Chlorodifluoromethane (R22)

Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Perform cardiopulmonary resuscitation if breathing stopped.

Symptoms: In high concentrations may cause asphyxiation. Symptoms may include loss of mobility/consciousness. Victim may not be aware of asphyxiation.

In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing. Obtain medical assistance.

Immediately flush eyes thoroughly with water for at least 15 minutes.

Ingestion is not considered a potential route of exposure.

Water spray or fog. Product does not burn, use fire control measures appropriate for the surrounding fire.

Do not use water jet to extinguish.

Exposure to fire may cause containers to rupture/explode.

Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat radiation may cause gas receptacles to rupture. Cool endangered receptacles with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems. If possible, stop flow of product. Use water spray or fog to knock down fire fumes if possible. Move containers away from the fire area if this can be done without risk.

Act in accordance with local emergency plan. Try to stop release. Evacuate area. Ensure adequate air ventilation. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. Stay upwind.

Try to stop release.

The product must be handled in accordance with good industrial hygiene and safety procedures. Only experienced and properly instructed persons should handle gases under pressure. Consider pressure relief device(s) in gas installations. Ensure the complete gas system was (or is regularly) checked for leaks before use. Do not smoke while handling product. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Avoid suck back of water, acid and alkalis. Do not breathe gas. Avoid release of product into work area. Refer to supplier's container handling instructions. Do not allow backfeed into the container. Protect containers from physical damage; do not drag, roll, slide or drop. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Leave valve protection caps in place until the container has been secured against either a wall or bench or placed in a container stand and is ready for use. If user experiences any difficulty operating valve discontinue use and contact supplier. Never attempt to repair or modify container valves or safety relief devices. Damaged valves should be reported immediately to the supplier. Keep container valve outlets clean and free from contaminants particularly oil and water. Replace valve outlet caps or plugs and container caps where supplied as soon as container is disconnected from equipment. Close container valve after each use and when empty, even if still connected to equipment. Never attempt to transfer gases from one cylinder/container to another. Never use direct flame or electrical heating devices to raise the pressure of a container. Do not remove or deface labels provided by the supplier for the identification of the content of the container. Suck back of water into the container must be prevented. Open valve slowly to avoid pressure shock.

Observe all regulations and local requirements regarding storage of containers. Containers should not be stored in conditions likely to encourage corrosion. Container valve guards or caps should be in place. Containers should be stored in the vertical position and properly secured to prevent them from falling over. Stored containers should be periodically checked for general condition and leakage. Keep container below 50°C in a well ventilated place. Store containers in location free from fire risk and away from sources of heat and ignition. Keep away from combustible materials.

The product must be handled in accordance with good industrial hygiene and safety procedures. Do not smoke while handling product.

Store containers in location free from fire risk and away from sources of heat and ignition. Do not smoke while handling product.

Provide adequate general and local exhaust ventilation. Product to be handled in a closed system. Systems under pressure should be regularly checked for leakages. Ensure exposure is below occupational exposure limits (where available). Oxygen detectors should be used when asphyxiating gases may be released. Consider the use of a work permit system e.g. for maintenance activities.

Wear working gloves when handling gas containers. Standard EN 388 - Protective gloves against mechanical risk, performance level 1 or higher. Wear cold insulating gloves when transfilling or breaking transfer connections. Standard EN 511 - Cold insulating gloves.

Wear goggles when transfilling or breaking transfer connections. Standard EN 166 - Personal eye-protection - specifications.

Standard EN 137 - Self-contained open-circuit compressed air breathing apparatus with full face mask. Self contained breathing apparatus (SCBA) or positive pressure airline with mask are to be used in oxygen-deficient atmospheres. Self contained breathing apparatus is recommended, where unknown exposure may be expected, e.g. during maintenance activities on installation systems.

Wear safety shoes while handling containers. Standard EN ISO 20345 - Personal protective equipment - Safety footwear.

Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for specific methods for waste gas treatment.

Stable under normal conditions.

No reactivity hazard other than the effects described in sub-sections below.

None.

Avoid moisture in installation systems.

May react violently with alkalis. For additional information on compatibility refer to ISO 11114.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.