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Safety Data Sheet EN

R-22

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
R-22
Chemical Name
Chlorodifluoromethane

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Refrigerant Gas

Manufacturers & Suppliers

N

National Refrigerants, Inc.

distributor

661 Kenyon Avenue, Bridgeton, New Jersey 08302

1-800-262-0012

Emergency Contacts

CHEMTREC

1-800-424-9300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Gases under pressure, Liquefied Gas

GHS Pictograms

GHS04 - Compressed gas

GHS04

Hazard Statements

H280 Contains gas under pressure, may explode if heated

Precautionary Statements

P410 + P403 Protect from sunlight, store in a well ventilated place

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Chlorodifluoromethane 75-45-6 100% No

Notes

There are no impurities or stabilizers that contribute to the classification of the material identified in Section 2

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Immediately remove to fresh air. If breathing has stopped, give artificial respiration. Use oxygen as required, provided a qualified operator is available. Get medical attention immediately. DO NOT give epinephrine (adrenaline).

Skin contact

Promptly flush skin with water until all chemical is removed. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. Get medical attention if symptoms persist.

Symptoms: frostbite

Eye contact

Immediately flush eyes with large amounts of water for at least 15 minutes (in case of frostbite, water should be lukewarm, not hot) lifting eyelids occasionally to facilitate irrigation. Get medical attention if symptoms persist.

Ingestion

Ingestion is unlikely because of the physical properties and is not expected to be hazardous. DO NOT induce vomiting unless instructed to do so by a physician.

Immediate Medical Attention

Get medical attention immediately.

Medical Treatment

Treatment of overexposure should be directed at the control of symptoms and the clinical conditions.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use any standard agent – choose the one most appropriate for type of surrounding fire (material itself is not flammable)

Specific hazards

R-22 is not flammable at ambient temperatures and atmospheric pressure. However, this material will become combustible when mixed with air under pressure and exposed to strong ignition sources. Contact with certain reactive metals may result in formation of explosive or exothermic reactions under specific conditions (e.g. very high temperatures and/or appropriate pressures).

Instructions

Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against possible toxic decomposition products. Proper eye and skin protection should be provided.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate unprotected personnel. Product dissipates upon release. Protected personnel should remove ignition sources and shut off leak, if without risk, and provide ventilation. Unprotected personnel should not return to the affected area until air has been tested and determined safe, including low-lying areas.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Always wear recommended personal protective equipment. Avoid breathing vapors and liquid contact with eyes, skin or clothing. Do not puncture or drop cylinders, expose them to open flame or excessive heat. Use authorized cylinders only. Follow standard safety precautions for handling and use of compressed gas cylinders.

Storage

Store in a cool, well-ventilated area of low fire risk and out of direct sunlight. Protect cylinder and its fittings from physical damage. Storage in subsurface locations should be avoided. Close valve tightly after use and when empty.

Hygiene

Always wear recommended personal protective equipment.

Fire prevention

Do not expose to open flame or excessive heat. R-22 should not be mixed with air above atmospheric pressure for leak testing or any other purpose.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide local ventilation at filling zones and areas where leakage is probable. Mechanical (general) ventilation may be adequate for other operating and storage areas.

Hands

General work clothing and gloves (leather) should provide adequate protection. If prolonged contact with liquid or gas is anticipated, insulated gloves constructed of PVA, neoprene or butyl rubber should be used.

Eyes

For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear chemical safety goggles.

Respiratory

None generally required for adequately ventilated work situations. For accidental release or non-ventilated situations, or release into confined space, where the concentration may be above the PEL of 1,000 ppm, use a self-contained, NIOSH approved breathing apparatus or supplied air respirator. For escape: use the former or a NIOSH approved gas mask with organic vapor canister.

Skin/Body

Skin contact with refrigerant may cause frostbite. General work clothing. Where contact with liquid is likely, such as in a spill or leak, impervious boots and clothing should be worn.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

State Under Standard Conditions
---
Upper Explosive Limit
---
Molecular Weight
86.45
Solubility
---
Relative Evaporation Rate
Compared to: CCl₄ = 1
Cloud Point
---
Bulk Density
---
Physical State Data
gas
Voc Content
---
Solidification Point
---
Kinematic Viscosity
---
Flammability
Not applicable
Properties Status
---
Partition Coefficient
Log Pow: 1.08-1.13
Physical State
Gas at ambient temperatures
Flash Point
Not applicable
Colour Intensity
---
Solubility In Water
0.3 wt% @ 25°C and 1 atmosphere
Odor Threshold
Not established
Density
---
Form
liquid and vapor
Boiling Point
-40.8°C (-41.40°F)
Odor
Faint ethereal odor
Lower Explosive Limit
---
Freezing Point
-160°C (-256°F)
Softening Point
---
Ph
Neutral
Relative Density
1.21 g/cm3 at 21.1 C
Vapor Pressure
136.1 psia @ 70°F; 311.4 psia @ 130°F
Auto Ignition Temperature
Not Determined
Explosive Limits
---
Appearance
Clear, colorless liquid and vapor
Dynamic Viscosity
---
Colour
colorless
Evaporation Rate
>1
Melting Point
---
Crystallisation Point
---
Metal Corrosion
---
Vapor Density
3.0
Solubility In Fat
---
Decomposition Temperature
>250 °C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Hazardous reactions

Will not occur

Avoid

Do not mix with oxygen or air above atmospheric pressure. Any source of high temperatures, such as lighted cigarettes, flames, hot spots or welding may yield toxic and/or corrosive decomposition products.

Incompatible

Freshly abraded aluminum surfaces (may cause strong exothermic reaction). Chemically reactive metals: potassium, calcium, powdered aluminum, magnesium, and zinc.

Decomposition

Halogens, halogen acids and possibly carbonyl halides.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1018
Shipping Name
Chlorodifluoromethane or Refrigerant gas R 22
Transport Class
2.2
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for R-22?

The signal word is warning.

What is the physical form of R-22?

R-22 is a gas at ambient temperatures appearing as clear, colorless liquid and vapor with colorless color. It has faint ethereal odor odor.

What is R-22 used for?

Refrigerant Gas

What are the hazard statements for R-22?

This substance has 1 hazard statement:

  • H280: Contains gas under pressure, may explode if heated