D133232

Consult a physician after significant exposure. If unconscious, place in recovery position and seek medical advice. If breathing has stopped, assist ventilation with a mechanical device. Do not use mouth-to-mouth resuscitation if exposure to hydrogen sulphide is suspected.

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. In case of burns apply cold water until pain subsides then seek medical advice.

Symptoms: Dermatitis

Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists: Get medical advice/ attention.

Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Obtain medical attention.

Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames

High volume water jet

Not classified as flammable or combustible, but will combust if ignited.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Fire-fighters should exercise extreme caution in enclosed spaces due to the possible presence of toxic decomposition and combustion products.

Avoid contact with spilled material. Do not touch or walk through spilled material.

Dyke far ahead of liquid spill for later recovery and disposal.

Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Try to prevent the material from entering drains or water courses.

Recover by pumping or with suitable absorbent. Soak up with inert absorbent material. Clean contaminated floors and objects thoroughly while observing environmental regulations.

Materials: inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust)

Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. This product contains Zinc Dialkyl DithioPhosphate (ZDDP), a thermally sensitive substance. Do not reheat above the maximum loading temperature. Extreme caution must be used in tank gauging or similar operations as overheating could lead to accumulation of lethal concentrations of hydrogen sulphide in the head-space of containers. Warning: If this material is overheated, especially in the presence of water, hydrogen sulphide may be released; this can cause rapid respiratory collapse, coma and death without necessarily any warning odour being sensed. If decomposition is suspected, or if the product has been overheated, do not open the container, discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary precautions to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as evacuation of contaminated areas, and use of suitable respiratory protection.

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. No decomposition if stored and applied as directed.

Smoking, eating and drinking should be prohibited in the application area.

Normal measures for preventive fire protection.

See attached ES. No special requirements under ordinary conditions of use and with adequate ventilation. If decomposition is suspected, or if the product has been overheated, do not open the container, discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary precautions to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as evacuation of contaminated areas, and use of suitable respiratory protection.

Polyvinyl alcohol or nitrile- butyl-rubber gloves Before removing gloves clean them with soap and water. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. When handling hot material, use heat resistant gloves. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Eye wash bottle with pure water. Tightly fitting safety goggles. Ensure that eyewash stations and safety showers are close to the workstation location. The applicable European standard can be found in EN 166.

In the case of vapour formation use a respirator with an approved filter. The applicable European standard can be found in EN 140, EN 137, EN 143, EN 14387.

Impervious clothing. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Long sleeved clothing. The applicable European standard can be found in EN 14605.

See attached ES. Prevent entry into waterways, sewers, basements or confined areas. Local authorities should be advised if significant spillages cannot be contained. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Try to prevent the material from entering drains or water courses. If the product contaminates rivers and lakes or drains inform respective authorities.

Stable under recommended storage conditions.

No dangerous reaction known under conditions of normal use.

No hazards to be specially mentioned.

Excessive heat.

Strong oxidizing agents, water

Hydrogen Sulfide

The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/ container to an approved waste disposal plant.

Dispose of contents/ container to an approved waste disposal plant. Disposal must be in accordance with applicable laws and regulations, and material characteristics at time of disposal.