Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- Formaldehyde solution min. 37% free from acid stabilized with about 10% methanol and calcium carbonate for histology
- Product Code
- 103999
Regulatory Identifiers
- CAS Number
- N/A
- REACH No.
- This product is a mixture. REACH Registration Number see section 3.
Identified Uses
In vitro diagnostic reagent, Reagent for analysis
Manufacturers & Suppliers
Merck KGaA
manufacturer
64271 Darmstadt * Germany
+49 6151 72-0
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS05
GHS06
GHS08
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
First Aid Measures
Emergency procedures for chemical exposure incidents
fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary oxygen. Immediately call in physician.
Symptoms: Cough, Shortness of breath
Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
Symptoms: Irritation and corrosion, Allergic reactions
rinse out with plenty of water. Immediately call in ophthalmologist.
Symptoms: Impairment of vision, blindness, Risk of blindness!
immediately make victim drink water (two glasses at most). Call a physician immediately. Risk of perforation!
Symptoms: inebriation, Dizziness, Headache, Drowsiness, agitation, spasms, narcosis, Coma
Immediate Medical Attention
Immediately call in physician.
Medical Treatment
Mention methanol.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Water, Carbon dioxide (CO2), Foam, Dry powder
For this substance/mixture no limitations of extinguishing agents are given.
Mixture with combustible ingredients. Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.
Suppress (knock down) gases/vapours/mists with a water spray jet.
Firefighter Protection
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.
Do not empty into drains. Risk of explosion.
Take up with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.
Materials: liquid-absorbent material (e.g. Chemizorb®)
Related Products
Similar products with comparable safety profiles
Formaldehyde Solution, 36%, For Histology, Glassware Washing and other General Applications
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Formaldehyde solution about 37% stabilized with about 10% methanol Ph Eur,BP,USP
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Formaldehyde 4% aqueous solution, buffered Q path® Formalin 10%
CAS: 50-00-0
Formaldehyde in Methanol
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10% Formalin
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10% Formalin
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Formaldehyde
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Paraformaldehyde
CAS: 30525-89-4
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. Observe label precautions.
Tightly closed. Protected from light. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons. Recommended storage temperature see product label.
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.
full contact: - Glove material: Nitrile rubber - Glove thickness: 0,40 mm - Break through time: > 480 min splash contact: - Glove material: polychloroprene - Glove thickness: 0,65 mm - Break through time: > 240 min The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 730 Camatril® -Velours (full contact), KCL 720 Camapren® (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet <(>, <) > supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Tightly fitting safety goggles
required when vapours/aerosols are generated. Recommended Filter type: filter ABEK The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
protective clothing
Do not empty into drains. Risk of explosion.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The product is chemically stable under standard ambient conditions (room temperature). Stabilizer: Methanol, calcium carbonate
Reducing agents, tends to polymerise, Vapour/air-mixtures are explosive at intense warming. A range from approx. 15 Kelvin below the flash point is to be rated as critical.
Violent reactions possible with: polymerisation initiators, nitrogen oxides, hydrogen peroxide, Oxidizing agents, performic acid, phenol, acids, Alkali metals, bases, halogens
Heating.
various metals, various alloys
no information available
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- 2209
- Shipping Name
- FORMALDEHYDE SOLUTION
- Transport Class
- 8
- Packing Group
- III
yes
yes
no
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for Formaldehyde solution min. 37% free from acid stabilized with about 10% methanol and calcium carbonate for histology?
The signal word is danger.
What is the physical form of Formaldehyde solution min. 37% free from acid stabilized with about 10% methanol and calcium carbonate for histology?
Formaldehyde solution min. 37% free from acid stabilized with about 10% methanol and calcium carbonate for histology is a liquid with colourless color. It has stinging odor.
What is Formaldehyde solution min. 37% free from acid stabilized with about 10% methanol and calcium carbonate for histology used for?
In vitro diagnostic reagent, Reagent for analysis
What are the hazard statements for Formaldehyde solution min. 37% free from acid stabilized with about 10% methanol and calcium carbonate for histology?
This substance has 7 hazard statements:
- H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
- H314: Causes severe skin burns and eye damage.
- H317: May cause an allergic skin reaction.
- H335: May cause respiratory irritation.
- H341: Suspected of causing genetic defects.
- H350: May cause cancer.
- H370: Causes damage to organs (Eyes).
What is the melting point of Formaldehyde solution min. 37% free from acid stabilized with about 10% methanol and calcium carbonate for histology?
The melting point is < -15 °C and the boiling point is 93 - 96 °C at 1.013 hPa.