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Safety Data Sheet EN

White Portland cement Type I-II

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
White Portland cement Type I-II
Synonyms
Portland cement, Hydraulic Cement

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Cement Mixes, Mortars, Concrete

Manufacturers & Suppliers

R

ROYAL WHITE CEMENT, INC.

manufacturer

8316 East Freeway Houston, TX 77029, USA

713-676-0000

Emergency Contacts

Emergency Contact

832-452-4500

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Corr. Cat. 1A
Eye Dam. Cat. 1
Skin Sens. Cat. 1
Carc. Cat. 1A
STOT SE Cat. 3

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H314 Exposure may cause skin drying, dermal irritation, severe burns, respiratory sensitivity, internal discomfort if swallowed, eye burns, inflammation of the cornea and it may contain elements known to cause cancer.

Precautionary Statements

P102 Keep out of the reach of children.
P261 Exposure to dust may cause immediate or delayed irritation or inflammation.
P264 Wash hands thoroughly after handling.
P264 Drying, thickening, and cracking of the skin and nails may also occur.
P271 Use only outdoors or in a well ventilated area, avoid breathing dust.
P280 Wear eye, face protection and protective gloves at all times.
P280 Long term exposure to wet or dry cement may cause chemical burns.
P301 + P310 Do not ingest Masonry cement.
P301 + P310 Ingestion of large quantities may cause severe irritation and chemical burns of the mouth, throat, stomach and digestive tract.
P301 + P312 IF INGESTED: Irritating to mouth, throat and stomach.
P302 + P352 IF ON SKIN: Wash with plenty soap and water.
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 Eye contact by larger amount of dry power or splashes of wet Masonry cement may cause effects ranging from moderate eye irritation to chemical burns or blindness.
P310 Immediately call a POISON CENTER or physician.
P311 Call a POISON CENTER or physician.
P315 Get immediate medical attention.
P333 + P313 If skin irritation or rash occurs: get medical attention.
P333 + P313 Symptoms of allergic reactions may include reddening of the skin, rash, and irritation.
P338 Remove contact lenses, if present and easy to do.
P338 Continue rinsing.
P351 IF IN EYES: Rinse cautiously with water for several minutes.
P362 Take off contaminated clothing.
P403 + P233 Keep containers tightly close in a dry and well ventilated area.
P501 Dispose of content and container according with all local, state and federal regulations

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Cement, portland, chemicals 6597-15-1 100% Yes
Calcium oxide 1305-78-8 5% Yes
Quartz 14808-60-7 3% Yes
Hexavalent Chromium 18450-29-9 --- No
Gypsum 7778-18-9 2 - 10% No
Magnesium oxide 1309-48-4 4% No
Limestone 1317-65-3 5% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air and support breathing as needed. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Consult a physician immediately if irritation persists. Inhalation of large amounts of Portland cement requires immediate medical attention.

Symptoms: Irritation to the moist mucous, membranes of the nose, throat and upper respiratory system, and may cause certain lung disease.

Skin contact

Immediately wash affected areas with neutral soap and clean, cool water for at least 15 minutes. For reddened or blistered skin, consult a physician immediately.

Symptoms: When in contact with moisture on skin, Portland cement becomes highly caustic and will damage or burn the skin.

Eye contact

Immediately thoroughly flush eyes with clean water. Continue flushing eyes for at least 15 minutes, including under lids to remove all particles. Consult a physician immediately. Remove contact lenses.

Symptoms: When in contact with moisture in eyes, Portland cement becomes highly caustic and will damage or burn the eyes.

Ingestion

If the material is ingested, have the conscious person drink plenty of water or milk. Never give anything by mouth to an unconscious or convulsing person. DO NOT INDUCE VOMITING. Consult a physician immediately.

Symptoms: May cause burns to mouth, throat and stomach. Adverse symptoms may include the following: stomach pains

Immediate Medical Attention

Consult a physician immediately for eyes, skin, inhalation, or ingestion.

Medical Treatment

Treat symptomatically. Specific treatments: Not applicable.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

Do not use water jet or water-based fire extinguishers.

Specific hazards

No specific fire or explosion hazard.

Instructions

Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use dry clean-up methods that do not disperse dust into the air or entry into surface water. Place in an appropriate container for disposal or use. Avoid inhalation of dust and contact with skin and eyes. Scrape up wet material and place in an appropriate container. Allow the material to “dry” before disposal.

Environmental

do not disperse dust into the air or entry into surface water.

Cleanup methods

Use dry clean-up methods that do not disperse dust into the air. Scrape up wet material and place in an appropriate container.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep dry until used. Handle and store in a manner so that airborne dust does not exceed applicable exposure limits. Use exposure control and personal protection methods as described in Section 8. Keep out of reach of children.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use adequate ventilation to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits.

Hands

Wear suitable gloves

Eyes

Wear safety glasses with side shields or goggles to avoid contact with the eyes. In extremely dusty environments and unpredictable environments, wear tight-fitting unvented or indirectly vented goggles to avoid eye irritation or injury. Contact lenses should not be worn when handling cement or cement containing products.

Respiratory

A NIOSH approved dust mas or filtering face piece is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirators should be selected and used under the direction of a trained health and safety professional following requirements found in OSHA’s respirator standard (29 CFR 1910.134) and ANSI’s standard for respiratory protection (Z88.2)

Skin/Body

Wear impervious abrasion- and alkali-resistant gloves, boots, long-sleeved shirt, long pants or other protective clothing to prevent skin contact. Promptly remove clothing dusty with dry Portland cement or clothing dampened with moisture mixed with Portland cement, and launder before re-use. If contact occurs, wash areas contacted by material with pH neutral soap and water.

Environmental

Maintain levels below Community environmental protection thresholds.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Gray, White and colored powder
Colour
---
Colour Intensity
---
Form
powder
Odor
No distinct odor
Odor Threshold
---
Ph
12 to 13
Melting Point
Not applicable
Boiling Point
Not applicable (i.e. > 1000_C)
Flash Point
---
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable
Vapor Pressure
Not applicable
Vapor Density
Not applicable
Relative Density
2.9 – 3.1
Bulk Density
---
Density
(H20 = 1.0) 3.15
Flammability
---
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Slightly soluble (0.1 to 1.0%)
Solubility In Fat
---
Molecular Weight
---
Voc Content
Not applicable
Metal Corrosion
---
Dynamic Viscosity
Not applicable
Kinematic Viscosity
Not applicable
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Product is stable.

Reactivity

No dangerous reactions known under normal use. Reacts slowly with water forming hydrate compounds, releasing heat and producing a strong alkali solution until the reactions is substantially complete.

Hazardous reactions

No dangerous reactions known under normal use. Do not mix with or expose to other chemicals.

Avoid

Keep dry

Incompatible

oxidizing materials, acids, aluminum, ammonium salt, aluminum powder, alkali and alkaline earth elements, limestone, alum, magnesium, fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, oxygen difluoride, hydrofluoric acid

Decomposition

Toxic gases or vapors, hydrogen gas, silicon tetrafluoride

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

## Toxicity **Ecology – General:** No recognized unusual toxicity to plants or animals. Do not flush to sewer or allow to enter waterways

No recognized unusual toxicity to plants or animals.

Persistency and degradability

There are no data available

There are no data available

Bioaccumulative potential

There are no data available

There are no data available

Mobility in soil

There are no data available

Other adverse effect

There are no data available

There are no data available regarding other adverse effects.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Comply with all applicable local, state and federal regulations for disposal of unusable or contaminated materials.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Portland cement is considered a hazardous chemical under the US OSHA Hazard Communication Rule 29 CFR 1910.1200.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is White Portland cement Type I-II known by?

White Portland cement Type I-II is also known as: Portland cement, Hydraulic Cement

What is the hazard signal word for White Portland cement Type I-II?

The signal word is danger.

What is the physical form of White Portland cement Type I-II?

White Portland cement Type I-II is a solid appearing as gray, white and colored powder . It has no distinct odor odor.

What is White Portland cement Type I-II used for?

Cement Mixes, Mortars, Concrete

What are the hazard statements for White Portland cement Type I-II?

This substance has 1 hazard statement:

  • H314: Exposure may cause skin drying, dermal irritation, severe burns, respiratory sensitivity, internal discomfort if swallowed, eye burns, inflammation of the cornea and it may contain elements known to cause cancer.

What is the melting point of White Portland cement Type I-II?

The melting point is Not applicable and the boiling point is Not applicable (i.e. > 1000_C).