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Safety Data Sheet EN

Potassium dichromate for analysis EMSURE® ACS,ISO,Reag. Ph Eur

CAS 7778-50-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Potassium dichromate for analysis EMSURE® ACS,ISO,Reag. Ph Eur
Product Code
1.04864
Chemical Name
Potassium dichromate

Regulatory Identifiers

CAS Number
7778-50-9 Check regulations →
REACH No.
01-2119454792-32-XXXX

Identified Uses

Reagent for analysis

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

Frankfurter Str. 250, D-64271 DARMSTADT

+49 (0)6151 72-0

Emergency Contacts

CHEMTREC (GB)

+(44)-870-8200418

CHEMTREC Ireland

+(353)-19014670

CHEMTREC India

001-803-017-9114

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Ox. Sol. Cat. 2 H272
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 2 H330
Acute Tox. Cat. 4 H312
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
Muta. Cat. 1B H340
Carc. Cat. 1B H350
Repr. Cat. 1B H360FD
STOT SE Cat. 3 H335
STOT RE Cat. 1 H372
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS03 - Oxidizing

GHS03

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H272 May intensify fire; oxidizer.
H301 Toxic if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H340 May cause genetic defects.
H350 May cause cancer.
H360FD May damage fertility. May damage the unborn child.
H372 Causes damage to organs (Cardio-vascular system) through prolonged or repeated exposure if inhaled.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe dust.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
potassium dichromate EC: 231-906-6 7778-50-9 100% Yes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise.

Immediate Medical Attention

Immediately call in physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Potassium oxides, Chromium oxides. Not combustible. Has a fire-promoting effect due to release of oxygen. Ambient fire may liberate hazardous vapours.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate the danger area, observe emergency procedures, consult an expert.

Cleanup methods

Take up carefully.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

No metal containers. Tightly closed. Keep locked up or in an area accessible only to qualified or authorized persons. Do not store near combustible materials. Recommended storage temperature see product label.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Recommendations based on EN 16523-1.

Eyes

Tightly fitting safety goggles. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Required when dusts are generated. Recommended Filter type: Filter type P3. Standards: DIN EN 143, DIN 14387.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Bulk Density
1.250 kg/m3
Boiling Point
> 500 °C
State Under Standard Conditions
---
Metal Corrosion
---
Softening Point
---
Properties Status
---
Explosive Limits
---
Odor
odorless
Solidification Point
---
Solubility In Water
ca.29,4 g/l at 20 °C
Colour Intensity
---
Flammability
No data available
Odor Threshold
---
Vapor Density
---
Melting Point
390 °C
Relative Evaporation Rate
---
Flash Point
Not applicable
Vapor Pressure
Not applicable
Upper Explosive Limit
No data available
Ph
3,5 - 5,0 at 29,4 g/l at 25 °C
Decomposition Temperature
ca. 500 °C
Solubility
---
Auto Ignition Temperature
does not ignite
Physical State Data
solid
Density
ca.2,680 g/cm3 at 20 °C
Freezing Point
390 C - 500 C at 1.013 hPa - Decomposition
Solubility In Fat
---
Evaporation Rate
---
Cloud Point
---
Dynamic Viscosity
No data available
Physical State
crystalline
Lower Explosive Limit
No data available
Voc Content
---
Form
---
Colour
orange
Kinematic Viscosity
No data available
Relative Density
ca.2,7 at 20 °C
Molecular Weight
---
Crystallisation Point
---
Partition Coefficient
Not applicable for inorganic substances
Appearance
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

No data available

Hazardous reactions

Risk of explosion with: Iron, magnesium, hydrazine and derivatives, hydroxylamine, ammonium nitrate, Boron. Exothermic reaction with: anhydrides, phosphides, Sulfides, nitrides, Fluorine. Risk of ignition or formation of inflammable gases or vapours with: organic combustible substances, glycerol, Powdered metals, hydrides, alkali compounds, Acetone with sulfuric acid. Generates dangerous gases or fumes in contact with: hydrochloric acid.

Avoid

no information available

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

No data available

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3086
Shipping Name
TOXIC SOLID, OXIDIZING, N.O.S. (potassium dichromate)
Transport Class
6.1 (5.1)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Potassium dichromate for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

The signal word is danger.

What is the physical form of Potassium dichromate for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

Potassium dichromate for analysis EMSURE® ACS,ISO,Reag. Ph Eur is a crystalline with orange color. It has odorless odor.

What is Potassium dichromate for analysis EMSURE® ACS,ISO,Reag. Ph Eur used for?

Reagent for analysis

What are the hazard statements for Potassium dichromate for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

This substance has 13 hazard statements:

  • H272: May intensify fire; oxidizer.
  • H301: Toxic if swallowed.
  • H312: Harmful in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H330: Fatal if inhaled.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H335: May cause respiratory irritation.
  • H340: May cause genetic defects.
  • H350: May cause cancer.
  • H360FD: May damage fertility. May damage the unborn child.
  • H372: Causes damage to organs (Cardio-vascular system) through prolonged or repeated exposure if inhaled.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Potassium dichromate for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

The melting point is 390 °C and the boiling point is > 500 °C.