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Propyl chloroformate

DANGER liquid SDS/MSDS

Chemical Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
Propyl chloroformate
Product Code
249467

Regulatory Identifiers

CAS Number
N/A

Chemical Abstracts Service registry number - unique identifier for chemical substances

Uses Information

Identified Uses
Laboratory chemicals, Synthesis of substances

Overview

Propyl chloroformate is a colourless substance commonly used laboratory chemicals, synthesis of substances.

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Organize and access your chemical safety data with ease.

GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (Danger)

Hazard Classifications

Flam. Liq. Category 2 H225
Acute Tox. Category 4 H302
Acute Tox. Category 3 H331
Skin Corr. Category 1B H314
Eye Dam. Category 1 H318

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS05 GHS Hazard Pictogram: Corrosive hazard - Materials that can cause severe skin burns and eye damage

GHS05

GHS06 GHS Hazard Pictogram: Acute toxicity hazard - Poisonous materials that can cause death or serious harm

GHS06

GHS07 GHS Hazard Pictogram: Health hazard warning - Materials harmful to health including irritants and sensitizers

GHS07

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H225: Highly flammable liquid and vapour.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H318: Causes serious eye damage.
  • H331: Toxic if inhaled.

Precautionary Statements

  • P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
  • P233: Keep container tightly closed.
  • P240: Ground/bond container and receiving equipment.
  • P241: Use explosion-proof electrical/ ventilating/ lighting/ equipment.
  • P242: Use only non-sparking tools.
  • P243: Take precautionary measures against static discharge.
  • P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
  • P264: Wash skin thoroughly after handling.
  • P270: Do not eat, drink or smoke when using this product.
  • P271: Use only outdoors or in a well-ventilated area.
  • P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
  • IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth.
  • IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
  • IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.
  • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.
  • P363: Wash contaminated clothing before reuse.
  • In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
  • Store in a well-ventilated place. Keep container tightly closed.
  • Store in a well-ventilated place. Keep cool.
  • P405: Store locked up.
  • P501: Dispose of contents/ container to an approved waste disposal plant.

Chemical Manufacturers & Supply Chain

Authorized suppliers, manufacturers, and distribution network information

Sigma-Aldrich

manufacturer

📍

3050 Spruce Street, SAINT LOUIS MO 63103, USA

🌍

US

📞

+1 800-325-5832

📠

+1 800-325-5052

24/7 Emergency Response & Poison Control

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

CHEMTREC

📞

+1-703-527-3887

🌍

US

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
Propyl chloroformate
EC: 203-687-7
109-61-5 100% ⚠️ Hazardous

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

🫁 Inhalation Exposure

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

🖐️ Skin Contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

👁️ Eye Contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Continue rinsing eyes during transport to hospital.

🍽️ Ingestion/Swallowing

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Fire Fighting Measures & Emergency Response

Fire suppression methods, extinguishing media, and firefighting safety procedures

Suitable Extinguishing Media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

⚠️ Specific Fire Hazards

Carbon oxides, Hydrogen chloride gas

🔥 Fire Fighting Instructions

Wear self-contained breathing apparatus for firefighting if necessary.

Accidental Release Measures & Spill Response

Emergency spill cleanup procedures, containment methods, and environmental protection

🚨 Emergency Procedures

Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.

🌍 Environmental Precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

🧹 Cleanup Methods

Place in container for disposal according to local regulations.

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

🧪 Physical State
liquid
Critical Property
📊 Physical State Data
liquid
📊 State Under Standard Conditions
Not available
👁️ Appearance
colourless
🎨 Colour
colourless
📊 Colour Intensity
Not available
📊 Form
liquid
👃 Odor
No data available
📊 Odor Threshold
No data available
🧪 Ph
No data available
🧊 Melting Point
< - 69.99 ℃ (< - 93.98 °F)
Critical Property
💨 Boiling Point
105 - 106 ℃ (221 - 223 ºF) - lit.
Critical Property
🔥 Flash Point
26 °℃ (79 ºF) - closed cup
Critical Property
📊 Freezing Point
Not available
📊 Softening Point
Not available
📊 Solidification Point
Not available
📊 Cloud Point
Not available
📊 Crystallisation Point
Not available
📊 Relative Evaporation Rate
Not available
💨 Evaporation Rate
No data available
💨 Vapor Pressure
59.967 hPa (44.979 mmHg) at 20 ℃ (68 ºF)
📊 Vapor Density
No data available
📊 Relative Density
1.09 g/cm3 at 25 ℃ (77 ºF)
📊 Bulk Density
Not available
⚖️ Density
Not available
🔥 Flammability
No data available
📊 Upper Explosive Limit
No data available
📊 Lower Explosive Limit
No data available
📊 Explosive Limits
Not available
📊 Auto Ignition Temperature
No data available
📊 Decomposition Temperature
No data available
💧 Solubility
No data available
📊 Partition Coefficient
475 °C (887 ºF)
📊 Solubility In Water
No data available
📊 Solubility In Fat
Not available
📊 Molecular Weight
Not available
📊 Voc Content
Not available
📊 Metal Corrosion
Not available
📊 Dynamic Viscosity
Not available
📊 Kinematic Viscosity
Not available
📊 Properties Status
Not available

Safe Handling & Storage Procedures

Industrial handling precautions, storage conditions, and workplace safety requirements

⚠️ Handling Precautions

• Avoid contact with skin and eyes.

• Avoid inhalation of vapour or mist.

• Use explosion-proof equipment.

• Keep away from sources of ignition - No smoking.

• Take measures to prevent the build up of electrostatic charge.

🏪 Storage Conditions

• Keep container tightly closed in a dry and well-ventilated place.

• Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Exposure Controls & Personal Protective Equipment (PPE)

Occupational exposure limits, engineering controls, and required safety equipment

🏭 Engineering Controls

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

🧤 Hand Protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact: Material: butyl-rubber, Minimum layer thickness: 0.3 mm, Break through time: 480 min, Material tested: Butoject® (KCL 897 / Aldrich Z677647, Size M). Splash contact: Material: butyl-rubber, Minimum layer thickness: 0.3 mm, Break through time: 480 min, Material tested: Butoject® (KCL 897 / Aldrich Z677647, Size M). Data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail [email protected], test method: EN374. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

👁️ Eye Protection

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

😷 Respiratory Protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

🦺 Skin/Body Protection

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

🌍 Environmental Exposure Controls

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Chemical Stability & Reactivity Data

Chemical stability, hazardous reactions, and incompatible materials information

Chemical Stability

Stable under recommended storage conditions.

⚗️ Reactivity

No data available

⚠️ Hazardous Reactions

Vapours may form explosive mixture with air.

🚫 Conditions to Avoid

Heat, flames and sparks.

🧪 Incompatible Materials

Strong bases, Alcohols, Amines

💨 Hazardous Decomposition Products

Other decomposition products - No data available

Ecological Information & Environmental Impact

Environmental toxicity, biodegradation, bioaccumulation, and ecological effects data

🌱 Toxicity to fish

static test LC50 - Danio rerio (zebra fish) - 3.16 mg/l - 96 h (OECD Test Guideline 203)

🌱 Persistence and degradability

No data available

🌱 Bioaccumulative potential

No data available

🌱 Mobility in soil

No data available

🌱 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

🌱 Other adverse effects

No data available

Waste Disposal & Treatment Methods

Waste disposal procedures, treatment methods, and regulatory compliance requirements

♻️ Waste Treatment Methods

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

🗂️ Product Disposal Recommendations

Contact a licensed professional waste disposal service to dispose of this material.

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

🏷️ UN Number

2740

📦 Proper Shipping Name

n-Propyl chloroformate

⚠️ Transport Hazard Class

6.1

📋 Packing Group

I

🚢 IMDG Maritime Transport Precautions

F-E, S-C

Regulatory Information & Compliance

Chemical regulations, safety assessments, and regulatory compliance status

📋 Regulatory Summary

This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Chemical Safety Assessment

No chemical safety assessment has been performed for this substance.

ℹ️ Additional Regulatory Information

Fire Hazard, Acute Health Hazard

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for Propyl chloroformate?

The signal word for this substance is "danger".

What is the physical form of Propyl chloroformate?

Propyl chloroformate is a liquid appearing as colourless with colourless color. It has no data available odor.

What is the solubility of Propyl chloroformate?

No data available

What is Propyl chloroformate used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Propyl chloroformate?

This substance has 5 hazard statements: H225: Highly flammable liquid and vapour. H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H318: Causes serious eye damage. H331: Toxic if inhaled.

What is the melting point of Propyl chloroformate?

The melting point is < - 69.99 ℃ (< - 93.98 °F) and the boiling point is 105 - 106 ℃ (221 - 223 ºF) - lit..