reducing agents, Acid chlorides, Strong bases, Aldehydes, Metals

Decomposition

Oxygen

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product: Toxicity to fish: LC50 (Brachidanio rerio): 10 - 100 mg/l, 96 h, OECD Test Guideline 203, GLP: yes Toxicity to daphnia and other aquatic invertebrates EC50 (Daphnia magna): 10 - 100 mg/l, 48 h, OECD Test Guideline 202, GLP: yes Toxicity to algae EC50 (Desmodesmus subspicatus (green algae)): 10 - 100 mg/l, 72 h, OECD Test Guideline 201, GLP: yes

12.1 Toxicity

Peracetic acid: Toxicity to fish : LC50 : 13 mg/l, 96 h, semi-static test, OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna): 3,3 mg/l, 48 h, OECD Test Guideline 202 Toxicity to algae : No data available

12.1 Toxicity

Toxicity to fish : LC50 (Gambusia affinis (Mosquito fish)): 251 mg/l, 96 h, static test Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna): 95 mg/l, 24 h Toxicity to algae : EC100 (Euglena gracilis): 720 mg/l, 0,25 h

12.1 Toxicity

Hydrogen peroxide: Toxicity to fish : LC50 (Fish): 16,4 - 37,4 mg/l, 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna): 2,4 mg/l, 48 h Toxicity to algae : ErC50 (Skeletonema costatum (marine diatom)): 1,38 mg/l, 72 h : NOEC (Skeletonema costatum (marine diatom)): 0,63 mg/l, 72 h

12.2 Persistence and degradability

12.2 Persistence and degradability

Peracetic acid: Biodegradability : Totally biodegradable, OECD Test Guideline 301

12.2 Persistence and degradability

Biodegradability : Totally biodegradable, OECD 301D / EEC 84/449 C6

12.2 Persistence and degradability

Hydrogen peroxide: Biodegradability : Totally biodegradable, OECD Test Guideline 301

12.3 Bioaccumulative potential

12.3 Bioaccumulative potential

Peracetic acid: Bioaccumulation : Does not bioaccumulate.

12.3 Bioaccumulative potential

Acetic acid: Bioaccumulation : Bioaccumulation is unlikely.

Bioaccumulation is unlikely.

12.3 Bioaccumulative potential

Hydrogen peroxide: Bioaccumulation : Does not bioaccumulate.

12.4 Mobility in soil

Components: Peracetic acid: Mobility : Water Hydrolyses readily. Acetic acid: Mobility : No data available Hydrogen peroxide: Mobility : Water Hydrolyses readily.

12.5 Results of PBT and vPvB assessment

Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Dispose of the product according to the defined EWC (European Waste Code) No. Dispose of as hazardous waste in compliance with local and national regulations.

Waste Codes

160903 peroxides, e.g. hydrogen peroxide EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3265
Shipping Name
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Acetic acid, Peracetic acid)
Transport Class
8
Packing Group
III
ADR

Not classified as supporting combustion according to the transport regulations.

IMDG

Not classified as supporting combustion according to the transport regulations.

IATA

Not classified as supporting combustion according to the transport regulations.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Take note of Directive 2000/39/EC establishing a first list of indicative occupational exposure limit values.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for dialox™?

The signal word is danger.

What is the physical form of dialox™?

dialox™ is a liquid appearing as liquid with colourless color. It has pungent odor.

What is dialox™ used for?

Disinfectant for medical device

What are the hazard statements for dialox™?

This substance has 1 hazard statement:

  • H314: Causes severe skin burns and eye damage.

What is the melting point of dialox™?

The melting point is ca. -15 °C and the boiling point is ca. 98 °C.