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Safety Data Sheet EN

Sulfuric acid 96% Ultrapur

CAS 7664-93-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Sulfuric acid 96% Ultrapur
Product Code
1.01516
Chemical Name
Sulfuric acid

Regulatory Identifiers

CAS Number
7664-93-9 Check regulations →
REACH No.
01-2119458838-20-XXXX

Identified Uses

Reagent for analysis

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

Frankfurter Str. 250, D-64271 DARMSTADT

+49 (0)6151 72-0

Emergency Contacts

CHEMTREC (GB)

+(44)-870-8200418

CHEMTREC Ireland

+(353)-19014670

CHEMTREC India

001-803-017-9114

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P234 Keep only in original packaging.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
sulphuric acid EC: 231-639-5 7664-93-9 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Fresh air. Call in physician.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

Rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

Make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Call in physician/ophthalmologist immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Not combustible. Ambient fire may liberate hazardous vapours.

Instructions

Suppress (knock down) gases/vapors/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up with liquid-absorbent and neutralising material. Dispose of properly. Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H ⁺ , Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

Recommended storage temperature see product label.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 120 min Material tested:Butoject® (KCL 898). This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type ABEK. The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colorless
Colour Intensity
---
Form
---
Odor
odorless
Odor Threshold
---
Ph
0,3 at 49 g/l at 25 °C
Melting Point
-20 °C
Boiling Point
No data available
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
ca.0,0001 hPa at 20 °C
Vapor Density
---
Relative Density
No data available
Bulk Density
Not applicable
Density
1,84 g/cm3 at 20 °C
Flammability
No data available
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
at 20 °C soluble, (caution ! development of heat)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
ca.24 mPa.s at 20 °C
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature) .

Reactivity

has a corrosive effect, strong oxidising agent

Hazardous reactions

A risk of explosion and/or of toxic gas formation exists with the following substances: Alkali metals alkali compounds Ammonia Aldehydes acetonitrile Alkaline earth metals alkalines Acids alkaline earth compounds Metals metal alloys Oxides of phosphorus phosphorus hydrides halogen-halogen compounds oxyhalogenic compounds permanganates nitrates Carbides combustible substances organic solvent acetylidene Nitriles organic nitro compounds anilines Peroxides picrates nitrides lithium silicide iron(III) compounds bromates chlorates Amines perchlorates hydrogen peroxide

Avoid

no information available

Incompatible

animal/vegetable tissues, Metals. Contact with metals liberates hydrogen gas.

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1830
Shipping Name
SULPHURIC ACID
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Sulfuric acid 96% Ultrapur?

The signal word is danger.

What is the physical form of Sulfuric acid 96% Ultrapur?

Sulfuric acid 96% Ultrapur is a liquid with colorless color. It has odorless odor.

What is Sulfuric acid 96% Ultrapur used for?

Reagent for analysis

What are the hazard statements for Sulfuric acid 96% Ultrapur?

This substance has 2 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of Sulfuric acid 96% Ultrapur?

The melting point is -20 °C and the boiling point is No data available.