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Safety Data Sheet EN

Phenol

CAS 108-95-2
EC 203-632-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Phenol
Product Code
P5566
Chemical Name
Phnol
Synonyms
Hydroxybenzene

Regulatory Identifiers

CAS Number
108-95-2 Check regulations →
EC Number
203-632-7 Check regulations →
REACH No.
01-2119471329-32-0018

Identified Uses

Laboratory chemicals, Synthesis of substances

Uses advised against

The product is being supplied under the TSCA R&D Exemption (40 CFR Section 720.36). It is the recipients responsibility to comply with the requirements of the R&D exemption. The product may not be used for a non-exempt commercial purpose under TSCA unless appropriate consent is granted in writing by MilliporeSigma.

Manufacturers & Suppliers

S

Sigma-Aldrich Inc.

global supplier

3050 SPRUCE ST ST. LOUIS MO 63103 UNITED STATES

+1 314 771-5765

Emergency Contacts

CHEMTREC

800-424-9300

24 Hours/day; 7 Days/week

CHEMTREC

+1-703-527-3887

24 Hours/day; 7 Days/week

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H331
Acute Tox. Cat. 3 H311
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Muta. Cat. 2 H341
STOT RE Cat. 2 H373
Aquatic Acute Cat. 2 H401
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H341 Suspected of causing genetic defects.
H373 May cause damage to organs (Nervous system, Kidney, Liver, Skin) through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.
P362 Take off contaminated clothing and wash before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Substances
Chemical Name CAS Number Concentration Hazardous
Phnol EC: 203-632-7 108-95-2 100% Yes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

After contact with skin: rinse out with polyethylene glycol 400 or a mixture of polyethylene glycol 300/ethanol 2:1 and wash with plenty of water. If neither is available wash with plenty of water. Immediately take off contaminated clothing. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.

Immediate Medical Attention

No data available

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact Material: Viton Minimum layer thickness: 0.7 mm Break through time: 480 min Material tested:Vitoject (KCL 890 / Aldrich Z677698, Size M). When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Viton Minimum layer thickness: 0.7 mm Break through time: 480 min Material tested:Vitoject (KCL 890 / Aldrich Z677698, Size M).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter A-(P3) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. required when dusts/vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Crystallisation Point
---
Density
1.13 g/cm3
Molecular Weight
---
Kinematic Viscosity
---
Partition Coefficient
log Pow: 1.47
Cloud Point
---
Vapor Density
3.2
Appearance
Form: solid
Auto Ignition Temperature
715 C (1319 F)
Bulk Density
---
Solubility In Water
87 g/l
Upper Explosive Limit
9.5 %(V)
Colour Intensity
---
Form
solid
Odor Threshold
0.005 ppm
Vapor Pressure
0.53 hPa
State Under Standard Conditions
---
Relative Evaporation Rate
---
Properties Status
---
Physical State
solid
Decomposition Temperature
No data available
Softening Point
---
Freezing Point
---
Solubility
---
Explosive Limits
---
Flash Point
79.0 C (174.2 F)
Boiling Point
181.8 C 359.2 F
Metal Corrosion
---
Solubility In Fat
---
Ph
6.0
Solidification Point
---
Voc Content
---
Evaporation Rate
No data available
Dynamic Viscosity
---
Melting Point
38 - 43 C (100 - 109 F)
Lower Explosive Limit
1.3 %(V)
Odor
stinging
Physical State Data
solid
Colour
---
Flammability
No data available
Relative Density
No data available
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1671
Shipping Name
Phenol, solid
Transport Class
6.1
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Phenol known by?

Phenol is also known as: Hydroxybenzene

What is the hazard signal word for Phenol?

The signal word is danger.

What is the physical form of Phenol?

Phenol is a solid appearing as form: solid . It has stinging odor.

What is Phenol used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Phenol?

This substance has 5 hazard statements:

  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
  • H314: Causes severe skin burns and eye damage.
  • H341: Suspected of causing genetic defects.
  • H373: May cause damage to organs (Nervous system, Kidney, Liver, Skin) through prolonged or repeated exposure.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Phenol?

The melting point is 38 - 43 C (100 - 109 F) and the boiling point is 181.8 C 359.2 F.

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