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Safety Data Sheet EN

UV-topcoat/high-gloss

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
UV-topcoat/high-gloss
Product Code
LM 4619/2

Regulatory Identifiers

CAS Number
N/A

Identified Uses

UV-Locquer

Manufacturers & Suppliers

Lott-Lacke GmbH logo

Lott-Lacke GmbH

manufacturer

Bunsenstrasse 22, 32052 Herford

+49 (0) 5221 - 29794-0

http://www.lott-lacke.de

Emergency Contacts

Emergency Contact

0800-181-7059

Emergency Contact

1-800-424-9300

Emergency Contact

H301 703 527 3887

Emergency Contact

4001 204937

ZH

Centoneus

800 968 793

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.
Water protection
Fire
Water

Precautionary Statements

P235 P235
P260 P260
P280 P280
P238
P202 + P352
P305 + P361 + P338

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Acrylate preparation

Chemical Name CAS Number Concentration Hazardous
oxylin(methyl-2,1-ethanediyl) diacrylate EC: 260-754-3 57472-69-1 10 - 12.5% Yes
Propylidynetrimethanol, ethoxylated, esters with acrylic acid EC: 500-066-5 28961-43-5 12.5 - 20% Yes
hexamethylene diacrylate EC: 235-921-9 13049-33-4 5 - 10% Yes
2-Propenoic acid, reaction products with glycidyl tert-decanoate EC: 305-033-5 94624-09-6 5 - 10% Yes
2-hydroxy-2-methylpropiophenone EC: 231-272-0 7473-98-5 1 - 2.5% Yes
methyl benzoyllormate EC: 239-263-3 15206-59-0 1 - 2.5% Yes
Acrylic acid EC: 201-177-9 79-10-7 0.5% Yes
2,2-tric(acryloyloxymethyl)butyl acrylate EC: 239-701-3 15625-69-5 0.5% Yes

Full text of classification: see section 16

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove casualty to fresh air and keep warm and at rest. In case of irregular breathing or respiratory arrest provide artificial respiration. Call a physician immediately. If unconscious place in recovery position and seek medical advice.

Skin contact

Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do not use solvents or thinners. Conditions to avoid: UV-radiation/sunlight. Call a physician immediately. Wash contaminated clothing before reuse.

Symptoms: May irritate skin. May cause sensitisation by skin contact.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice immediately. Show this safety data sheet to the doctor in attendance.

Symptoms: May irritate eyes.

Ingestion

Remove casually to fresh air and keep warm and at rest. Seek medical advice immediately. Show this safety data sheet to the doctor in attendance. Keep victim calm. Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person or a person with cramps. If unconscious place in recovery position and seek medical advice. Do not leave affected person unattended.

Immediate Medical Attention

Call a physician immediately.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Co-ordinate fire-fighting measures to the fire surroundings.

Unsuitable media

strong water jet

Specific hazards

Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.

Instructions

Cool closed containers that are near the source of the fire.

Firefighter Protection

Wear a self-contained breathing apparatus and chemical protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours. Keep people away from and upwind of spill/leak. Special danger of slipping by leaking/spilling product.

Environmental

Do not allow to enter into surface water or drains.

Cleanup methods

Clean using cleansing agents. Do not use solvents.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only in well-ventilated areas. Keep away from heat sources, sparks and open flames. Avoid contact with skin, eyes and clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using do not eat, drink or smoke. Personal protection equipment: refer to section 8. Do not empty containers with pressure - no pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal protection and safety regulations.

Storage

Store in a well-ventilated and dry room at temperatures between 15 °C and 30 °C. Protect from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Store carefully closed containers upright to prevent any leaks.

Hygiene

Wash hands before breaks and after work. Take off immediately all contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Handle in accordance with good industrial hygiene and safety practice. Keep work clothes separately. Wash contaminated clothing prior to re-use. Keep away from food, drink and animal feedingstuffs.

Fire prevention

Keep away from heat sources, sparks and open flames.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide good ventilation. This can be achieved with local or room suction.

Hands

For prolonged or repeated handling the following glove material must be used: Chemical proof safety gloves. Thickness of the glove material > 0,4 mm; Breakthrough time (maximum wearing time) > 480 min. Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended glove articles DIN EN 374. Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.

Eyes

Wear eye glasses with side protection according to EN 166.

Respiratory

If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection must be used. Observe the wear time limits according Ge/ScoffV in combination with the rules for using respiratory protection apparatus (SGR 190). Use only respiratory protection equipment with CE-symbol including four digit test number. respirator with AP-filter (EN 14387)

Skin/Body

Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers.

Environmental

Do not allow to enter into surface water or drains. Discharge into the environment must be avoided. If the product contaminates lakes, rivers or sewages, inform competent authorities in accordance with local regulations.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Squid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
not determined
Ph
not determined
Melting Point
not applicable
Boiling Point
not determined
Flash Point
> 88 °C
Freezing Point
not applicable
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
not determined
Vapor Pressure
not determined
Vapor Density
not determined
Relative Density
not determined
Bulk Density
---
Density
not determined
Flammability
---
Upper Explosive Limit
not determined
Lower Explosive Limit
not determined
Explosive Limits
---
Auto Ignition Temperature
not determined
Decomposition Temperature
not determined
Solubility
---
Partition Coefficient
See section 12.
Solubility In Water
Insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable under storage at normal ambient temperatures.

Reactivity

No dangerous reaction known under conditions of normal use.

Hazardous reactions

No hazardous reaction when handled and stored according to provisions.

Avoid

Heat, strong ultraviolet radiation, frost.

Incompatible

Radical former, Oxidising agent, Peroxides.

Decomposition

Hazardous decomposition byproducts may form with exposure to high temperatures.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

2,2-bis(acryloyloxymethyl)butyl acrylate Fish toxicity, LC50, Leuciscus idus (golden orfe): 1 - 2,2 mg/L (96 h) Daphnia toxicity, EC50, Daphnia magna (Big water flea): 19,9 mg/L (48 h) Algae toxicity, EtC50, Scenedesmus subspicatus: 4,9 mg/L (72 h) Acrylic acid Fish toxicity, LC50, Brachydanio rerio (zebra-fish): 222 mg/L (96 h) Daphnia toxicity, EC50, Daphnia magna (Big water flea): 95 mg/L (48 h) Algae toxicity, EtC50, Scenedesmus subspicatus: 0,04 mg/L (72 h) hecamethylene diacrylate Fish toxicity, LC50, Leuciscus idus (golden orfe): 4,61 - 9,9 mg/L (96 h) Method: DIN 38412 / part 15 Daphnia toxicity, EC50, Daphnia magna (Big water flea): 2,6 mg/L (48 h) Algae toxicity, EtC50, Scenedesmus subspicatus: 1,5 mg/L (72 h) Method: DIN 38412 / part 9 Propyldymetrimethanol, ethoxylated, esters with acrylic acid Fish toxicity, LC50, Brachydanio rerio (zebra-fish): 1,95 mg/L (96 h) Method: OECD 203 Daphnia toxicity, EC50, Daphnia magna: 70,7 mg/L (48 h) Method: OECD 202 Algae toxicity, EtC50, Scenedesmus subspicatus.: 2,2 mg/L (72 h) Method: OECD 201 methyl benzoylformate Daphnia toxicity, EC50, Daphnia magna: 354 mg/L (48 h) Long-term Ecotoxicity 2,2-bis(acryloyloxymethyl)butyl acrylate Fish toxicity, LC50: (96 h)

12.2. Persistence and degradability

2,2-bis(acryloyloxymethyl)butyl acrylate Biodegradation: 82 - 90 % (28 D) Readily biodegradable (according to OECD criteria) Acrylic acid Biodegradation: 81 % (28 D) Method: OECD 301D / EEC 92/69 annex V, C.4-E hexamethylene diacrylate Biodegradation: 80 - 70 % (28 D) Readily biodegradable (according to OECD criteria). Propyldymetrimethanol, ethoxylated, esters with acrylic acid Biodegradation: 58 - 61 % (28 D) Method: OECD 301B / ISO 9439 / EEC 92/69 annex V, C.4-C

12.3. Bioaccumulative potential

2-hydroxy-2-methylpropiophenone Partition coefficient: n-octanol/water: Based on the n-octanol/water partition coefficient accumulation in organisms is not expected. Bioconcentration factor (BCF) Toxicological data are not available.

Based on the n-octanol/water partition coefficient, accumulation in organisms is not expected. Bioconcentration factor (BCF) data are not available.

12.4. Mobility in soil

Toxicological data are not available.

12.5. Results of PBT and vPvB assessment

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

12.6. Other adverse effects

12.6. Other adverse effects
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way.

Disposal

Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way.

Waste Codes

080111 waste paint and varnish containing organic solvents or other dangerous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
not applicable
Transport Class
not applicable
Packing Group
not applicable
ADR

Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8

IMDG

Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8

IATA

Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for UV-topcoat/high-gloss?

The signal word is warning.

What is the physical form of UV-topcoat/high-gloss?

UV-topcoat/high-gloss is a squid with colourless color. It has characteristic odor.

What is UV-topcoat/high-gloss used for?

UV-Locquer

What are the hazard statements for UV-topcoat/high-gloss?

This substance has 7 hazard statements:

  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H412: Harmful to aquatic life with long lasting effects.
  • Water protection
  • Fire
  • Water

What is the melting point of UV-topcoat/high-gloss?

The melting point is not applicable and the boiling point is not determined.