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Safety Data Sheet EN

Potassium hydroxide pellets for analysis (max. 0.05% Na) EMSURE® ACS, Reag. Ph Eur

CAS 1310-58-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Potassium hydroxide pellets for analysis (max. 0.05% Na) EMSURE® ACS, Reag. Ph Eur
Product Code
1.05029
Chemical Name
Potassium hydroxide

Regulatory Identifiers

CAS Number
1310-58-3 Check regulations →
REACH No.
01-2119487136-33-XXXX

Identified Uses

Reagent for analysis, Chemical production

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

Frankfurter Str. 250, D-64271 DARMSTADT

+49 (0)6151 72-0

Emergency Contacts

CHEMTREC (GB)

+(44)-870-8200418

CHEMTREC Ireland

+(353)-19014670

CHEMTREC India

001-803-017-9114

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dusts or mists.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
caustic potash EC: 215-181-3 1310-58-3 --- Yes

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Eye contact

After eye contact: rinse out with plenty of water. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Do not attempt to neutralise.

Immediate Medical Attention

Call in physician. Call a physician immediately. Immediately call in ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Potassium oxides. Ambient fire may liberate hazardous vapours.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up dry. Clean up affected area.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

No aluminium, tin, or zinc containers. No metal containers. Tightly closed. Dry. Recommended storage temperature see product label.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
colorless
Colour
colorless
Colour Intensity
---
Form
solid
Odor
odorless
Odor Threshold
Not applicable
Ph
ca.13,5 at 5,6 g/l at 25 °C
Melting Point
360 °C
Boiling Point
1.327 °C at 1.013 hPa
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
1 hPa at 719 °C
Vapor Density
No data available
Relative Density
No data available
Bulk Density
---
Density
2,04 g/cm3 at 20 °C
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
Not applicable for inorganic substances
Solubility In Water
1.130 g/l at 20 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

No data available

Hazardous reactions

Risk of explosion with: Tetrahydrofuran, Peroxides, sodium azide, benzoyl chloride, Calcium (in powder form), carbides, Chlorine, halogen oxides, organic nitro compounds, phosphorus, nonmetallic oxides, chlorine dioxide, Fluorine, magnesium, Nitroso compound, nitrogen trichloride. Exothermic reaction with: acetonitrile, Acrolein, Aldehydes, Alcohols, acetic acid, Halogenated hydrocarbon, halogen-halogen compounds, Peroxides, hydrogen sulphide, hydrogen peroxide, vinyl acetate, Reducing agents, Acids, Acid chlorides, Acid anhydrides, peroxi compounds, Methanol, Chloroform. Risk of ignition or formation of inflammable gases or vapours with: Aluminum, Ammonium salts, Germanium, anhydrides, Oxides of phosphorus, azides, Lead, Copper, Copper alloys, Tin, Zinc. Release of: Hydrogen.

Avoid

no information available

Incompatible

animal/vegetable tissues, glass, various plastics, Metals

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity to fish LC50 - Gambusia affinis (Mosquito fish) - 80 mg/l - 96 h

12.2 Persistence and degradability

The methods for determining the biological degradability are not applicable to inorganic substances.

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture does not contain PBT or vPvB components at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

Harmful effect due to pH shift. Forms corrosive mixtures with water even if diluted. Neutralisation possible in waste water treatment plants. Discharge into the environment must be avoided.

Harmful effect due to pH shift. Forms corrosive mixtures with water even if diluted. Neutralisation possible in waste water treatment plants. Discharge into the environment must be avoided.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

Disposal

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1813
Shipping Name
POTASSIUM HYDROXIDE, SOLID
Transport Class
8
Packing Group
II
ADR

No data available

IMDG

No data available

IATA

No data available

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Potassium hydroxide pellets for analysis (max. 0.05% Na) EMSURE® ACS, Reag. Ph Eur?

The signal word is danger.

What is the physical form of Potassium hydroxide pellets for analysis (max. 0.05% Na) EMSURE® ACS, Reag. Ph Eur?

Potassium hydroxide pellets for analysis (max. 0.05% Na) EMSURE® ACS, Reag. Ph Eur is a solid appearing as colorless with colorless color. It has odorless odor.

What is Potassium hydroxide pellets for analysis (max. 0.05% Na) EMSURE® ACS, Reag. Ph Eur used for?

Reagent for analysis, Chemical production

What are the hazard statements for Potassium hydroxide pellets for analysis (max. 0.05% Na) EMSURE® ACS, Reag. Ph Eur?

This substance has 3 hazard statements:

  • H290: May be corrosive to metals.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of Potassium hydroxide pellets for analysis (max. 0.05% Na) EMSURE® ACS, Reag. Ph Eur?

The melting point is 360 °C and the boiling point is 1.327 °C at 1.013 hPa.