NextSDS Logo
Safety Data Sheet EN

Phenol

CAS 108-95-2
EC 203-632-7

Keep this SDS organized and up to date

Add this SDS to your NextSDS library and keep all its safety information in one place.

Add to my SDS library for free
01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Phenol
Product Code
149340000, 149340010, 149340050, 149340500, 149340051, 149340025
Chemical Name
Phenol
Synonyms
Carbolic acid; Hydroxybenzene

Regulatory Identifiers

CAS Number
108-95-2 Check regulations →
EC Number
203-632-7 Check regulations →
REACH No.
01-2119471329-32

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher Scientific

manufacturer

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

F

Fisher Scientific UK

distributor

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

F

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1B H314
Muta. Cat. 2 H341
STOT RE Cat. 2 H373
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage
H341 Suspected of causing genetic defects
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician

Still copying SDS data manually?Free

You don't have to. NextSDS reads this SDS and adds the information to your library automatically.

Let NextSDS do it for me
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Phenol EC: 203-632-7 108-95-2 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Possible perforation of stomach or esophagus should be investigated.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water mist may be used to cool closed containers. CO₂, dry chemical, dry sand, alcohol-resistant foam.

Unsuitable media

No information available.

Specific hazards

The product causes burns of eyes, skin and mucous membranes.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Environmental

Should not be released into the environment.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not ingest. If swallowed then seek immediate medical assistance. Do not breathe (dust, vapor, mist, gas). Avoid dust formation.

Storage

Store under an inert atmosphere. Protect from moisture. Protect from light. Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Fire prevention

Keep away from heat, sparks and flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves Butyl rubber Neoprene. Glove material: Natural rubber, Butyl rubber, Nitrile rubber, Neoprene, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement)

Eyes

Goggles (European standard - EN 166)

Respiratory

Effective dust mask Filter type A. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Particulates filter conforming to EN 143. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask> Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141; Particle filtering: EN149:2001. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Crystalline Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Colorless - Translucent White
Colour
---
Colour Intensity
---
Form
---
Odor
pungent
Odor Threshold
No data available
Ph
6 @ 20°C 10 g/L aq.sol
Melting Point
39 - 42 °C / 102.2 - 107.6 °F
Boiling Point
182 °C / 359.6 °F @ 760 mmHg
Flash Point
79 °C / 174.2 °F Method - No information available
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable - Solid
Vapor Pressure
0.4 mbar @ 20 °C
Vapor Density
Not applicable
Relative Density
---
Bulk Density
---
Density
1.070
Flammability
---
Upper Explosive Limit
9.5 Vol%
Lower Explosive Limit
1.3 Vol%
Explosive Limits
---
Auto Ignition Temperature
605 °C / 1121 °F
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
1.47 (Phenol)
Solubility In Water
Soluble
Solubility In Fat
---
Molecular Weight
94.11
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
3.437 mPa.s (50°C)
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hygroscopic, Light sensitive.

Reactivity

Yes

Hazardous reactions

None under normal processing. Hazardous Polymerization: No information available.

Avoid

Avoid dust formation. Incompatible products. Exposure to moisture. Exposure to light. Keep away from open flames, hot surfaces and sources of ignition. Exposure to moist air or water.

Incompatible

Acids. Bases. Strong oxidizing agents. Halogens. Lead. Metals.

Decomposition

Carbon monoxide (CO). Carbon dioxide $(\mathrm{CO}_{2})$

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecotoxicity effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. | Component | Freshwater Fish | Water Flea | Freshwater Algae | | --- | --- | --- | --- |

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

12.1 Toxicity

Freshwater Fish: 4-7 mg/L LC50 96 h; 32 mg/L LC50 96 h. Water Flea: EC50: 10.2 - 15.5 mg/L, 48h (Daphnia magna); EC50: 4.24 - 10.7 mg/L, 48h Static (Daphnia magna). Freshwater Algae: EC50: 187 - 279 mg/L, 72h static (Desmodesmus subspicatus); EC50: 0.0188 - 0.1044 mg/L, 96h static (Pseudokirchneriella subcapitata); EC50: = 46.42 mg/L, 96h (Pseudokirchneriella subcapitata)

12.2 Persistence and degradability

Not specified

12.3 Bioaccumulative potential

Not specified

12.4 Mobility in soil

Not specified

12.5 Results of PBT and vPvB assessment

Not specified

12.6 Endocrine disrupting properties

Not specified

12.7 Other adverse effects

Not specified

12.1 Toxicity

Phenol | EC50 21 - 36 mg/L 30 min | EC50 = 23.28 mg/L 5 min EC50 = 25.61 mg/L 15 min EC50 = 28.8 mg/L 5 min EC50 = 31.6 mg/L 15 min

12.2. Persistence and degradability

Persistence Degradation in sewage treatment plant Soluble in water, Persistence is unlikely, based on information available. Contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

Persistence is unlikely. Contains substances known to be hazardous to the environment or not degradable in waste water treatment plants.

12.3. Bioaccumulative potential

Bioaccumulation is unlikely | Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- |

Bioaccumulation is unlikely.

12.3 Bioaccumulative potential

Component: Phenol, log Pow: 1.47, Bioconcentration factor (BCF): 17.5

12.4. Mobility in soil

The product is water soluble, and may spread in water systems. Will likely be mobile in the environment due to its water solubility. Highly mobile in soils

12.5. Results of PBT and vPvB assessment

Substance is not considered persistent, bioaccumulative and toxic (PBT) / very persistent and very bioaccumulative (vPvB).

The substance is not considered to be PBT or vPvB.

12.6. Endocrine disrupting properties

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

The product does not contain any known or suspected endocrine disruptors.

12.7. Other adverse effects

Persistent Organic Pollutant Ozone Depletion Potential This product does not contain any known or suspected substance This product does not contain any known or suspected substance

The product does not contain any known or suspected persistent organic pollutants or substances that deplete the ozone layer.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Disposal

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Waste Codes

Not product specific Waste codes are not product specific, but application specific. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1671
Shipping Name
PHENOL, SOLID
Transport Class
6.1
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Take note of Directive 2000/39/EC establishing a first list of indicative occupational exposure limit values. UK - Take note of Control of Substances Hazardous to Health Regulations (COSHH) 2002 and 2005 Amendment. Swiss Regulations: Article 4 para. 4 of the Ordinance on the protection of young people in the workplace (SR 822.115) and Article 1 lit. f of the EAER regulation on hazardous work and young people (SR 822.115.2). Take note on Article 13 Maternity Ordinance (SR 822.111.52) with regards expectant and nursing mothers.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Phenol known by?

Phenol is also known as: Carbolic acid; Hydroxybenzene

What is the hazard signal word for Phenol?

The signal word is danger.

What is the physical form of Phenol?

Phenol is a crystalline solid appearing as colorless - translucent white . It has pungent odor.

What is Phenol used for?

Laboratory chemicals.

What are the hazard statements for Phenol?

This substance has 5 hazard statements:

  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
  • H314: Causes severe skin burns and eye damage
  • H341: Suspected of causing genetic defects
  • H373: May cause damage to organs through prolonged or repeated exposure
  • H411: Toxic to aquatic life with long lasting effects

What is the melting point of Phenol?

The melting point is 39 - 42 °C / 102.2 - 107.6 °F and the boiling point is 182 °C / 359.6 °F @ 760 mmHg.