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Safety Data Sheet EN

SIGMACOVER 350 BASE OFFWHITE

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SIGMACOVER 350 BASE OFFWHITE
Product Form
Liquid.
Product Code
000001099807
Synonyms
00312532

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Professional applications, Used by spraying. Coating.

Uses advised against

Not applicable.

Manufacturers & Suppliers

P

PPG PMC Japan Co., Ltd.

manufacturer

8F, Shintetsu Bldg., 1-1, Daikaidori 1-chome, Kobe 652-0803 Japan

+81-78-574-2777

Emergency Contacts

Emergency Contact

078 574 2777

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Skin Irrit. Cat. 2
Eye Dam. Cat. 1
Skin Sens. Cat. 1
Muta. Cat. 2
Carc. Cat. 1A
Repr. Cat. 1B
STOT SE Cat. 1
STOT SE Cat. 3
STOT RE Cat. 1
Aquatic Acute Cat. 2
Aquatic Chronic Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapor.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H336 May cause drowsiness or dizziness.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H372 Causes damage to organs. (central nervous system (CNS), kidneys, liver, respiratory organs)
H400 Toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P261 Do not breathe vapor.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye or face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor.
P310 Immediately call a POISON CENTER or doctor.
P312 Call a POISON CENTER or doctor if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice or attention.
P403 Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Talc (containing no asbestos or quartz) 14807-96-6 15 - 20% No
Epoxy Resin (700<MW<=1100) 25036-25-3 12.5 - 15% No
crystalline silica, non-respirable powder (>10 microns) 14808-60-7 12.5 - 15% No
Xylene 1330-20-7 10 - 12.5% No
Titanium dioxide (excluding nanoparticle) 13463-67-7 7 - 10% No
bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 5 - 7% No
benzyl alcohol 100-51-6 3 - 5% No
isobutyl alcohol 78-83-1 3 - 5% No
Ethyl Benzene 100-41-4 2 - 3% No
Octadecanamide, N,N'-1,6-hexanediylbis [12-hydroxy- 55349-01-4 1 - 2% No
Crystalline silica (quartz) 14808-60-7 1 - 2% No
Silica (silicon dioxide containing crystalline and amorphous) 7631-86-9 0.1% No

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Adverse symptoms may include the following: nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

Symptoms: Causes damage to organs following a single exposure in contact with skin. Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction. Adverse symptoms may include the following: pain or irritation redness dryness cracking blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.

Symptoms: Causes serious eye damage. Adverse symptoms may include the following: pain, watering, redness.

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: Causes damage to organs following a single exposure if swallowed. Can cause central nervous system (CNS) depression. Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations

Immediate Medical Attention

Seek immediate medical attention. If swallowed, seek medical advice immediately and show this container or label.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is toxic to aquatic life. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material. Wash spillages into an effluent treatment plant.

Materials: Inert dry material, non-combustible absorbent material (sand, earth, vermiculite or diatomaceous earth)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Hygiene

Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Off-white
Colour Intensity
---
Form
---
Odor
Aromatic
Odor Threshold
---
Ph
---
Melting Point
---
Boiling Point
>37.78°C (>100°F)
Flash Point
Closed cup: 29.5°C (85.1°F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
1.48
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Not soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
60 - 100 s (ISO 6mm)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

When exposed to high temperatures may produce hazardous decomposition products.

Incompatible

Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids.

Decomposition

Depending on conditions, decomposition products may include the following materials: carbon oxides nitrogen oxides metal oxide/oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

| Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | Titanium dioxide (excluding nanoparticle) | Acute LC50 >100 mg/l Fresh water | Daphnia - Daphnia magna | 48 hours |

12.1 Toxicity

Product/ingredient name: bis-[4-(2,3-epoxipropoxi)phenyl]propane Result: Acute LC50 1.8 mg/l Fresh water, Species: Daphnia - daphnia magna, Exposure: 48 hours Result: Chronic NOEC 0.3 mg/l, Species: Daphnia, Exposure: 21 days

12.1 Toxicity

Product/ingredient name: isobutyl alcohol; Result: Acute EC50 1100 mg/l; Species: Daphnia; Exposure: 48 hours

12.1 Toxicity

Product/ingredient name: Ethyl Benzene Result: Acute EC50 1.8 mg/l Fresh water, Species: Daphnia, Exposure: 48 hours Result: Chronic NOEC 1 mg/l Fresh water, Species: Daphnia - Ceriodaphnia dubia

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

Acute EC50 2.2 g/L Fresh water, Daphnia - Daphnia magna - Neonate, 48 hours

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | | Acute LC50 >10000 mg/l | Fish | 96 hours | | | Chronic NOEC 12.5 mg/l Fresh water | Daphnia - Daphnia magna - Neonate | 21 days |

Persistence/degradability

| Product/ingredient name | Test | Result | | Dose | | Inoculum | | --- | --- | --- | --- | --- | --- | --- |

12.2 Persistence and degradability

Product/ingredient name | Test | Result | | Dose | | Inoculum | Ethyl Benzene | - | 79 % - Readily - 10 days | | - | | -

12.2 Persistence and degradability

Product/ingredient name: Xylene; Test: -; Result: Readily; Dose: -; Inoculum: -

12.2 Persistence and degradability

Product/ingredient name: bis-[4-(2,3-epoxipropoxi)phenyl]propane. Result: Not readily / Readily.

12.2 Persistence and degradability

benzyl alcohol | - | | - | | Readily | |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | | Dose | | Inoculum | | --- | --- | --- | --- | --- | --- | --- | | Ethyl Benzene | - | | - | | Readily | |

12.3 Bioaccumulative potential

## Bioaccumulative potential | Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- |

12.3 Bioaccumulative potential

Product/ingredient name: Xylene, LogPow: 3.12, BCF: 7.4 to 18.5, Potential: Low

12.3 Bioaccumulative potential

Product/ingredient name: benzyl alcohol, LogPow: 0.87, BCF: -, Potential: Low

12.3 Bioaccumulative potential

Product/ingredient name: isobutyl alcohol, LogPow: 1, BCF: -, Potential: Low

Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | Ethyl Benzene | 3.6 | 79.43 | Low |

Mobility in soil

Soil/Water partition coefficient : Not available. Mobility : Not available.

Other adverse effects

No known significant effects or critical hazards.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
PAINT
Transport Class
3
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is SIGMACOVER 350 BASE OFFWHITE known by?

SIGMACOVER 350 BASE OFFWHITE is also known as: 00312532

What is the hazard signal word for SIGMACOVER 350 BASE OFFWHITE?

The signal word is danger.

What is the physical form of SIGMACOVER 350 BASE OFFWHITE?

SIGMACOVER 350 BASE OFFWHITE is a liquid with off-white color. It has aromatic odor.

What is SIGMACOVER 350 BASE OFFWHITE used for?

Professional applications, Used by spraying. Coating.

What are the hazard statements for SIGMACOVER 350 BASE OFFWHITE?

This substance has 11 hazard statements:

  • H226: Flammable liquid and vapor.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H318: Causes serious eye damage.
  • H336: May cause drowsiness or dizziness.
  • H341: Suspected of causing genetic defects.
  • H350: May cause cancer.
  • H360: May damage fertility or the unborn child.
  • H372: Causes damage to organs. (central nervous system (CNS), kidneys, liver, respiratory organs)
  • H400: Toxic to aquatic life.
  • H412: Harmful to aquatic life with long lasting effects.