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Safety Data Sheet EN

Methyl 4-hydroxybenzoate EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF

CAS 99-76-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methyl 4-hydroxybenzoate EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF
Product Code
1.06757
Chemical Name
Methyl 4-hydroxybenzoate

Regulatory Identifiers

CAS Number
99-76-3 Check regulations →
REACH No.
01-2119463264-40-XXXX

Identified Uses

Pharmaceutical production and analysis

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

Frankfurter Str. 250, D-64271 DARMSTADT

+49 (0)6151 72-0

Emergency Contacts

CHEMTREC (GB)

+(44)-870-8200418

CHEMTREC Ireland

+(353)-19014670

CHEMTREC India

001-803-017-9114

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS09 - Environmental hazard

GHS09

Hazard Statements

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P391 Collect spillage.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
methyl 4-hydroxybenzoate EC: 202-785-7 99-76-3 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Eye contact

After eye contact: rinse out with plenty of water. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most).

Immediate Medical Attention

Consult doctor if feeling unwell.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides. Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up dry. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

Tightly closed. Dry. Recommended storage temperature see product label.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested: KCL 741 Dermatril® L. Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested: KCL 741 Dermatril® L

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P1. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
white
Colour Intensity
---
Form
---
Odor
odorless
Odor Threshold
---
Ph
5,72 at 1,88 g/l at 20 °C
Melting Point
125 °C - OECD Test Guideline 102
Boiling Point
Decomposes below the boiling point.
Flash Point
168 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
< 1 hPa at 20 °C
Vapor Density
---
Relative Density
---
Bulk Density
ca.300 - 400 kg/m³
Density
1,38 g/cm³ at 20 °C - OECD Test Guideline 109
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
> 403 °C - Relative self-ignition temperature for solids
Decomposition Temperature
270 - 280 °C
Solubility
---
Partition Coefficient
Pow: 95,5; log Pow: 1,98 at 22 °C - Bioaccumulation is not expected.
Solubility In Water
1,88 g/l at 20 °C - OECD Test Guideline 105
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

Violent reactions possible with: Bases, Strong oxidizing agents

Avoid

Strong heating.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3077
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (methyl 4-hydroxybenzoate)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Methyl 4-hydroxybenzoate EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF?

The signal word is no signal word.

What is the physical form of Methyl 4-hydroxybenzoate EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF?

Methyl 4-hydroxybenzoate EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF is a solid with white color. It has odorless odor.

What is Methyl 4-hydroxybenzoate EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF used for?

Pharmaceutical production and analysis

What are the hazard statements for Methyl 4-hydroxybenzoate EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF?

This substance has 1 hazard statement:

  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Methyl 4-hydroxybenzoate EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF?

The melting point is 125 °C - OECD Test Guideline 102 and the boiling point is Decomposes below the boiling point..