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Safety Data Sheet EN

Hardtop AX Comp A

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hardtop AX Comp A
Product Form
Liquid
Product Code
16480

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Use in coatings - Industrial use Use in coatings - Professional use

Manufacturers & Suppliers

J

Jotun A/S

manufacturer

P.O. Box 2021, 3202 Sandefjord Norway

+47 33 45 70 00

J

Jotun Paints (Europe) Ltd.

distributor

Stather Road Flixborough, Scunthorpe North, Lincolnshire DN15 8RR England

+44 1724 400 000

Emergency Contacts

NHS Direct

111

24/7

Jotun Norway (head office)

+47 33 45 70 00

NHS Direct

0845 4647

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H317 May cause an allergic skin reaction.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing vapour.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P312 IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice or attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Keep cool.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
barium sulfate EC: 231-784-4 7727-43-7 25% No
n-butyl acetate EC: 204-658-1 123-86-4 25% Yes
talc (non-asbestos form) EC: 238-877-9 14807-96-6 5% No
hydrocarbons, C9, aromatics EC: 918-668-5 128601-23-0 3% Yes
2-methoxy-1-methylethyl acetate EC: 203-603-9 108-65-6 3% Yes
pentane-2,4-dione EC: 204-634-0 123-54-6 3% Yes
reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate and methyl1,2,2,6,6-pentamethyl-4-piperidylsebacate 1065336-91-5 2.1% Yes
Neodecanoic acid, zinc salt, basic EC: 282-780-4 84418-68-8 0.3% Yes
2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester, polymer with butyl 2-propenoate, compd. with polyethylene glycol hydrogen maleate C9-11-alkyl ethers 1259547-09-5 0.3% Yes
2-Hydroxyethyl methacrylate EC: 212-782-2 868-77-9 0.3% Yes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness

Skin contact

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: irritation, redness

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

Symptoms: No specific data.

Ingestion

Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No specific data.

Immediate Medical Attention

Get medical attention. If necessary, call a poison center or physician. If unconscious, get medical attention immediately.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Recommended: alcohol-resistant foam, CO₂, powders, water spray.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is harmful to aquatic life with long lasting effects.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to British standard BS EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.

Cleanup methods

Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Materials: inert material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent the creation of flammable or explosive concentrations of vapours in air. Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist. Wear appropriate personal protective equipment. Never use pressure to empty. Keep in original container.

Storage

Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Keep away from heat, sparks and flame. No sparking tools should be used. Use earthing leads when transferring. Operators should wear antistatic footwear and clothing.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. The breakthrough time must be greater than the end use time of the product. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical/chemical damage and poor maintenance. Barrier creams may help to protect the exposed areas of the skin but should not be applied once exposure has occurred. Wear suitable gloves tested to EN 374. Recommended, gloves(breakthrough time) > 8 hours: Teflon (> 0.35 mm), polyvinyl alcohol (PVA) (> 0.3 mm), butyl rubber (> 0.4 mm) May be used, gloves(breakthrough time) 4 - 8 hours: 4H/Silver Shield® (> 0.07 mm), neoprene (> 0.35 mm), nitrile rubber (> 0.75 mm), PVC (> 0.5 mm), Viton® (> 0.7 mm) For right choice of glove materials, with focus on chemical resistance and time of penetration, seek advice by the supplier of chemical resistant gloves. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use, as included in the user's risk assessment.

Eyes

Safety eyewear complying to EN 166 should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory

If workers are exposed to concentrations above the exposure limit, they must use a respirator according to EN 140. Use respiratory mask with charcoal and dust filter when spraying this product, according to EN 14387 (as filter combination A2-P2). In confined spaces, use compressed-air or fresh-air respiratory equipment. When use of roller or brush, consider use of charcoal filter.

Skin/Body

Use chemical-resistant protective suit / disposable overall. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to British Standard BS EN 1149 for further information on material and design requirements and test methods. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Do not allow to enter drains or watercourses.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Brown., Black, Blue., Brown., Clear., Green., Grey, MCI Base 1, MCI Base 2, MCI Base 3, MCI Base 5, MCI Base 6, Off-white., Orange, Orange, Red, Violet., White., Yellow., Yellow-base
Colour Intensity
---
Form
---
Odor
Characteristic.
Odor Threshold
Not applicable.
Ph
Not applicable.
Melting Point
Not applicable.
Boiling Point
Not available.
Flash Point
Closed cup: 28°C (82.4°F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Not available.
Vapor Density
Not available.
Relative Density
---
Bulk Density
---
Density
1.323 to 1.509 g/cm³
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
cold water: Not soluble, hot water: Not soluble
Partition Coefficient
Not applicable.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Dynamic (room temperature): Not available.
Kinematic Viscosity
Kinematic (40°C): >20.5 mm²/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage and handling conditions (see Section 7).

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

When exposed to high temperatures may produce hazardous decomposition products.

Incompatible

Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strong acids.

Decomposition

Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product/ingredient name hydrocarbons, C9, aromatics Result Acute - LC50 Fish <10 mg/l [96 hours] Acute - EC50 Daphnia <10 mg/l [48 hours] Acute - IC50 Algae <10 mg/l [72 hours]

12.1 Toxicity

Pentane-2,4-dione Acute - LC50 - Fresh water Daphnia - Water flea - Daphnia magna - Neonate Age: 0 to 24 hours 47600 μg/l [48 hours] Effect: Mortality Acute - LC50 - Fresh water Fish - Bluegill - Lepomis macrochirus Weight: 0.47 g 60100 μg/l [96 hours] Effect: Mortality

12.1 Toxicity

Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate Acute - LC50 Fish 0.9 mg/l [96 hours] Acute - EC50 Algae 1.68 mg/l [96 hours] Chronic - NOEC Daphnia 1 mg/l [21 days]

12.2 Persistence and degradability

Not available.

Not available.

12.2 Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | hydrocarbons, C9, aromatics | - | - | Not readily |

12.3 Bioaccumulative potential

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | n-butyl acetate | 2.3 | - | Low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | n-butyl acetate | 2.3 | - | Low | | hydrocarbons, C9, aromatics | - | 10 to 2500 | High |

12.3 Bioaccumulative potential

Product/ingredient name | LogP_{ow} | BCF | Potential | --- | --- | --- | --- | n-butyl acetate | 2.3 | - | Low | | hydrocarbons, C9, aromatics | - | 10 to 2500 | High | | 2-methoxy-1-methylethyl acetate | 1.2 | - | Low |

12.3 Bioaccumulative potential

Product/ingredient name | LogP_{ow} | BCF | Potential --- | --- | --- | --- n-butyl acetate | 2.3 | - | Low hydrocarbons, C9, aromatics | - | 10 to 2500 | High 2-methoxy-1-methylethyl acetate | 1.2 | - | Low pentane-2,4-dione | 0.68 | - | Low

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | 2-Hydroxyethyl methacrylate | 0.42 | - | Low |

12.4 Mobility in soil

Soil/water partition coefficient : Not available. Mobility : Not available.

Data not available.

12.5 Results of PBT and vPvB assessment

| Product/ingredient name | PBT | P | B | T | vPvB | vP | vB | | --- | --- | --- | --- | --- | --- | --- | --- | | barium sulfate | No | No | No | No | No | No | No | | n-butyl acetate | No | N/A | N/A | No | N/A | N/A | N/A | | talc (non-asbestos form) | No | No | No | No | No | No | No | | hydrocarbons, C9, aromatics | No | N/A | No | No | No | N/A | No | | 2-methoxy-1-methylethyl acetate | No | N/A | N/A | No | N/A | N/A | N/A | | pentane-2,4-dione | No | N/A | N/A | No | N/A | N/A | N/A | | reaction mass of bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl | N/A | N/A | N/A | Yes | N/A | N/A | N/A | | 1,2,2,6,6-pentamethyl-4-piperidyl sebacate | | | | | | | | | Neodecanoic acid, zinc salt, basic | No | N/A | N/A | No | N/A | N/A | N/A | | 2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester, polymer with butyl 2-propenoate, compd. with polyethylene glycol hydrogen maleate | No | N/A | N/A | No | N/A | N/A | N/A | | C9-11-alkyl ethers | | | | | | | | | 2-Hydroxyethyl methacrylate | No | N/A | N/A | No | N/A | N/A | N/A |

12.6 Other adverse effects

No known significant effects or critical hazards.

No known significant effects or critical hazards.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Waste Codes

08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances EWC
15 01 10* packaging containing residues of or contaminated by hazardous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
Paint
Transport Class
3
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

UK (GB)/REACH: None of the components are listed in Annex XIV or as SVHC. Ozone depleting substances, PIC, and POPs are not listed. Seveso Directive applies.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hardtop AX Comp A?

The signal word is warning.

What is the physical form of Hardtop AX Comp A?

Hardtop AX Comp A is a liquid. with brown., black, blue., brown., clear., green., grey, mci base 1, mci base 2, mci base 3, mci base 5, mci base 6, off-white., orange, orange, red, violet., white., yellow., yellow-base color. It has characteristic. odor.

What is the solubility of Hardtop AX Comp A?

cold water: Not soluble, hot water: Not soluble

What is Hardtop AX Comp A used for?

Use in coatings - Industrial use Use in coatings - Professional use

What are the hazard statements for Hardtop AX Comp A?

This substance has 4 hazard statements:

  • H226: Flammable liquid and vapour.
  • H317: May cause an allergic skin reaction.
  • H336: May cause drowsiness or dizziness.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of Hardtop AX Comp A?

The melting point is Not applicable. and the boiling point is Not available..