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Safety Data Sheet EN

Glutardialdehyde solution 25% for electron microscopy, acc. to P.J. Anderson (purified and filled under nitrogen)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Glutardialdehyde solution 25% for electron microscopy, acc. to P.J. Anderson (purified and filled under nitrogen)
Product Code
112179

Regulatory Identifiers

CAS Number
N/A

Identified Uses

In vitro diagnostic reagent, Reagent for analysis

Manufacturers & Suppliers

Merck KGaA logo

Merck KGaA

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64271 Darmstadt * Germany

+49 6151 72-0

www.merck-chemicals.com

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Skin Corr. Cat. 1B H314
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 + H332 Harmful if swallowed or if inhaled
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.

Precautionary Statements

P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Mixture

Aqueous solution

Chemical Name CAS Number Concentration Hazardous
GLUTAARDIALDEHYDE EC: 203-856-5 111-30-8 25 - 50% Yes

Notes

purified and filled under nitrogen

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air. If breathing stops: mouth-to-mouth breathing or artificial respiration. Oxygen if necessary. Immediately call in physician.

Symptoms: Cough, Shortness of breath

Skin contact

wash off with plenty of water. Immediately remove contaminated clothing. If available swab with polyethylene glycol 400. Call a physician immediately.

Symptoms: Irritation and corrosion, Allergic reactions

Eye contact

rinse out with plenty of water. Immediately call in ophthalmologist.

Symptoms: conjunctivitis, Risk of corneal clouding., Risk of blindness!

Ingestion

caution if victim vomits. Risk of aspiration! Keep airways free. Risk of perforation! Call a physician immediately. Do not attempt to neutralise.

Symptoms: Diarrhoea, Nausea, Vomiting, Circulatory collapse, Headache, drowziness, Coma, death

Immediate Medical Attention

Immediately call in physician (for inhalation and swallowing). Call a physician immediately (for skin contact). Immediately call in ophthalmologist (for eye contact).

Medical Treatment

No information available.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: Nitrile rubber Glove thickness: 0,40 mm Break through time: - 480 min splash contact: Glove material: natural latex Glove thickness: 0,6 mm Break through time: - 240 min The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 730 Camatril -Velours (full contact), KCL 706 Lapren (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g., KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not empty into drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Softening Point
---
Flammability
No information available.
Solubility
---
Crystallisation Point
---
Density
---
Cloud Point
---
Melting Point
-6 C
Explosive Limits
---
Freezing Point
---
Voc Content
---
Molecular Weight
---
Relative Density
1,06 g/cm at 20 C
Flash Point
not applicable
Odor Threshold
No information available.
Solubility In Fat
---
Properties Status
---
State Under Standard Conditions
---
Vapor Pressure
0,27 hPa at 20 C
Physical State
liquid
Colour
colourless
Evaporation Rate
No information available.
Dynamic Viscosity
No information available.
Odor
characteristic
Upper Explosive Limit
not applicable
Decomposition Temperature
No information available.
Form
liquid
Metal Corrosion
---
Ph
- 3,0 at 20 C
Physical State Data
liquid
Appearance
---
Solubility In Water
soluble at 20 C
Partition Coefficient
No information available.
Lower Explosive Limit
not applicable
Colour Intensity
---
Auto Ignition Temperature
No information available.
Bulk Density
---
Vapor Density
---
Boiling Point
100,5 C at 1.013 hPa
Relative Evaporation Rate
---
Solidification Point
---
Kinematic Viscosity
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 2922
Shipping Name
CORROSIVE LIQUID, TOXIC, N.O.S. (GLUTARDIALDEHYDE SOLUTION)
Transport Class
8 (6.1)
Packing Group
II
ADR

yes

IMDG

yes

IATA

no

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Glutardialdehyde solution 25% for electron microscopy, acc. to P.J. Anderson (purified and filled under nitrogen)?

The signal word is danger.

What is the physical form of Glutardialdehyde solution 25% for electron microscopy, acc. to P.J. Anderson (purified and filled under nitrogen)?

Glutardialdehyde solution 25% for electron microscopy, acc. to P.J. Anderson (purified and filled under nitrogen) is a liquid with colourless color. It has characteristic odor.

What is Glutardialdehyde solution 25% for electron microscopy, acc. to P.J. Anderson (purified and filled under nitrogen) used for?

In vitro diagnostic reagent, Reagent for analysis

What are the hazard statements for Glutardialdehyde solution 25% for electron microscopy, acc. to P.J. Anderson (purified and filled under nitrogen)?

This substance has 6 hazard statements:

  • H302 + H332: Harmful if swallowed or if inhaled
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H335: May cause respiratory irritation.
  • H400: Very toxic to aquatic life.

What is the melting point of Glutardialdehyde solution 25% for electron microscopy, acc. to P.J. Anderson (purified and filled under nitrogen)?

The melting point is -6 C and the boiling point is 100,5 C at 1.013 hPa.

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