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Safety Data Sheet EN

Glutardialdehyde solution 25% for electron microscopy

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Glutardialdehyde solution 25% for electron microscopy
Product Code
1.04239, 104239

Regulatory Identifiers

CAS Number
N/A

Identified Uses

In vitro diagnostic reagent, Reagent for analysis

Uses advised against

This product is not intended for consumer use.

Manufacturers & Suppliers

M

Merck Life Science UK Limited

national supplier

New Road, The Old Brickyard, GILLINGHAM, Dorset, SP8 4XT, UNITED KINGDOM

+44 (0)1747 833-000

Emergency Contacts

CHEMTREC

+44 (0)870 8200418

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 + H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Glutaraldehyde EC: 203-856-5 111-30-8 25 - 30% Yes

Included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH)

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Immediately call in physician. Call a physician immediately. Immediately call in ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides. Mixture with combustible ingredients. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully with liquid-absorbent material. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Tightly closed. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0.40 mm, Break through time: > 480 min, Material tested: Camatril® (KCL 730 / Aldrich Z677442, Size M). Splash contact: Material: Latex gloves, Minimum layer thickness: 0.6 mm, Break through time: > 240 min, Material tested: Lapren® (KCL 706 / Aldrich Z677558, Size M). This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colorless
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
---
Ph
> 3.0 at 20 °C
Melting Point
-6 °C
Boiling Point
100.5 °C at 1,013 hPa
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
0.27 hPa at 20 °C
Vapor Density
---
Relative Density
No data available
Bulk Density
---
Density
1.06 g/cm³ at 20 °C
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature). heat-sensitive

Reactivity

No data available

Hazardous reactions

Violent reactions possible with: Amines, Strong oxidizing agents, Strong acids, Strong bases. Violent reactions possible with: The generally known reaction partners of water.

Avoid

Strong heating.

Incompatible

Aluminum, various metals

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Mixture No data available

No data available

12.2 Persistence and degradability

No data available

No data available

12.3 Bioaccumulative potential

No data available

No data available

12.4 Mobility in soil

No data available

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture does not contain PBT or vPvB components at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.1 Toxicity

Components Glutaraldehyde Toxicity to fish static test LC50 - Oncorhynchus mykiss (rainbow trout) - 0.8 mg/l - 96 h (US-EPA) Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - 0.6 mg/l - 72 h (OECD Test Guideline 201) Toxicity to bacteria

12.7 Other adverse effects

Biological effects: Bactericidal effect. Forms toxic mixtures in water, dilution measures notwithstanding. When discharged properly, no impairments in the function of adapted biological wastewater treatment plants are to be expected. Discharge into the environment must be avoided.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Waste material must be disposed of in accordance with the national and local regulations.

Disposal

Leave chemicals in original containers. No mixing with other waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1760
Shipping Name
CORROSIVE LIQUID, N.O.S. (Glutaraldehyde)
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed

Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Glutardialdehyde solution 25% for electron microscopy?

The signal word is danger.

What is the physical form of Glutardialdehyde solution 25% for electron microscopy?

Glutardialdehyde solution 25% for electron microscopy is a liquid with colorless color. It has characteristic odor.

What is Glutardialdehyde solution 25% for electron microscopy used for?

In vitro diagnostic reagent, Reagent for analysis

What are the hazard statements for Glutardialdehyde solution 25% for electron microscopy?

This substance has 6 hazard statements:

  • H302 + H332: Harmful if swallowed or if inhaled.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H335: May cause respiratory irritation.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Glutardialdehyde solution 25% for electron microscopy?

The melting point is -6 °C and the boiling point is 100.5 °C at 1,013 hPa.