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Safety Data Sheet EN

Bouin's Solution

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Bouin's Solution
Product Form
Dispenser Pack
Product Code
AR166, AR167, AR173

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory use

Manufacturers & Suppliers

Agilent Technologies, Inc. logo

Agilent Technologies, Inc.

manufacturer

5301 Stevens Creek Blvd, Santa Clara, CA 95051, USA

+1 800 227 9770

http://www.Agilent.com

A

Agilent Technologies Singapore (International) Pte Ltd.

distributor

No. 1 Yishun Avenue 7, Singapore, 768923

(65) 6276 2622

A

Agilent Technologies LDA UK Ltd.

distributor

5500 Lakeside Cheadle Royal Business Park, Cheadle, Cheshire, SK8 3GR, United Kingdom

+44 (0) 345 712 5292

Emergency Contacts

CHEMTREC®

+(44)-870-8200418

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Acute Tox. Cat. 4 H332
Skin Corr. Cat. 1 H314
Skin Sens. Cat. 1 H317
Muta. Cat. 2 H341
Carc. Cat. 1B H350
STOT SE Cat. 3 H335

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.

Precautionary Statements

P201 Obtain special instructions before use.
P280 Wear protective gloves, protective clothing and eye or face protection.
P308 + P313 IF exposed or concerned: Get medical advice or attention.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.
IF INHALED: Immediately call a POISON CENTER or doctor.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Formaldehyde, solution EC: 200-001-8 50-00-0 10 - 25% Yes
acetic acid EC: 200-580-7 64-19-7 5% Yes
2,4,6-trinitrophenol EC: 201-865-9 88-89-1 0.98% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Harmful if inhaled. May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing.

Skin contact

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: Causes severe burns. Harmful in contact with skin. May cause an allergic skin reaction. Adverse symptoms may include the following: pain or irritation, redness, blistering may occur.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.

Symptoms: Causes serious eye damage. Adverse symptoms may include the following: pain, watering, redness.

Ingestion

Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Severely corrosive to the digestive tract. Causes severe burns. Harmful if swallowed. Adverse symptoms may include the following: stomach pains.

Immediate Medical Attention

Get medical attention immediately. Call a poison center or physician. Chemical burns must be treated promptly by a physician.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

None known.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Stop leak if without risk. Move containers from spill area. Dispose of via a licensed waste disposal contractor.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from alkalis. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Separate from alkalis. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Yellow.
Colour Intensity
---
Form
---
Odor
Formaldehyde. / Vinegar-like
Odor Threshold
Not available.
Ph
1.2 to 1.6
Melting Point
Not available.
Boiling Point
Not available.
Flash Point
Closed cup: 39 °C (acetic acid); Closed cup: 83 °C (Formaldehyde, solution)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
23.8 mm Hg (at 20°C) (Water); 3.2 kPa (at 20°C) (Water); 92.258 mm Hg (at 50°C) (Water); 12.3 kPa (at 50°C) (Water); 15.59 mm Hg (at 20°C) (acetic acid); 2.1 kPa (at 20°C) (acetic acid)
Vapor Density
Not available.
Relative Density
Not available.
Bulk Density
---
Density
---
Flammability
Not applicable.
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
300 °C (2,4,6-trinitrophenol); 430 °C (Formaldehyde, solution)
Decomposition Temperature
Not available.
Solubility
Soluble in the following materials: cold water and hot water.
Partition Coefficient
Not applicable.
Solubility In Water
Yes.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

No specific data.

Incompatible

Attacks many metals producing extremely flammable hydrogen gas which can form explosive mixtures with air. Reactive or incompatible with the following materials: alkalis

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1760
Shipping Name
CORROSIVE LIQUID, N.O.S. (Formaldehyde, solution, acetic acid)
Transport Class
8
Packing Group
II
IMDG

274

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Bouin's Solution?

The signal word is danger.

What is the physical form of Bouin's Solution?

Bouin's Solution is a liquid. with yellow. color. It has formaldehyde. / vinegar-like odor.

What is the solubility of Bouin's Solution?

Soluble in the following materials: cold water and hot water.

What is Bouin's Solution used for?

Laboratory use

What are the hazard statements for Bouin's Solution?

This substance has 6 hazard statements:

  • H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H335: May cause respiratory irritation.
  • H341: Suspected of causing genetic defects.
  • H350: May cause cancer.

What is the melting point of Bouin's Solution?

The melting point is Not available. and the boiling point is Not available..