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Safety Data Sheet EN

Methyl 4-hydroxybenzoate

CAS 99-76-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methyl 4-hydroxybenzoate
Product Code
AC126960000; AC126960025; AC126960100; AC126961000; AC126965000
Synonyms
Methylparaben

Regulatory Identifiers

CAS Number
99-76-3 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

A

Acros Organics

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

Emergency Contacts

Emergency Number US

001-201-796-7100

Europe

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

GHS09 - Environmental hazard

GHS09

Hazard Statements

H411 Toxic to aquatic life with long lasting effects

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Methyl p-hydroxybenzoate 99-76-3 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

Do NOT induce vomiting.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable media

No information available

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition.

Instructions

Keep product and empty container away from heat and sources of ignition.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not flush into surface water or sanitary sewer system.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid dust formation. Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.

Hands

Wear appropriate protective gloves and clothing to prevent skin exposure.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Colour
---
Freezing Point
---
Vapor Pressure
0.000005 mbar @ 20 °C
Physical State Data
solid
State Under Standard Conditions
---
Colour Intensity
---
Vapor Density
Not applicable
Auto Ignition Temperature
600 °C / 1112 °F
Kinematic Viscosity
---
Partition Coefficient
No data available
Explosive Limits
---
Melting Point
125 - 128 °C / 257 - 262.4 °F
Molecular Weight
152.15
Solubility
0.25% (25 C) Slightly soluble in water
Odor Threshold
No information available
Dynamic Viscosity
---
Lower Explosive Limit
No data available
Ph
5.8 (@ 20) 2.5g/L (20°C)
Appearance
White
Flammability
No information available
Boiling Point
298.6 °C / 569.5 °F @ 760 mmHg
Physical State
Powder Solid
Properties Status
---
Solubility In Water
---
Crystallisation Point
---
Voc Content
---
Upper Explosive Limit
No data available
Softening Point
---
Odor
Odorless
Decomposition Temperature
>270°C
Solubility In Fat
---
Relative Evaporation Rate
---
Relative Density
---
Metal Corrosion
---
Evaporation Rate
Not applicable
Bulk Density
---
Density
---
Solidification Point
---
Cloud Point
---
Flash Point
No information available
Form
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous Polymerization: No information available.

Avoid

Avoid dust formation. Incompatible products. Excess heat.

Incompatible

Strong oxidizing agents, Strong bases

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3077
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Methyl 4-hydroxybenzoate known by?

Methyl 4-hydroxybenzoate is also known as: Methylparaben

What is the hazard signal word for Methyl 4-hydroxybenzoate?

The signal word is no signal word.

What is the physical form of Methyl 4-hydroxybenzoate?

Methyl 4-hydroxybenzoate is a powder solid appearing as white . It has odorless odor.

What is the solubility of Methyl 4-hydroxybenzoate?

0.25% (25 C) Slightly soluble in water

What is Methyl 4-hydroxybenzoate used for?

Laboratory chemicals.

What are the hazard statements for Methyl 4-hydroxybenzoate?

This substance has 1 hazard statement:

  • H411: Toxic to aquatic life with long lasting effects

What is the melting point of Methyl 4-hydroxybenzoate?

The melting point is 125 - 128 °C / 257 - 262.4 °F and the boiling point is 298.6 °C / 569.5 °F @ 760 mmHg.