Chemical Product Identification & Regulatory Data
Official chemical identifiers, CAS numbers, and regulatory compliance information
Basic Product Information
Regulatory Identifiers
Chemical Abstracts Service registry number - unique identifier for chemical substances
Uses Information
Overview
Methyl chloroformate is a colourless substance commonly used laboratory chemicals, synthesis of substances.
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Organize and access your chemical safety data with ease.
GHS Hazard Classification & Safety Warnings
Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications
Classification Status
Signal Word
Hazard Classifications
GHS Hazard Pictograms & Safety Symbols
GHS02
GHS05
GHS06
GHS07
GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions
Hazard Statements
- H225: Highly flammable liquid and vapour.
- H302: Harmful if swallowed or in contact with skin
- H312: Harmful if swallowed or in contact with skin
- H314: Causes severe skin burns and eye damage.
- H318: Causes serious eye damage.
- H330: Fatal if inhaled.
Precautionary Statements
- P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
- P233: Keep container tightly closed.
- P240: Ground/bond container and receiving equipment.
- P241: Use explosion-proof electrical/ ventilating/ lighting/ equipment.
- P242: Use only non-sparking tools.
- P243: Take precautionary measures against static discharge.
- P260: Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
- P264: Wash skin thoroughly after handling.
- P270: Do not eat, drink or smoke when using this product.
- P271: Use only outdoors or in a well-ventilated area.
- P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
- P284: Wear respiratory protection.
- IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
- P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
- P303+P361+P353: IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
- IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
- P363: Wash contaminated clothing before reuse.
- P370+P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
- P403+P233: Store in a well-ventilated place. Keep container tightly closed.
- P403+P235: Store in a well-ventilated place. Keep cool.
- P405: Store locked up.
- P501: Dispose of contents/ container to an approved waste disposal plant.
Chemical Manufacturers & Supply Chain
Authorized suppliers, manufacturers, and distribution network information
Sigma-Aldrich
manufacturer
3050 Spruce Street SAINT LOUIS MO 63103 USA
US
+1 800-325-5832
+1 800-325-5052
24/7 Emergency Response & Poison Control
Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies
CHEMTREC
+1-703-527-3887
US
Chemical Composition & Hazardous Ingredients
Detailed component analysis, concentration ranges, and hazardous substance identification
Chemical Components & Hazardous Substances
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Methyl chloroformate EC: 201-187-3 | 79-22-1 | 90-100% | ⚠️ Hazardous |
Emergency First Aid Measures
Critical first aid procedures for chemical exposure incidents and medical emergencies
🫁 Inhalation Exposure
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
🖐️ Skin Contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
👁️ Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Continue rinsing eyes during transport to hospital.
🍽️ Ingestion/Swallowing
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Fire Fighting Measures & Emergency Response
Fire suppression methods, extinguishing media, and firefighting safety procedures
✅ Suitable Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
🔥 Fire Fighting Instructions
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental Release Measures & Spill Response
Emergency spill cleanup procedures, containment methods, and environmental protection
🚨 Emergency Procedures
Evacuate personnel to safe areas. Ensure adequate ventilation. Remove all sources of ignition.
🌍 Environmental Precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
🧹 Cleanup Methods
Place in container for disposal according to local regulations.
Related Chemical Substances & Alternative Products
Similar chemicals with comparable safety profiles and industrial applications
Technical Specifications & Material Properties
Physical state, chemical properties, melting point, boiling point, and material characteristics
Safe Handling & Storage Procedures
Industrial handling precautions, storage conditions, and workplace safety requirements
⚠️ Handling Precautions
• Avoid contact with skin and eyes.
• Avoid inhalation of vapour or mist.
• Use explosion-proof equipment.
• Keep away from sources of ignition - No smoking.
• Take measures to prevent the build up of electrostatic charge.
🏪 Storage Conditions
• Keep container tightly closed in a dry and well-ventilated place.
• Containers which are opened must be carefully resealed and kept upright to prevent leakage.
🔥 Fire Prevention Measures
Keep away from sources of ignition - No smoking.
Exposure Controls & Personal Protective Equipment (PPE)
Occupational exposure limits, engineering controls, and required safety equipment
🏭 Engineering Controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
🧤 Hand Protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: butyl-rubber Minimum layer thickness: 0.3 mm Break through time: 480 min Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M) Splash contact Material: butyl-rubber Minimum layer thickness: 0.3 mm Break through time: 480 min Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail [email protected], test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
👁️ Eye Protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
😷 Respiratory Protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
🦺 Skin/Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
🌍 Environmental Exposure Controls
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Chemical Stability & Reactivity Data
Chemical stability, hazardous reactions, and incompatible materials information
✅ Chemical Stability
Stable under recommended storage conditions.
⚗️ Reactivity
No data available
⚠️ Hazardous Reactions
Vapours may form explosive mixture with air.
🚫 Conditions to Avoid
Heat, flames and sparks.
🧪 Incompatible Materials
Amines, Strong bases, Alcohols, Water, Dimethylformamide, Dimethyl sulfoxide. (DMSO)
💨 Hazardous Decomposition Products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen chloride gas. Other decomposition products - No data available.
Ecological Information & Environmental Impact
Environmental toxicity, biodegradation, bioaccumulation, and ecological effects data
🌱 Toxicity
🌱 Persistence and degradability
🌱 Bioaccumulative potential
🌱 Mobility in soil
🌱 Results of PBT and vPvB assessment
🌱 Endocrine disrupting properties
Waste Disposal & Treatment Methods
Waste disposal procedures, treatment methods, and regulatory compliance requirements
♻️ Waste Treatment Methods
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
🗂️ Product Disposal Recommendations
Dispose of as unused product.
Transportation & Shipping Information
UN numbers, shipping names, transport classes, and regulatory transport requirements
🏷️ UN Number
1238
📦 Proper Shipping Name
Methyl chloroformate
⚠️ Transport Hazard Class
6.1 (3, 8)
📋 Packing Group
I
🚢 IMDG Maritime Transport Precautions
F-E, S-C
Regulatory Information & Compliance
Chemical regulations, safety assessments, and regulatory compliance status
📋 Regulatory Summary
The following components are subject to reporting levels established by SARA Title III, Section 302 and Section 313. Fire Hazard and Acute Health Hazard are noted.
❌ Chemical Safety Assessment
No chemical safety assessment has been performed for this substance.
Chemical Safety FAQ & Common Questions
Most frequently asked questions about safety, handling, storage, and regulatory compliance
What is the hazard signal word for Methyl chloroformate?
The signal word for this substance is "danger".
What is the physical form of Methyl chloroformate?
Methyl chloroformate is a liquid appearing as colourless with colourless color. It has no data available odor.
What is the solubility of Methyl chloroformate?
No data available
What is Methyl chloroformate used for?
Laboratory chemicals, Synthesis of substances
What are the hazard statements for Methyl chloroformate?
This substance has 6 hazard statements: H225: Highly flammable liquid and vapour. H302: Harmful if swallowed or in contact with skin H312: Harmful if swallowed or in contact with skin H314: Causes severe skin burns and eye damage. H318: Causes serious eye damage. H330: Fatal if inhaled.
What is the melting point of Methyl chloroformate?
The melting point is < - 80.99 ℃ ( < - 113.78 ºF) and the boiling point is 70 - 72 °℃ (158 - 162 ºF) - lit..