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Safety Data Sheet EN

ortho-Phosphoric acid 85% for analysis EMSURE® ACS, ISO, Reag. Ph Eur

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ortho-Phosphoric acid 85% for analysis EMSURE® ACS, ISO, Reag. Ph Eur
Product Code
100573

Regulatory Identifiers

CAS Number
N/A
REACH No.
This product is a mixture. REACH Registration Number see section 3.

Identified Uses

Reagent for analysis, Chemical production

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1B H314

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/ physician.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Chemical nature Aqueous solution

Chemical Name CAS Number Concentration Hazardous
phosphoric acid 7664-38-2 50 - 100% Yes

The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16. For the full text of the R-phrases mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air. Call in physician.

Symptoms: Cough, Shortness of breath

Skin contact

wash off with plenty of water. Remove contaminated clothing. Call a physician immediately.

Symptoms: Irritation and corrosion, Pain

Eye contact

rinse out with plenty of water. Immediately call in ophthalmologist.

Symptoms: conjunctivitis, Risk of blindness!

Ingestion

make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Symptoms: Pain, Spasm, shock

Immediate Medical Attention

Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Not combustible. Ambient fire may liberate hazardous vapours.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Collect, bind, and pump off spills. Take up with liquid-absorbent and neutralising material. Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions.

Storage

Tightly closed. Recommended storage temperature see product label.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, break through time: > 480 min; splash contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact), KCL 741 Dermatril® L (splash contact).

Eyes

Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: Filter P 2 (acc. to DIN 3181) for solid and liquid particles of harmful substances. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Vapor Pressure
2 hPa at 20 °C
Properties Status
---
Ph
< 0,5 at 100 g/l 20 °C
Vapor Density
---
Odor
odourless
Solubility In Fat
---
Voc Content
---
Bulk Density
---
Auto Ignition Temperature
No information available.
Melting Point
ca. 21 °C
Evaporation Rate
No information available.
Solidification Point
---
Flammability
No information available.
Explosive Limits
---
Appearance
---
Flash Point
does not flash
Colour
colourless
Solubility In Water
soluble at 20 °C
Kinematic Viscosity
30,5 mm²/s at 20 °C
Decomposition Temperature
No information available.
Crystallisation Point
---
Physical State
liquid
Metal Corrosion
May be corrosive to metals.
Freezing Point
---
State Under Standard Conditions
---
Boiling Point
ca. 158 °C at 1.013 hPa
Cloud Point
---
Density
1,71 g/cm³ at 20 °C
Physical State Data
liquid
Lower Explosive Limit
not applicable
Solubility
---
Relative Evaporation Rate
---
Molecular Weight
---
Dynamic Viscosity
No information available.
Upper Explosive Limit
not applicable
Relative Density
No information available.
Softening Point
---
Partition Coefficient
No information available.
Form
liquid
Colour Intensity
---
Odor Threshold
not applicable
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

See section 10.3

Hazardous reactions

Risk of ignition or formation of inflammable gases or vapours with: Metals, metal alloys. Possible formation of: Hydrogen. Violent reactions possible with: bases, metallic oxides

Avoid

no information available

Incompatible

Aluminium, iron/iron-containing compounds, Mild steel. Gives off hydrogen by reaction with metals.

Decomposition

in the event of fire: See section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1805
Shipping Name
PHOSPHORIC ACID, SOLUTION
Transport Class
8
Packing Group
III
ADR

yes

IMDG

yes

IATA

no

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for ortho-Phosphoric acid 85% for analysis EMSURE® ACS, ISO, Reag. Ph Eur?

The signal word is danger.

What is the physical form of ortho-Phosphoric acid 85% for analysis EMSURE® ACS, ISO, Reag. Ph Eur?

ortho-Phosphoric acid 85% for analysis EMSURE® ACS, ISO, Reag. Ph Eur is a liquid with colourless color. It has odourless odor.

What is ortho-Phosphoric acid 85% for analysis EMSURE® ACS, ISO, Reag. Ph Eur used for?

Reagent for analysis, Chemical production

What are the hazard statements for ortho-Phosphoric acid 85% for analysis EMSURE® ACS, ISO, Reag. Ph Eur?

This substance has 2 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of ortho-Phosphoric acid 85% for analysis EMSURE® ACS, ISO, Reag. Ph Eur?

The melting point is ca. 21 °C and the boiling point is ca. 158 °C at 1.013 hPa.