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Safety Data Sheet EN

Cement

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Cement
Product Form
bagged cement or bulk cement

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Cements are used in industrial installations to manufacture/formulate hydraulic binders for building and construction work, such as ready-mixed concrete, mortars, renders, grouts, plasters as well as precast concrete. Common cements and cement containing mixtures (hydraulic binders) are used industrially, by professionals as well as by consumers in building and construction work, indoor and outdoor.

Uses advised against

Any uses not mentioned above, are advised against..

Manufacturers & Suppliers

Heidelberg Materials Benelux SA logo

Heidelberg Materials Benelux SA

manufacturer

Boulevard de France 3-5, 1420 Braine L'Alleud

+32 (0)2 678 32 11

https://www.heidelbergmaterials.com/en/benelux

Emergency Contacts

Europe

112

Anti-Poison Center

+ 32 (0)70 245 245

24h/24, available outside office hours

FR, NL, EN

Centre Antipoison de Nancy

+ 33 3 83 85 21 92

24h/24, available outside office hours

FR

BfR Bundesinstitut für Risikobewertung

+49 30 18412 0

24h/24, available outside office hours

DE

Luxembourg

070 245 245

24h/24

Luxembourg

02 264 96 30

Luxembourg

8002-5500

24/24

Ministère-Direction de la Santé

+352 24785551

FR

Dutch Poisons Center

+31 88 75 585 61

24h/24, available outside office hours

NL

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation
H317 skin sensitizing
H318 Causes serious eye damage
H335 May cause respiratory irritation

Precautionary Statements

P102 Keep out of reach of children.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 + P310 IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
P501 Dispose of contents/container to a collecting parc according to the local regulation.
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/ attention.
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Tricalcium silicate EC: 235-336-9 12168-85-3 85% No
Dicalcium silicate EC: 233-107-8 10034-77-2 85% No
Tetracalcium aluminoferrite EC: 235-094-4 12068-35-8 30% No
Tricalcium aluminate EC: 234-932-6 12042-78-3 20% No
Calcium oxide (free lime) EC: 215-138-9 1305-78-8 10% No
Portland cement clinker EC: 266-043-4 65997-15-1 5 - 100% Yes
Flue dust from production of Portland cement clinker EC: 270-659-9 68475-76-3 5% Yes

Notes

No application. Cement is a mixture and not a substance.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move the person to fresh air. Dust in throat and nasal passages should clear spontaneously. Contact a physician if irritation persists or later develops or if discomfort, coughing or other symptoms persist.

Symptoms: Dust in throat and nasal passages. Repeated inhalation of dust of Common cements over a long period of time increases the risk of developing lung diseases.

Skin contact

For dry cement, remove and rinse abundantly with water. For wet cement, wash skin with plenty of water. Remove contaminated clothing, footwear, watches, etc. and clean thoroughly before re-using them. Seek medical treatment in all cases of irritation or burns.

Symptoms: Irritating effect on moist skin (due to sweat or humidity) after prolonged contact or may cause contact dermatitis after repeated contact. Prolonged skin contact with wet cement or wet concrete may cause serious burns because they develop without pain being felt.

Eye contact

Do not rub eyes in order to avoid possible cornea damage as a result of mechanical stress. Remove contact lenses if any. Incline head to injured eye, open the eyelid(s) widely and flush eye(s) immediately by thoroughly rinsing with plenty of clean water for at least 20 minutes to remove all particles. Avoid flushing particles into uninjured eye. If possible, use isotonic water (0.9% NaCl). Contact a specialist of occupational medicine or an eye specialist.

Symptoms: Serious and potentially irreversible injuries.

Ingestion

Do not induce vomiting. If the person is conscious, wash out mouth with water and give plenty of water to drink. Get immediate medical attention or contact the anti poison centre.

Immediate Medical Attention

Get immediate medical attention or contact the anti poison centre (for ingestion). Seek medical treatment in all cases of irritation or burns (for skin).

Medical Treatment

Contact a specialist of occupational medicine or an eye specialist (for eyes). Seek medical treatment in all cases of irritation or burns (for skin).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Common cements are not flammable.

Specific hazards

Cements are non-combustible and non-explosive and will not facilitate or sustain the combustion of other materials.

Instructions

Cement poses no fire-related hazards.

Firefighter Protection

No need for special protective equipment for fire-fighters.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Emergency procedures are not required.

Environmental

Do not wash cement down sewage and drainage systems or into bodies of water (e.g. streams).

Cleanup methods

Collect the spillage in a dry state if possible. Use cleanup methods such as vacuum clean-up or vacuum extraction. Alternatively, wipe-up the dust by mopping, wet brushing or by using water sprays or hoses and remove slurry. If not possible, remove by slurrying with water. Clean up wet cement and place in a container.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Follow the recommendations as given under Section 8. Do not sweep. Use dry cleanup methods such as vacuum clean-up or vacuum extraction, which do not cause airborne dispersion.

Storage

Bulk cement should be stored in silos that are waterproof, dry, clean and protected from contamination. Packed products should be stored in unopened bags clear of the ground in cool, dry conditions and protected from excessive draught.

Hygiene

Do not handle or store near food and beverages or smoking materials.

Fire prevention

Not applicable.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Measures to reduce generation of dust and to avoid dust propagating in the environment such as dedusting, exhaust ventilation and dry clean-up methods which do not cause airborne dispersion.

Hands

Use watertight, wear, and alkali resistant protective gloves (e.g. nitrile soaked cotton gloves with CE marking) internally lined with cotton. Layer thickness of c. 0.15 mm. Provide sufficient protection over a period of 480 minutes. Always change damaged or soaked gloves immediately. Always have spare gloves in ready supply.

Eyes

Wear approved glasses or safety goggles according to EN 166 when handling dry or wet cement to prevent contact with eyes.

Respiratory

When a person is potentially exposed to dust levels above exposure limits, use appropriate respiratory protection. The type of respiratory protection should be adapted to the dust level and conform to the relevant EN standard, (e.g. EN 149) or national standard.

Skin/Body

Use boots, closed long-sleeved protective clothing as well as skin care products (e.g. barrier creams) to protect the skin from prolonged contact with wet cement. Particular care should be taken to ensure that wet cement does not enter the boots. In some circumstances, such as when laying concrete or screed, waterproof trousers or kneepads are necessary.

Environmental

Environmental exposure control for the emission of cement particles into air has to be in accordance with the available technology and regulations for the emission of general dust particles. Water: Do not wash cement into sewage systems or into bodies of water, to avoid high pH. Above pH 9 negative ecotoxicological impacts are possible. Soil and terrestrial environment: No special emission control measures are necessary for the exposure to the terrestrial environment.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
dry cement is a finely ground inorganic material
Physical State Data
solid
State Under Standard Conditions
---
Appearance
powder
Colour
white or grey
Colour Intensity
---
Form
powder
Odor
odourless
Odor Threshold
---
Ph
11-13,5
Melting Point
> 1250 °C
Boiling Point
not applicable
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
not applicable
Vapor Density
Not applicable
Relative Density
2.75-3.20 g/cm³
Bulk Density
0.9-1.5 g/cm³
Density
---
Flammability
Not applicable, material is a solid and not flammable, cannot ignite by friction
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
Not applicable
Solubility
---
Partition Coefficient
Not applicable
Solubility In Water
Weak (0.1-1.5 g/l)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Dry cements are stable as long as they are properly stored (see Section 7) and compatible with most other building materials. They should be kept dry.

Reactivity

When mixed with water, cements will harden into a stable mass that is not reactive in normal environments.

Hazardous reactions

Cements do not cause hazardous reactions.

Avoid

Humid conditions during storage may cause lump formation and loss of product quality.

Incompatible

Acids, ammonium salts, aluminium or other non-noble metals. Uncontrolled use of aluminium powder in wet cement should be avoided as hydrogen is produced.

Decomposition

Cements will not decompose into any hazardous products.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not dispose of into sewage systems or surface waters.

Disposal

Expired cement: use in controlled closed processes, recycle, dispose according to local legislation, or treat with reducing agent. Unused residue/slurries: harden with water and dispose as concrete waste.

Waste Codes

10 13 99 wastes not otherwise specified EWC
10 13 06 Other particulates and dust EWC
10 13 14 waste from manufacturing of cement – waste concrete or concrete sludge EWC
17 01 01 construction and demolition wastes - concrete EWC
15 01 01 wastepaper and cardboard packaging EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not relevant
Shipping Name
Not relevant
Transport Class
Not relevant
Packing Group
Not relevant
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Cement is a mixture according to REACH and is not subject to registration. Cement clinker is exempt from registration (Art 2.7 (b) and Annex V.10 of REACH).

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Cement?

The signal word is danger.

What is the physical form of Cement?

Cement is a dry cement is a finely ground inorganic material appearing as powder with white or grey color. It has odourless odor.

What is Cement used for?

Cements are used in industrial installations to manufacture/formulate hydraulic binders for building and construction work, such as ready-mixed concrete, mortars, renders, grouts, plasters as well as precast concrete. Common cements and cement containing mixtures (hydraulic binders) are used industrially, by professionals as well as by consumers in building and construction work, indoor and outdoor.

What are the hazard statements for Cement?

This substance has 4 hazard statements:

  • H315: Causes skin irritation
  • H317: skin sensitizing
  • H318: Causes serious eye damage
  • H335: May cause respiratory irritation

What is the melting point of Cement?

The melting point is > 1250 °C and the boiling point is not applicable.