1-Chloroethyl chloroformate

Remove from exposure, lie down. Remove to fresh air. If not breathing, give artificial respiration. Immediate medical attention is required.

Symptoms: Difficulty in breathing.

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is required.

Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. Call a physician immediately. Clean mouth with water. If possible drink milk afterwards.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

Carbon dioxide (CO₂). Dry chemical. Chemical foam. Water mist may be used to cool closed containers.

Water.

Flammable. Contact with water liberates toxic gas. Water reactive. Produce flammable gases on contact with water. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

See Section 12 for additional Ecological Information. Do not let this chemical enter the environment.

Soak up with inert absorbent material

Materials: sand, silica gel, acid binder, universal binder, sawdust

Do not breathe mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not ingest. If swallowed then seek immediate medical assistance.

Keep in a dry place. Keep container tightly closed. Keep away from heat, sparks and flame. Corrosives area. Flammables area. Keep under nitrogen. Keep refrigerated. Keep containers tightly closed in a dry, cool and well-ventilated place.

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Keep away from heat, sparks and flame. Use spark-proof tools. Take precautionary measures against static discharges.

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof electrical/ventilating/lighting/equipment. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Protective gloves. Glove material: Natural rubber, Butyl rubber, Nitrile rubber, Neoprene, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement)

Goggles (European standard - EN 166)

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Particulates filter conforming to EN 143 Acid gases filter Type E Yellow conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

No information available.

Stable under normal conditions. Moisture sensitive.

Yes

Hazardous polymerization does not occur. No information available.

Keep away from open flames, hot surfaces and sources of ignition. Incompatible products. Exposure to moist air or water.

Bases. Strong oxidizing agents. Alcohols. Amines.

Carbon monoxide (CO). Carbon dioxide (CO₂). Hydrogen chloride gas.

Waste is classified as hazardous. Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

No special precautions required

No special precautions required