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Safety Data Sheet EN

LOCTITE VN 3262 DR-S 200KG

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE VN 3262 DR-S 200KG
Product Code
2947512

Regulatory Identifiers

CAS Number
N/A

Identified Uses

1-component-polyurethane adhesive

Uses advised against

None identified

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way, Rocky Hill, Connecticut 06067

+1 (860) 571-5100

www.henkelna.com

Emergency Contacts

Poison Control Center

1-877-671-4608

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
Resp. Sens. Cat. 1
Skin Sens. Cat. 1
STOT SE Cat. 3
STOT RE Cat. 1

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 CAUSES SKIN IRRITATION.
H317 MAY CAUSE AN ALLERGIC SKIN REACTION.
H319 CAUSES SERIOUS EYE IRRITATION.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335 MAY CAUSE RESPIRATORY IRRITATION.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

Precautionary Statements

P233 Keep container tightly closed.
P261 Do not breathe vapors, mist, or spray.
P264 Wash affected area thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves, eye protection, and face protection.
P285 In case of inadequate ventilation wear respiratory protection.
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or physician if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P342 + P311 If experiencing respiratory symptoms: Call a poison center or physician.
P352 IF ON SKIN: Wash with plenty of water.
P362 Take off contaminated clothing.
P403 Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Glycerol polyethylene-polypropylene glycol ether (1:3) polymer with polymethylene polyphenylene isocyanate and polypropylene glycol 84563-02-0 30 - 60% Yes
Diphenylmethane diisocyanate, isomers and homologs 9016-87-9 30 - 60% Yes
Methylenebis(phenylisocyanate) 101-68-8 10 - 30% Yes

Notes

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If not breathing, give artificial respiration. If breathing is difficult, oxygen should be administered by qualified personnel. Move to fresh air. If symptoms persist, seek medical advice.

Symptoms: Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Extreme asthmatic reactions can be life threatening.

Skin contact

Remove contaminated clothing and shoes. Rinse with running water and soap. Seek medical attention immediately. Wash contaminated clothing before reuse. Thoroughly clean shoes before reuse.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical attention immediately.

Symptoms: Corneal injury, corneal epithelial edema impairing vision.

Ingestion

If material is ingested, immediately contact a physician or poison control center. Keep individual calm. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Seek medical attention immediately.

Immediate Medical Attention

Seek medical attention immediately.

Medical Treatment

Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Treat symptomatically as for contact dermatitis or thermal burns. Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray (fog), foam, dry chemical or carbon dioxide.

Specific hazards

At higher temperatures isocyanate may be released. The product may undergo spontaneous polymerization at high temperatures. Polymerization is exothermic and may cause damage to the container and/or release of thermal decomposition products. Sealed containers at elevated temperatures or contaminated with water may rupture explosively.

Instructions

In case of fire, keep containers cool with water spray.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Refer to Section 8 'Exposure Controls / Personal Protection' prior to clean up. Remove all sources of ignition.

Small spill

For minor spills, absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well ventilated area (outside) and treat with neutralizing solution: mixture of 80% water and 20% non-ionic surfactant Tergitol TMN-10; or 90% water, 3-8% concentrated ammonia and 2% detergent. Allow to stand uncovered for 48 hours to let carbon dioxide escape.

Large spill

Large quantities may be pumped into closed, but not sealed containers for disposal.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well ventilated area (outside) and treat with neutralizing solution

Materials: sawdust or other absorbent

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wear suitable protective clothing, safety glasses and gloves. Keep container closed.

Storage

Do not let moisture contaminate this material. Product reacts with water to release carbon dioxide, which could build up pressure in closed containers and lead to bursting. Do not reseal if moisture contamination is suspected. Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials.

Hygiene

Wash thoroughly after handling.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility In Water
Not miscible. Reacts slowly with water to liberate carbon dioxide gas.
Colour
beige
Density
---
Colour Intensity
---
Solubility
---
Evaporation Rate
Not available.
Dynamic Viscosity
18,000 - 30,000 cp
Decomposition Temperature
Not available.
Vapor Density
> 1
Lower Explosive Limit
Not available.
Odor Threshold
Not available.
State Under Standard Conditions
---
Relative Density
1.146 - 1.176 Freq 001
Explosive Limits
---
Melting Point
Not applicable, Product is a liquid
Molecular Weight
---
Appearance
---
Solubility In Fat
---
Auto Ignition Temperature
Not available.
Partition Coefficient
Not available.
Crystallisation Point
---
Ph
Not applicable, Product is non-soluble (in water).
Bulk Density
---
Metal Corrosion
---
Flash Point
> 180 °C (> 356°F) ASTM D 93-96 Flash point
Cloud Point
---
Upper Explosive Limit
Not available.
Boiling Point
Not applicable, Decomposes before boiling point is reached
Relative Evaporation Rate
---
Properties Status
---
Form
---
Odor
odourless
Physical State Data
liquid
Solidification Point
---
Freezing Point
---
Physical State
liquid
Kinematic Viscosity
---
Voc Content
Not available.
Flammability
Not applicable
Vapor Pressure
< 0.00001 hPa (20 °C (68°F)) < 0.0005 hPa (50 °C (122°F))
Softening Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of storage and use.

Reactivity

Not available.

Hazardous reactions

Exothermic. Polymerization may occur at elevated temperature or in the presence of incompatible materials.

Avoid

Avoid moisture. Container can be pressurised by carbon dioxide due to reaction with humid air and/or water. Extremes of temperature and direct sunlight. Contamination with water. Keep away from heat, ignition sources and incompatible materials.

Incompatible

Water. Alcohols. Amines. Moisture. Strong acids and strong bases.

Decomposition

Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Hydrogen cyanide. Isocyanate vapors

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
RQ, Environmentally hazardous substance, liquid, n.o.s.
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LOCTITE VN 3262 DR-S 200KG?

The signal word is danger.

What is the physical form of LOCTITE VN 3262 DR-S 200KG?

LOCTITE VN 3262 DR-S 200KG is a liquid with beige color. It has odourless odor.

What is LOCTITE VN 3262 DR-S 200KG used for?

1-component-polyurethane adhesive

What are the hazard statements for LOCTITE VN 3262 DR-S 200KG?

This substance has 6 hazard statements:

  • H315: CAUSES SKIN IRRITATION.
  • H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
  • H319: CAUSES SERIOUS EYE IRRITATION.
  • H334: MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
  • H335: MAY CAUSE RESPIRATORY IRRITATION.
  • H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

What is the melting point of LOCTITE VN 3262 DR-S 200KG?

The melting point is Not applicable, Product is a liquid and the boiling point is Not applicable, Decomposes before boiling point is reached.